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Analytical Chemistry

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Analytical chemistry is the subject for the method and basic principle of studying and identifying of the composition, status, structure of matter as well as determination of related content. It is an important branch of chemistry subject. Analytical chemistry plays an important role in not only its own development but also in various fields related to the chemistry. We can say that all the practice of any human activity involving chemical phenomena is inseparable from analytical chemistry. Now, people have developed various kinds of different analytical methods, which can be classified based on an analysis task, analysis object, the basis of the analysis, requirement of the analysis and sample dosage.

According to the analysis tasks, it can be divided into qualitative analysis, quantitative analysis and structural analysis. Task of qualitative analysis is to identify the elements, radicals, functional groups or compounds that constituting the substances; the task of the quantitative analysis is to determine the content of the related components in the sample; the task of structural analysis is to study the molecular structure or crystal structure of the material.

(1) According to the analysis objects, it can be divided into organic and inorganic analysis; the object for the inorganic analysis is inorganic substance; the object of organic analysis is organic substance. In the inorganic analysis, it is generally required to determine what elements, ions, radicals or compounds that constitutes the sample and measure the percentage of each component; and sometimes it is also necessary for determination of the crystal structure; in the organic analysis, it not only requires the identification of the constituent elements, but also, more importantly, should do the structure analysis and functional group analysis.
(2) According to whether the analysis is based on the physical properties or chemical properties of the substance, it can be divided into instrumental analysis and chemical analysis. Depending on the specific requirements, it can be divided into routine analysis, rapid analysis and arbitration Analysis. Routine analysis refers to the general daily laboratory production analysis, also known as conventional analysis; rapid analysis is a kind of routine analysis and is mainly applied to the control of the production process, demanding the report of the results in the shortest possible time with the error generally being allowed to be greater; arbitration analysis is needed when there is controversy in the analysis results from different institute, demanding related department to conduct accurate analysis using specific method in order to determine the accuracy of the results of the original analysis.
(3) According to the amount of the sample, it can be generally divided into constant (> 0.1g), semi-micro (0.01 ~ 0.1g) and trace (1 ~ 10mg) analysis.
(4) In the inorganic qualitative chemical analysis, people generally apply semi-micro method while people generally apply constant analysis in the quantitative chemical analysis. According to the relative amounts of the analyzed components contained in the sample, it is also roughly divided into constant component analysis (> 1%), minor component analysis (0.01 to 1%) and trace components analysis (<0.01%). For the analysis of some trace amount of components contained in some kinds of complicated mixture and some substances, it is necessary to perform separation and enrichment. This produces a series of separation techniques, such as extraction, distillation, ion exchange, chromatography, sedimentation and flotation separation, these chemical separation techniques are an integral part of the analysis.

Environmental Analytical Chemistry
Environmental Analytical Chemistry is briefly referred to environmental analysis. It is a kind of subject to study the types, components of pollutants in the environment as well as how to perform qualitative and quantitative analysis on the chemical contaminants in the environment. It is a branch of environmental chemistry.

Environmental analytical chemistry emerged, developed and improved during the process of solving environmental problems. In 1950s, the public nuisance disease occurred in Japan had alerted the whole world. In order to find the cause of public nuisance disease, after experiencing as long as 11 years, later, the chemists of environmental analysis had applied light spectrum and identified that the river in Itai-itai disease area contained harmful elements such as lead, cadmium, arsenic and so on. Further by means of tracking element analysis of the soil and food in the disease area, people had found high lead and cadmium content. Later, people had further conducted spectral quantitative analysis on the body and bone of the patients in the disease area and found that the bone ashes contained alarmingly high content of zinc, lead and cadmium. To determine the causative agent, people further incorporated zinc, lead and cadmium into the food for feeding animals and conduct trace elemental analysis for animals and confirmed the serious harm of cadmium on the bone, revealing the cause of the Itai-itai disease. The development of modern science, especially the development of modern chemistry, physics, mathematics, electronics, biology, as well as the emergence of accurate, reliable, sensitive, selective, rapid, simple environmental pollution analysis technology and automation equipment, has been resulting in the maturation of environmental analytical chemistry. Environmental analytical chemistry now has penetrated into all areas of the entire environmental science subject. It is the most effective means of access to environmental information quality.
The objects of the environmental analytical chemistry research are quite complicated, including air, water, soil, sediment, minerals, waste, animals, plants, food, and human tissue. The content of chemical elements or compound to be determined in the environmental analytic chemistry is very low, with the absolute content being within the level of 10-6 to 10-12 grams.


The analysis technology in the environmental analytical chemistry is developing towards the direction of continuous automation, computerization and joint combination of various methods and instruments. Currently applied automatic analysis methods include colorimetric analysis, ion selective electrode, x-ray fluorescence spectroscopy, atomic absorption spectroscopy, polarography, gas chromatography, liquid chromatography and flow injection analysis. Laser, as the light source of analytical chemistry technique, has also been applied. Since the laser analysis has properties of high resolution, high sensitivity, long-range and short-term, the laser technology will play a pivotal role in the development of environmental analytical chemistry.

With the deepened development of environmental science, environmental analytical chemistry is often demanded for trace levels and ultra-trace-level detection and analysis, therefore, high sensitivity. Thus study of analysis methods of high sensitivity, good selectivity, rapid trace and ultra trace will become the major development direction for environmental analysis in the near future.

Qualitative Analysis of Chemistry
Qualitative analytic chemistry is the subject to identify the chemical elements and atoms groups contained in the sample. It is a branch subject of the analysis chemistry. Its purpose is to ascertain the chemical composition of the research object (specimen).
The major research content of the qualitative analytic chemistry includes:

1 the tested samples were analyzed separately. Namely take part of the sample and use exclusive reaction to detect a desire detection component.
2 systematic analysis of the samples. This means successively apply a few selective reactions for gradual separation of the ions followed by separation of each group until separating to only one substance and finally apply confirming reaction to ascertain the existence of this substance. The most famous cation system analysis method is H2S system. In recent years, due to the use of advanced equipment, qualitative analysis has also rapidly developed together with multivariate analysis and has also become an important direction for analytical chemistry.

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Structure:
Chemical Name:
Peramivir Impurity 30
CAS:
2758048-79-0
MF:
C20H36N2O6
Chemical Name:
Cefmetazole Impurity E
Structure:
Chemical Name:
Azlocillin Opern-Ring Decarboxylation Impurity
CAS:
99795-14-9
MF:
C19H25N5O5S
Structure:
Chemical Name:
Cefotiam Impurity 1
CAS:
2243596-87-2
MF:
C18H23N9O4S3
Chemical Name:
Eribulin Impurity 3
Chemical Name:
NICERGOLINE IMP. D (EP): 5-BROMOPYRIDINE-3-CARBOXYLIC ACID
Structure:
Chemical Name:
AMOXICILLIN TRIHYDRATE IMP. D (EP) AS SODIUM SALT:(4S)-2-[[[(2R)-2-AMINO-2-(4-HYDROXYPHENYL)ACETYL]AMINO]-CARBOXYMETHYL]-5,5-DIMETHYLTHIAZOLIDINE-4-CARBOXYLIC ACID SODIUM SALT (PENICILLOICACIDS OF AMO
CAS:
1642629-94-4
MF:
C16H21N3O6S
Structure:
Chemical Name:
4-CHLORO-6-(2-CHLORO-ETHOXY)-7-(2-METHOXY-ETHOXY)-QUINAZOLINE
CAS:
183322-19-2
MF:
C13H14Cl2N2O3
Chemical Name:
cefdinir
Chemical Name:
ACICLOVIR, Impurity J
Structure:
Chemical Name:
1H-Inden-1-amine, 2,3-dihydro-N-2-propen-1-yl-
CAS:
91639-43-9
MF:
C12H15N
Structure:
Chemical Name:
Salbutamol impurity 42
CAS:
18910-69-5
MF:
C14H23NO3
Chemical Name:
(E)-8-(3,4-dimethoxystyryl)
Chemical Name:
tert-butyl (3R,5R)-7-((3R,5R)-7-(2-(4-fluorophenyl)-5-isopropyl-3-phenyl-4-(phenylcarbamoyl)-1H-pyrrol-1-yl)-3,5-dihydroxyheptanamido)-3,5-dihydroxyheptanoate
Structure:
Chemical Name:
(+)-Mediresinol Di-O-β-D-glucopyranoside
CAS:
88142-63-6
MF:
C33H44O17
Structure:
Chemical Name:
1H-Imidazole-1-carboxylic acid, (1R)-2-(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)-1-[[[(2R)-3-(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)-2-[(1H-imidazol-1-ylcarbonyl)oxy]propyl][4-(3-oxo-4-morpholinyl)phenyl]amino]methyl]ethyl ester
CAS:
2097255-05-3
MF:
C40H34N8O10
Chemical Name:
Elagolix Sodium impurity5
Chemical Name:
Tadalafil Impurity 46
Structure:
Chemical Name:
(S)-3-Methyl-1-(2-piperidin-1-ylphenyl)butylamine
CAS:
147769-93-5
MF:
C16H26N2
Structure:
Chemical Name:
4,4′-DIPHENOQUINONE (DQ)
CAS:
494-72-4
MF:
C12H8O2
Structure:
Chemical Name:
S-(+)-O-DESMETHYL VENLAFAXINE
CAS:
142761-12-4
MF:
C16H25NO2
Structure:
Chemical Name:
ACETYLSIMVASTATIN
CAS:
145576-25-6
MF:
C27H40O6
Structure:
Chemical Name:
5-[2-(4'-METHYLBIPHENYL)]TETRAZOLE
CAS:
120568-11-8
MF:
C14H12N4
Structure:
Chemical Name:
L-2-Aminobutanamide
CAS:
7324-11-0
MF:
C4H10N2O
Structure:
Chemical Name:
Dihydro-Simvastatin
CAS:
92083-03-9
MF:
C25H40O5
Chemical Name:
Ceftriaxone Sodium impurity 3
Chemical Name:
Sugammadex sodium Monoiodo Impurity
Structure:
Chemical Name:
(3S,4R)-3-((benzo[d][1,3]dioxol-5-yloxy)methyl)-1-methyl-4-phenylpiperidine
MF:
C20H23NO3
Structure:
Chemical Name:
Avatrombopag Impurity 22
CAS:
570403-14-4
MF:
C31H38Cl2N6O3S2
Structure:
Chemical Name:
176760-99-9
CAS:
176760-99-9
MF:
C17H13FN2O4
Structure:
Chemical Name:
NILOTINIB IMPURITY 17
CAS:
851137-91-2
MF:
C17H15N5O
Chemical Name:
DexMedetoMidine IMpurity 16
Structure:
Chemical Name:
(trans)-4-((2-amino-3,4-dibromobenzyl)amino)cyclohexanol
MF:
C13H18Br2N2O
Chemical Name:
(trans)-3-(4-((trans)-1,3,4-trihydroxybutan-2-yl)-1,4,7,10-tetraazacyclododecan-1-yl)butane-1,2,4-triol
Chemical Name:
Cefdinir CP Impurity B
Structure:
Chemical Name:
Voriconazole Impurity 15
CAS:
321589-00-8
MF:
C22H19F4N7O
Chemical Name:
Fluconazole Impurity 2
Chemical Name:
Imatinib EP Impurity D Chloride
Chemical Name:
Favipiravir Impurity
Structure:
Chemical Name:
Vildagliptin Dione Impurity
CAS:
1844894-70-7
MF:
C17H24N2O3
Chemical Name:
Adsorption of hydrogen sulfide Adsorption of impurities in water filter material
Structure:
Chemical Name:
Citalopram impurity 9/Citalopram EP Impurity C Oxalate Salt/3-Oxo Citalopram Oxalate Salt/Citalopram Related Compound C Oxalate Salt/3-(3-Dimethylaminopropyl)-3-(4-fluorophenyl)-6-cyano-1(3H)-isobenzofuranone oxalate
CAS:
1440961-11-4
MF:
C22H21FN2O6
Structure:
Chemical Name:
1H-Pyrrole-3-carboxamide, 5-[(Z)-(5-fluoro-1,2-dihydro-2-oxo-3H-indol-3-ylidene)methyl]-N-(2-hydroxyethyl)-2,4-dimethyl-
CAS:
2170562-55-5
MF:
C18H18FN3O3
Structure:
Chemical Name:
Apixaban Impurity 70
CAS:
1998079-14-3
MF:
C44H40N8O9
Structure:
Chemical Name:
Favipiravir Impurity 14
CAS:
356783-49-8
MF:
C5HClFN3
Structure:
Chemical Name:
Posaconazole Impurity 93
CAS:
165115-82-2
MF:
C19H19F2IO2
Chemical Name:
N-Dealkyl Flurazepam (Midazolam impurity)
Chemical Name:
4-((3-amino-1H-indazol-5-yl)methyl)phthalazin-1(2H)-one
Chemical Name:
AMIKACIN IMPURITY A
Structure:
Chemical Name:
FUROSEMIDE IMPURITY A
MF:
C12H11ClN2O5S
Chemical Name:
GLICLAZIDE IMPURITY F
Chemical Name:
ONDANSETRON IMPURITY D
Chemical Name:
PERINDOPRIL IMPURITY A
Structure:
Chemical Name:
(E)-Ceftiofur
CAS:
120882-20-4
MF:
C19H17N5O7S3
Structure:
Chemical Name:
CAPECITABINE-D11
CAS:
1132662-08-8
MF:
C15H13D11FN3O6
Structure:
Chemical Name:
Abacavir
CAS:
141271-12-7
MF:
C10H14ClN5O
Chemical Name:
Canagliflozin Impurity 42
Structure:
Chemical Name:
Maleic Acid
CAS:
2170020-79-6
MF:
C21H20FN3O6S
Structure:
Chemical Name:
Ozagrel Impurity 21
CAS:
883942-98-1
MF:
C23H20N2O4
Structure:
Chemical Name:
Terbutaline Impurity
CAS:
1226543-90-3
MF:
C22H20O4
Structure:
Chemical Name:
lidocaine impurity
CAS:
1374010-02-2
MF:
C30H36N4O3
Chemical Name:
Desloratadine Impurity 7
Chemical Name:
Esomeprazole Impurity 28
Structure:
Chemical Name:
ethyl 2-(3-carbamoyl-4-isobutoxyphenyl)-4-methylthiazole-5- carboxylate
CAS:
1346238-15-0
MF:
C18H22N2O4S
Structure:
Chemical Name:
Ropivacaine impurity
CAS:
1786518-57-7
MF:
C13H16N2O3
Structure:
Chemical Name:
Mono Oxidation Sugammadex(Org199425-1)
CAS:
2412953-14-9
MF:
C72H113NaO49S8
Chemical Name:
Piperacillin Impurity N
Structure:
Chemical Name:
2-(1-(dimethylamino)ethyl)phenol 2,3-dihydroxysuccinate
CAS:
26050-44-2
MF:
C10H15NO
Structure:
Chemical Name:
1,11-ditosyl-1,4,8,11-tetraazacyclotetradecane dihydrochloride
CAS:
117152-73-5
MF:
C24H36N4O4S2
Structure:
Chemical Name:
PeraMpanel
CAS:
684648-40-6
MF:
C10H10BNO2
Structure:
Chemical Name:
3-CHLORO-N-(3-METHOXYPHENYL)PROPANAMIDE
CAS:
21261-76-7
MF:
C10H12ClNO2
Structure:
Chemical Name:
Amlodipine Impurity 31
CAS:
496024-43-2
MF:
C20H22ClNO5
Chemical Name:
Fudosteine Impurity 5
Structure:
Chemical Name:
Rasagiline Impurity 4
CAS:
1175018-79-7
MF:
C12H14ClN
Chemical Name:
Canagliflozin Impurity 2
CAS:
2952941-15-8
Chemical Name:
Rivaroxaban Impurity 22
Structure:
Chemical Name:
Levofloxacin Impurity 5
CAS:
2206360-62-3
MF:
C13H10FNO5
Chemical Name:
Ezetimibe Impurity 33
Structure:
Chemical Name:
Ezetimibe-28
CAS:
1478663-95-4
MF:
C44H52F2N2O6Si
Chemical Name:
Vonoprazan Impurity U4
Structure:
Chemical Name:
Emtricitabine Impurity 28
CAS:
1238210-14-4
MF:
C8H11N3O4S
Chemical Name:
Parecoxib SodiuM iMpurity 37
Structure:
Chemical Name:
(3R,4R)-3-((benzo[d][1,3]dioxol-5-yloxy)methyl)-4-(4-fluorophenyl)-1-methylpiperidine compound
CAS:
105834-21-7
MF:
C20H22FNO3
Chemical Name:
Ninhydrine, ozone friendly ready to use spray for TLC chromatography
CAS:
32-70-2
MF:
C9H4O3.H2O
Chemical Name:
Apixaban Impurity BMS-A
Structure:
Chemical Name:
Afatinib Impurity 70
CAS:
125781-04-6
MF:
C4H7ClO2
Structure:
Chemical Name:
Apixaban impurity 14/6-(4-aminophenyl)-1-(4-methoxyphenyl)-7-oxo-4,5,6,7-tetrahydro-1H-pyrazolo[3,4-c]pyridine-3-carboxylic acid
CAS:
1704504-93-7
MF:
C20H18N4O4
Structure:
Chemical Name:
Cabozantinib Impurity 46
CAS:
1247859-37-5
MF:
C11H10FNO3
Structure:
Chemical Name:
Ivabradine Impurity S33172
CAS:
2247881-26-9
MF:
C26H34N2O5
Chemical Name:
Tenofovir Impurity 71
Structure:
Chemical Name:
2-(chloromethyl)-3-methylpyridin-4-ol
CAS:
1805648-51-4
MF:
C7H8ClNO
Chemical Name:
Ampicillin EP Impurity S
Chemical Name:
Ampicillin EP Impurity S
Structure:
Chemical Name:
Mupirocin Calcium EP Impurity I
MF:
C26H44CaO9
Structure:
Chemical Name:
Benzenepropanoic acid, α-hydroxy-β-[[(3E)-1-oxo-3-hexen-1-yl]amino]-, (2aR,4S,4aS,6R,9S,11S,12S,12aR,12bS)-6,12b-bis(acetyloxy)-12-(benzoyloxy)-2a,3,4,4a,5,6,9,10,11,12,12a,12b-dodecahydro-4,11-dihydroxy-4a,8,13,13-tetramethyl-5-oxo-7,11-methano-1H-cyclod
CAS:
2243233-98-7
MF:
C46H55NO14
Structure:
Chemical Name:
D-erythro-Hexonic acid, 2,4-dideoxy-3,5-O-(1-methylethylidene)-6-S-(5-methyl-1,3,4-thiadiazol-2-yl)-6-thio-, 1,1-dimethylethyl ester
CAS:
1326303-05-2
MF:
C16H26N2O4S2
Structure:
Chemical Name:
L-Leucine, N-[(2S)-2-amino-1-oxo-4-phenylbutyl]-
CAS:
290298-02-1
MF:
C16H24N2O3
Structure:
Chemical Name:
Glycine, N-[4-(aminocarbonyl)phenyl]-
CAS:
355809-32-4
MF:
C9H10N2O3
Structure:
Chemical Name:
5-Isobenzofurancarbonitrile, 1-[3-(dimethylamino)propyl]-1,3-dihydro-1-hydroxy-
CAS:
2102609-59-4
MF:
C14H18N2O2
Structure:
Chemical Name:
L-Milnacipran Carbamoyl-beta-D-Glucuronide
CAS:
1446438-98-7
MF:
C22H30N2O9