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Benzophenone imine

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Benzophenone imine Basic information

Product Name:
Benzophenone imine
Synonyms:
  • Benzophenone imine ,98%
  • Benzophenone imine ,97%
  • 1-naphtholphthalein.BenzophenoneiMine
  • 6-benzoylcyclohexa-2,4-dien-1-iMine
  • Benzophenone iMine, stabilized, 97% 100GR
  • Benzophenone iMine, stabilized, 97% 5GR
  • 1,1-Diphenylmethylimine, Benzophenone imine, 1,1-Diphenylmethanimine
  • DiphenylMethaniMineiMine
CAS:
1013-88-3
MF:
C13H11N
MW:
181.23
EINECS:
440-870-2
Product Categories:
  • Pharmaceutical Intermediates
  • B
  • Stains and Dyes
  • Stains&Dyes, A to
  • Aromatic Building Blocks
Mol File:
1013-88-3.mol
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Benzophenone imine Chemical Properties

Melting point:
-30 °C
Boiling point:
151-153 °C10 mm Hg(lit.)
Density 
1.08 g/mL at 25 °C(lit.)
vapor pressure 
0.082Pa at 20℃
refractive index 
n20/D 1.618(lit.)
Flash point:
145 °C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
DMSO (Slightly), Ethyl Acetate (Slightly)
form 
Liquid
pka
pK1:6.82 (25°C)
color 
Clear colorless to light yellow-brownish
Water Solubility 
0.3 g/L (25 ºC)
BRN 
1100371
InChIKey
SXZIXHOMFPUIRK-UHFFFAOYSA-N
CAS DataBase Reference
1013-88-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzenemethanimine, «alpha»-phenyl-(1013-88-3)
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Safety Information

Hazard Codes 
Xi,N,Xn
Risk Statements 
36/37/38-51/53-38-22
Safety Statements 
26-36-61-37
RIDADR 
UN3082
WGK Germany 
3
HS Code 
29252900

MSDS

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Benzophenone imine Usage And Synthesis

Chemical Properties

clear colorless to light yellow-brownish liquid

Uses

Useful in the preparation of nitrile ylide dimers.Benzophenone imine as ammonia surrogate. As intermediate material for synthesis of organic chemicals. Catalytic enantioselective alkylation of the benzophenone imine of glycine t-butyl ester using phosphazene (Schwesinger) bases and chiral quaternary ammonium salts yields either enantiomer of amino acid derivatives in excellent yield.

Uses

Benzophenone imine is useful in the preparation of nitrile ylide dimers.

Synthesis Reference(s)

Synthetic Communications, 18, p. 1501, 1988 DOI: 10.1080/00397918808081307

Flammability and Explosibility

Not classified

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