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Analytical Chemistry

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Analytical chemistry is the subject for the method and basic principle of studying and identifying of the composition, status, structure of matter as well as determination of related content. It is an important branch of chemistry subject. Analytical chemistry plays an important role in not only its own development but also in various fields related to the chemistry. We can say that all the practice of any human activity involving chemical phenomena is inseparable from analytical chemistry. Now, people have developed various kinds of different analytical methods, which can be classified based on an analysis task, analysis object, the basis of the analysis, requirement of the analysis and sample dosage.

According to the analysis tasks, it can be divided into qualitative analysis, quantitative analysis and structural analysis. Task of qualitative analysis is to identify the elements, radicals, functional groups or compounds that constituting the substances; the task of the quantitative analysis is to determine the content of the related components in the sample; the task of structural analysis is to study the molecular structure or crystal structure of the material.

(1) According to the analysis objects, it can be divided into organic and inorganic analysis; the object for the inorganic analysis is inorganic substance; the object of organic analysis is organic substance. In the inorganic analysis, it is generally required to determine what elements, ions, radicals or compounds that constitutes the sample and measure the percentage of each component; and sometimes it is also necessary for determination of the crystal structure; in the organic analysis, it not only requires the identification of the constituent elements, but also, more importantly, should do the structure analysis and functional group analysis.
(2) According to whether the analysis is based on the physical properties or chemical properties of the substance, it can be divided into instrumental analysis and chemical analysis. Depending on the specific requirements, it can be divided into routine analysis, rapid analysis and arbitration Analysis. Routine analysis refers to the general daily laboratory production analysis, also known as conventional analysis; rapid analysis is a kind of routine analysis and is mainly applied to the control of the production process, demanding the report of the results in the shortest possible time with the error generally being allowed to be greater; arbitration analysis is needed when there is controversy in the analysis results from different institute, demanding related department to conduct accurate analysis using specific method in order to determine the accuracy of the results of the original analysis.
(3) According to the amount of the sample, it can be generally divided into constant (> 0.1g), semi-micro (0.01 ~ 0.1g) and trace (1 ~ 10mg) analysis.
(4) In the inorganic qualitative chemical analysis, people generally apply semi-micro method while people generally apply constant analysis in the quantitative chemical analysis. According to the relative amounts of the analyzed components contained in the sample, it is also roughly divided into constant component analysis (> 1%), minor component analysis (0.01 to 1%) and trace components analysis (<0.01%). For the analysis of some trace amount of components contained in some kinds of complicated mixture and some substances, it is necessary to perform separation and enrichment. This produces a series of separation techniques, such as extraction, distillation, ion exchange, chromatography, sedimentation and flotation separation, these chemical separation techniques are an integral part of the analysis.

Environmental Analytical Chemistry
Environmental Analytical Chemistry is briefly referred to environmental analysis. It is a kind of subject to study the types, components of pollutants in the environment as well as how to perform qualitative and quantitative analysis on the chemical contaminants in the environment. It is a branch of environmental chemistry.

Environmental analytical chemistry emerged, developed and improved during the process of solving environmental problems. In 1950s, the public nuisance disease occurred in Japan had alerted the whole world. In order to find the cause of public nuisance disease, after experiencing as long as 11 years, later, the chemists of environmental analysis had applied light spectrum and identified that the river in Itai-itai disease area contained harmful elements such as lead, cadmium, arsenic and so on. Further by means of tracking element analysis of the soil and food in the disease area, people had found high lead and cadmium content. Later, people had further conducted spectral quantitative analysis on the body and bone of the patients in the disease area and found that the bone ashes contained alarmingly high content of zinc, lead and cadmium. To determine the causative agent, people further incorporated zinc, lead and cadmium into the food for feeding animals and conduct trace elemental analysis for animals and confirmed the serious harm of cadmium on the bone, revealing the cause of the Itai-itai disease. The development of modern science, especially the development of modern chemistry, physics, mathematics, electronics, biology, as well as the emergence of accurate, reliable, sensitive, selective, rapid, simple environmental pollution analysis technology and automation equipment, has been resulting in the maturation of environmental analytical chemistry. Environmental analytical chemistry now has penetrated into all areas of the entire environmental science subject. It is the most effective means of access to environmental information quality.
The objects of the environmental analytical chemistry research are quite complicated, including air, water, soil, sediment, minerals, waste, animals, plants, food, and human tissue. The content of chemical elements or compound to be determined in the environmental analytic chemistry is very low, with the absolute content being within the level of 10-6 to 10-12 grams.


The analysis technology in the environmental analytical chemistry is developing towards the direction of continuous automation, computerization and joint combination of various methods and instruments. Currently applied automatic analysis methods include colorimetric analysis, ion selective electrode, x-ray fluorescence spectroscopy, atomic absorption spectroscopy, polarography, gas chromatography, liquid chromatography and flow injection analysis. Laser, as the light source of analytical chemistry technique, has also been applied. Since the laser analysis has properties of high resolution, high sensitivity, long-range and short-term, the laser technology will play a pivotal role in the development of environmental analytical chemistry.

With the deepened development of environmental science, environmental analytical chemistry is often demanded for trace levels and ultra-trace-level detection and analysis, therefore, high sensitivity. Thus study of analysis methods of high sensitivity, good selectivity, rapid trace and ultra trace will become the major development direction for environmental analysis in the near future.

Qualitative Analysis of Chemistry
Qualitative analytic chemistry is the subject to identify the chemical elements and atoms groups contained in the sample. It is a branch subject of the analysis chemistry. Its purpose is to ascertain the chemical composition of the research object (specimen).
The major research content of the qualitative analytic chemistry includes:

1 the tested samples were analyzed separately. Namely take part of the sample and use exclusive reaction to detect a desire detection component.
2 systematic analysis of the samples. This means successively apply a few selective reactions for gradual separation of the ions followed by separation of each group until separating to only one substance and finally apply confirming reaction to ascertain the existence of this substance. The most famous cation system analysis method is H2S system. In recent years, due to the use of advanced equipment, qualitative analysis has also rapidly developed together with multivariate analysis and has also become an important direction for analytical chemistry.

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Chemical Name:
Peramivir Deacetyl Impurity
Chemical Name:
Empagliflozin Impurity 116
Chemical Name:
(3R,5aS)-5,8-dioxooctahydro-5H-pyrrolo[1,2-a]thiazolo[3,2-d]pyrazine-3-carboxylic acid
Chemical Name:
Phospholipid Impurity 1(DPPE-MPEG5000 Impurity 1)
Chemical Name:
Carbazochrome Sodium Sulfonate Impurity 4
Chemical Name:
Empagliflozin Furanose Impurity
Chemical Name:
Rosuvastatin Impurity 144
Chemical Name:
Cetrorelix Impurity 11
Chemical Name:
Cetrorelix Impurity 4 (8-D-Arg)
Chemical Name:
Cetrorelix Impurity 1 (+L-Arg)
Chemical Name:
Peramivir Intermediate Impurity 36
Chemical Name:
Peramivir Intermediate Impurity 41
Chemical Name:
Peramivir Impurity 999
Chemical Name:
Palonosetron impurity 20XH
Chemical Name:
Apixaban Impurity 89
Chemical Name:
Levofloxacin benzopazine impurity
Structure:
Chemical Name:
Bumetanide Impurity 14
CAS:
1431501-10-8
MF:
C21H27NO3
Chemical Name:
Trans,rel-(1R,4R)-4-{[(2-Aminophenyl)methyl]amino}cyclohexan-1-ol Hydrochloride
Structure:
Chemical Name:
2-(2-NITROPHENYL)ETHANAMINE
CAS:
33100-15-1
MF:
C8H10N2O2
Structure:
Chemical Name:
CLOZAPINE-D3
CAS:
1215691-72-7
MF:
C18H19ClN4
Chemical Name:
Bendamustine Impurity 25
Chemical Name:
Canagliflozin Impurity 25
Structure:
Chemical Name:
Edoxaban Impurity 41
CAS:
1353893-25-0
MF:
C14H27N3O3
Chemical Name:
Istradefylline Impurity 5
Chemical Name:
Milrinone Impurity 10
Structure:
Chemical Name:
N-(2-Chloro-ethyl)-N'-(2,3-dichloro-phenyl)-ethane-1,2-diamine
MF:
C10H13Cl3N2
Structure:
Chemical Name:
Olanzapine Impurity 3
MF:
C17H20N4S
Chemical Name:
Ticagrelor Related Compound 54
Chemical Name:
Adefovir Impurity D
Chemical Name:
Blonanserin Impurity N
Chemical Name:
Brexpiprazole Impurity N
Chemical Name:
Cefaclor Impurity 1
Chemical Name:
Cefminox Sodium impurity 4
Chemical Name:
Cefradine Impurity B
Chemical Name:
Dapoxetine Impurity F
Chemical Name:
Olaparib Impurity E
Structure:
Chemical Name:
Cefathiamidine Impurity 6
CAS:
28240-16-6
MF:
C12H13ClN2O6S
Structure:
Chemical Name:
rac-2,2'-(((3aR,3a'R,4R,4'R,6S,6aS,6'S,6a'S)-((5-nitro-2-(propylthio)pyrimidine-4,6-diyl)bis(azanediyl))bis(2,2-dimethyltetrahydro-4H-cyclopenta[d][1,3]dioxole-6,4-diyl))bis(oxy))bis(ethan-1-ol)
CAS:
1882095-50-2
MF:
C27H43N5O10S
Structure:
Chemical Name:
Levofloxacin Impurity 23
CAS:
2206825-95-6
MF:
C19H21ClFN3O4
Structure:
Chemical Name:
Nitrendipine impurity 1
CAS:
1242511-98-3
MF:
C18H18N2O5
Chemical Name:
Sugammadex Sodium Impurity 08
Chemical Name:
2-bromo-3-(6'-oxo-1'-phenyl-1',6'-dihydro-[2,3'-bipyridin]-5'-yl)benzonitrile
Structure:
Chemical Name:
INDEX NAME NOT YET ASSIGNED
CAS:
2412953-12-7
MF:
C72H112O49S8
Structure:
Chemical Name:
4a(2H)-Isoquinolinol, octahydro-4-(4-methoxyphenyl)-2-methyl-
CAS:
2568340-30-5
MF:
C17H25NO2
Structure:
Chemical Name:
3-Quinolinecarbonitrile, 4-[(2,4-dichloro-5-hydroxyphenyl)amino]-6-methoxy-7-[3-(4-methyl-1-piperazinyl)propoxy]-
CAS:
2468737-92-8
MF:
C25H27Cl2N5O3
Structure:
Chemical Name:
Uridine, 4-oxime, 5'-(2-methylpropanoate), (4E)-
CAS:
2492423-30-8
MF:
C13H19N3O7
Chemical Name:
Empagliflozin Furanose Impurity
Chemical Name:
Tazobactam Impurity XTE
Chemical Name:
Isavuconazole Impurity 46
Structure:
Chemical Name:
5-(1-((5,6-diethyl-2,3-dihydro-1H-inden-2-yl)amino)-2-hydroxyethyl)-8-hydroxyquinolin-2(1H)-one
CAS:
2226428-25-5
MF:
C24H28N2O3
Structure:
Chemical Name:
INDEX NAME NOT YET ASSIGNED
CAS:
2740235-22-5
MF:
C13H22N2O5
Structure:
Chemical Name:
2-(4-ethylpiperazin-1-yl)-4-(2-fluorophenyl)-5,6,7,8,9,10-hexahydrocycloocta[b]pyridine
MF:
C23H30FN3
Structure:
Chemical Name:
1-Naphthalenamine, 4-(2,3-dichlorophenyl)-1,2,3,4-tetrahydro-N-methyl-, (1R,4S)-rel-
CAS:
2184053-08-3
MF:
C17H17Cl2N
Chemical Name:
Rosuvastatin Impurity 152
Structure:
Chemical Name:
methyl 7-bromo-4-hydroxyisoquinoline-3-carboxylate
CAS:
1572439-66-7
MF:
C11H8BrNO3
Structure:
Chemical Name:
Dapoxetine impurity
CAS:
2242008-36-0
MF:
C28H26O3
Structure:
Chemical Name:
Pregabalin Impurity 11
CAS:
177432-20-1
MF:
C7H11NO3
Structure:
Chemical Name:
Pregabalin Impurity 6
CAS:
2102350-92-3
MF:
C9H15NO3
Chemical Name:
Sunitinib Impurity 2
Structure:
Chemical Name:
(2S,3R,4R,5S,6R)-2-(3-(4-ethoxybenzyl)phenyl)-6-(hydroxyl methyl)tetrahydro-2H-pyran-3,4,5-triol
CAS:
2452300-89-7
MF:
C21H26O6
Structure:
Chemical Name:
(R)-Zanubrutinib
CAS:
1691249-44-1
MF:
C27H29N5O3
Structure:
Chemical Name:
LUMAT-005
CAS:
313369-16-3
MF:
C16H19N3O3
Chemical Name:
Fimasartan Impurity F
Structure:
Chemical Name:
Amlodipine Impurity 23 (E-Isomer)
MF:
C26H31ClN2O8S
Chemical Name:
Axitinib Impurity 12
Chemical Name:
Axitinib Impurity 17
Chemical Name:
Erlotinib Impurity 37
Chemical Name:
Gefitinib impurity M
Structure:
Chemical Name:
Fulvestrant EP Impurity E
CAS:
2170200-14-1
MF:
C32H45F5O3S
Structure:
Chemical Name:
Liquiritigenin-7-O-apiosyl(1-2)-glucoside
CAS:
135432-48-3
MF:
C26H30O13
Chemical Name:
Edaravone Impurity 16
Chemical Name:
Linagliptin Impurity 50
Structure:
Chemical Name:
Landiolol impurity K
CAS:
190601-22-0
MF:
C19H29N3O6
Structure:
Chemical Name:
Efinaconazole Impurity 13
CAS:
2055038-61-2
MF:
C18H22F2N4O
Structure:
Chemical Name:
Crisaborole Impurity
CAS:
906673-42-5
MF:
C14H10BNO3
Structure:
Chemical Name:
tert-butyl 2-((4R,6S)-6-(2-(2-(4-fluorophenyl)-5-isopropyl-3-phenyl- 4-(phenylcarbamoyl)-1H-pyrrol-1-yl)ethyl)-2,2-dimethyl-1,3-dioxan-4-yl)acetate
CAS:
947249-30-1
MF:
C40H47FN2O5
Structure:
Chemical Name:
Olanzapine impurity N
MF:
C17H20N4S
Chemical Name:
Cabozantinib impurity 25
Chemical Name:
Afatinib impurity 43
Chemical Name:
Vildagliptin Impurity 39
Chemical Name:
Tazobactam Impurity D
Structure:
Chemical Name:
Palonosetron Impurity 22
CAS:
1217547-14-2
MF:
C19H24N2O2
Chemical Name:
Pitavastatin Impurity 35
Chemical Name:
Pralatrexate Impurity 15
Chemical Name:
Pitavastatin Impurity 52
Structure:
Chemical Name:
Pitavastatin Impurity 60
CAS:
1661064-71-6
MF:
C25H22FNO3
Chemical Name:
Lenvatinib Impurity 43
Chemical Name:
Voriconazole Impurity 10
Chemical Name:
Prednicarbate Impurity D
Structure:
Chemical Name:
Olprinone Impurity A
CAS:
141354-29-2
MF:
C12H10N4O
Structure:
Chemical Name:
Everolimus EP Impurity E
CAS:
1237826-25-3
MF:
C52H79NO14
Chemical Name:
Edaravone Impurity P4
Chemical Name:
Afatinib impurity 47
Chemical Name:
Canagliflozin Impurity 50
Chemical Name:
Canagliflozin Impurity 66
Chemical Name:
Acyclovir Impurity 12
Structure:
Chemical Name:
4-(4-Hydroxy-3-hydroxymethyl-phenoxy)-benzonitrile
MF:
C14H11NO3
Chemical Name:
Bumetanide iMpurity F
Structure:
Chemical Name:
IODIXANOL RELATED COMPOUND D (50 MG) (5-[ACETYL(2-HYDROXY-3-METHYLPROPYL)AMINO]-N,N'-BIS(2,3-DIHYDROXYPROPYL)2,4,6-TRIIODO-1,3-BENZE-NEDICARBOXAMIDE)
CAS:
89797-00-2
MF:
C20H28I3N3O9
Structure:
Chemical Name:
NIMODIPINE RELATED COMPOUND B (50 MG) (BIS(2-METHOXYETHYL) 2,6-DIMETHYL-4-(3-NITROPHE-NYL)-1,4-DIHYDROPYRIDINE-3,5-DICARBOXYLATE) (AS)
CAS:
70172-96-2
MF:
C21H26N2O8