Boc-D-Phenylglycine Chemical Properties

Melting point:

88-91 °C

alpha 

-142 º (c=1% in ethanol)

Boiling point:

407.2±38.0 °C(Predicted)

Density 

1.182±0.06 g/cm3(Predicted)

refractive index 

-140 ° (C=1, EtOH)

storage temp. 

Keep in dark place,Sealed in dry,Room Temperature

solubility 

DMSO, Methanol

pka

3.51±0.10(Predicted)

form 

Crystalline Powder

color 

White

optical activity

[α]20/D 141.0±5.0°, c = 1% in ethanol

Water Solubility 

Insoluble in water. Slightly soluble in DMSO and methanol.

BRN 

3033982

CAS DataBase Reference

33125-05-2(CAS DataBase Reference)

Safety Information

Safety Statements 

24/25

WGK Germany 

3

HazardClass 

IRRITANT

HS Code 

29242990

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

Boc-D-Phenylglycine Usage And Synthesis

Chemical Properties

White powder

Uses

It is a reagent of choice for assignment of absolute configuration of chiral primary amines by 1H NMR, giving better results than Mosher's acid ((R)-(+)-?-Methoxy-?-(trifluoromethyl)-phenyl-acetic acid. αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is D-(+)-2-Phenylglycine with Boc protecting group. (αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is used as part of a catalyst combination to catalyze regioselective [4 + 2] cycloadditions of β-substituted cyclic enones and polyconjugated malononitriles. It can also be used to catalyze stereoselective preparation of polyfunctional nitrocyclohexene carboxaldehydes.

Boc-D-Phenylglycine(33125-05-2)Related Product Information

• Glycine
• D-2-Phenylglycine
• Anilinoacetic acid
• 4-Aminophenylacetic acid
• 4-Hydroxy-D-(-)-2-phenylglycine
• L-Phenylglycine
• Tamoxifen
• Boc-Aib-OH
• N-Carbobenzyloxyglycine
• BOC-Glycine
• 2-Phenoxyethanol
• Phenoxybenzamine hydrochloride
• BOC-GLY-LEU-OH
• BOC-L-PHENYLGLYCINE(BOC-PHG-OH),N-ALPHA-T-BOC-D-PHENYLGLYCINE,N-BOC-D-PHENYLGLYCINE
• N-BOC-DL-PHENYLGLYCINE
• BOC-DL-Phg-OH
• BOC-L-PHENYLGLYCINE HYDROXY-SUCCINIMIDE ESTER,BOC-L-PHENYLGLYCINE N-HYDROXYSUCCINIMIDE ESTER,BOC-L-PHENYLGLYCINE HYDROXY-SUCCINIMIDESTER
• BOC-D-PHENYLGLYCINE N-HYDROXYSUCCINIMIDE ESTER,BOC-D-PHENYLGLYCINE HYDROXY-SUCCINIMIDE ESTER,BOC-D-PHENYLGLYCINE HYDROXY-SUCCINIMIDESTER