Basic information Safety Supplier Related
ChemicalBook >  Product Catalog >  Biochemical Engineering >  Amino Acids and Derivatives >  Glycine derivative >  Boc-D-Phenylglycine

Boc-D-Phenylglycine

Basic information Safety Supplier Related

Boc-D-Phenylglycine Basic information

Product Name:
Boc-D-Phenylglycine
Synonyms:
  • Boc-(R)-2-aminobenzeneacetic acid
  • N-(tert-Butoxycarbonyl)-D-2-phenylglycine
  • N-Boc-D-2-phenylglycine
  • N-(tert-butoxycarbonyl)-D-alpha-phenylglycine
  • N-Boc-D-2-phenylglycine Boc-D-Phg-OH
  • (R)-2-((tert-butoxycarbonyl)aMino)-2-phenylacetic acid
  • N-Boc-D-phenylglycine (Boc-D-Phg-OH)
  • BOC-(PHENYL)GLY-OH
CAS:
33125-05-2
MF:
C13H17NO4
MW:
251.28
EINECS:
1533716-785-6
Product Categories:
  • Phenylglycine [Phg]
  • Unusual Amino Acids
  • Amino Acids
  • Amino Acids (N-Protected)
  • Biochemistry
  • Boc-Amino Acids
  • Boc-Amino acid series
Mol File:
33125-05-2.mol
More
Less

Boc-D-Phenylglycine Chemical Properties

Melting point:
88-91 °C
alpha 
-142 º (c=1% in ethanol)
Boiling point:
407.2±38.0 °C(Predicted)
Density 
1.182±0.06 g/cm3(Predicted)
refractive index 
-140 ° (C=1, EtOH)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
DMSO, Methanol
pka
3.51±0.10(Predicted)
form 
Crystalline Powder
color 
White
optical activity
[α]20/D 141.0±5.0°, c = 1% in ethanol
Water Solubility 
Insoluble in water. Slightly soluble in DMSO and methanol.
BRN 
3033982
CAS DataBase Reference
33125-05-2(CAS DataBase Reference)
More
Less

Safety Information

Safety Statements 
24/25
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29242990

MSDS

More
Less

Boc-D-Phenylglycine Usage And Synthesis

Chemical Properties

White powder

Uses

It is a reagent of choice for assignment of absolute configuration of chiral primary amines by 1H NMR, giving better results than Mosher's acid ((R)-(+)-?-Methoxy-?-(trifluoromethyl)-phenyl-acetic acid. αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is D-(+)-2-Phenylglycine with Boc protecting group. (αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is used as part of a catalyst combination to catalyze regioselective [4 + 2] cycloadditions of β-substituted cyclic enones and polyconjugated malononitriles. It can also be used to catalyze stereoselective preparation of polyfunctional nitrocyclohexene carboxaldehydes.

Boc-D-PhenylglycineSupplier

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Email
jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Email
market03@meryer.com
Alfa Aesar
Tel
400-6106006
Email
saleschina@alfa-asia.com
TAIYUAN RHF CO.,LTD.
Tel
+86 351 7031519
Email
sales@RHFChem.com
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Email
Sales-CN@TCIchemicals.com