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Benzophenone hydrazone

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Benzophenone hydrazone Basic information

Product Name:
Benzophenone hydrazone
Synonyms:
  • 3-iodo-N-[[2-[4-(2-methyl-1-oxopropyl)-1-piperazinyl]anilino]-sulfanylidenemethyl]benzamide
  • Ht--103 Benzophenonehydrazone (Bph)
  • BENZOPHENONE HYDRAZONE
  • BENZOPHENONE HYDROZONE
  • Methanone, diphenyl-, hydrazone
  • Benzophenone hydrazone, 98+%
  • Benzophenone hydrazo
  • Di(phenyl)methylidenehydrazine
CAS:
5350-57-2
MF:
C13H12N2
MW:
196.25
EINECS:
226-321-8
Product Categories:
  • Pharmaceutical Intermediates
  • Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes
  • Phenylhydrazine
  • Heterocyclic Compounds
  • bc0001
  • 5350-57-2
Mol File:
5350-57-2.mol
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Benzophenone hydrazone Chemical Properties

Melting point:
95-98 °C (lit.)
Boiling point:
225-230 °C/55 mmHg (lit.)
Density 
1.1
refractive index 
1.5014 (estimate)
Flash point:
146°C
storage temp. 
2-8°C
solubility 
Soluble in ether, benzene, chloroform and other organic solvents.
pka
1.44±0.70(Predicted)
form 
Crystalline Needles or Crystalline Powder
color 
White to yellow
BRN 
1910177
InChIKey
QYCSNMDOZNUZIT-UHFFFAOYSA-N
CAS DataBase Reference
5350-57-2(CAS DataBase Reference)
NIST Chemistry Reference
Methanone, diphenyl-, hydrazone(5350-57-2)
EPA Substance Registry System
Methanone, diphenyl-, hydrazone (5350-57-2)
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Safety Information

Hazard Codes 
Risk Statements 
Safety Statements 
WGK Germany 
3
RTECS 
PC4954487
TSCA 
Yes
HS Code 
29280090

MSDS

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Benzophenone hydrazone Usage And Synthesis

Synthesis

Benzophenone hydrazone was synthesised by Benzophenone and hydrazine hydrate stirred in ionic liquid for 0.5-6h at 0~140℃.

Chemical Properties

white to light yellow crystal powde

Uses

An important compound in organic photochemistry and perfumery as well as in organic synthesis. Used in the antibiotics synthesis of 6-APA and 7-ACA of the carboxyl protecting groups and other organic compounds. Used as organic pigment and medical intermediate. It is used as a photoinitiator of UV-curing applications in inks, adhesive, coatings and optical fiber.

Synthesis Reference(s)

Journal of the American Chemical Society, 72, p. 2890, 1950 DOI: 10.1021/ja01163a024
Organic Syntheses, Coll. Vol. 3, p. 351, 1955

Benzophenone hydrazoneSupplier

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