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(Pentamethylcyclopentadienyl)iridium(III) chloride dimer

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(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Basic information

Product Name:
(Pentamethylcyclopentadienyl)iridium(III) chloride dimer
Synonyms:
  • (PentaMethylcyclopentadienyl)iridiuM(III) chloride diMer, 99% 250MG
  • PentaMethylcyclopentadienyl)iridiuM(III) chloride diMer,98% (Cp*IrCl2)2
  • (PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM(III) CHLORIDE DIMER
  • Dichloro(pentaMethylcyclopentadienyl)iridiuM(III)diMMer
  • Pentamethylcyclopentadienyliridium(Ⅲ) chloride dimer
  • PentaMethylcyclopentadienyl)iridiuM(III) chloride diMer,(Cp*IrCl2)2
  • PentaMethylcyclopentadienyliridiuM(Ⅲ) chloride diMer, 48% Ir, Product of UMicore
  • PentaMethylcyclopentadienyliridiuM(III) chloride,diMer 96%
CAS:
12354-84-6
MF:
C20H30Cl4Ir210*
MW:
796.7
Product Categories:
  • Ir
  • organometallic complexes
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Ir (Iridium) Compounds
  • Metal Complexes
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Iridium
Mol File:
12354-84-6.mol
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(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Chemical Properties

Melting point:
245 °C (decomp)(Solv: chloroform (67-66-3); hexane (110-54-3))
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Sparingly), Methanol (Slightly)
form 
crystal
color 
orange
Stability:
Moisture Sensitive
CAS DataBase Reference
12354-84-6
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38-R36/37/38
Safety Statements 
37/39-26-S37/39-S26-24/25
WGK Germany 
3
TSCA 
No
HS Code 
28439000

MSDS

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(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Usage And Synthesis

Reaction

  1. Iridium-catalyzed C-3 alkylation of oxindole with alcohols.
  2. Precursor to N-heterocyclic carbene catalyst effective for hydrogenation and alkylation of amines and alcohols.
  3. Precursor to efficient phosphine free catalyst for enantioselective hydrogenation of quinoline derivatives.
  4. Catalyst for oxidative C–H activation.
  5. Precursor to an effective water oxidation catalyst. 

Chemical Properties

orange fine crystalline powder

Uses

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer is used as a precursor to catalysts for the asymmetric transfer hydrogenation of ketones. It is a catalyst for greener amine synthesis.

General Description

This product has been enhanced for catalytic efficiency.

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