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P(t-Bu)3 Pd G4

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P(t-Bu)3 Pd G4 Basic information

Product Name:
P(t-Bu)3 Pd G4
Synonyms:
  • P(t-Bu)3 Pd G4
  • Methanesulfonato(tri-t-butylphosphino)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II),[P(t-Bu)3 Palladacycle Gen. 4]
  • METHANESULFONATO(TRI-T-BUTYLPHOSPHINO)(2'-METHYLAMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),98%[P(T-BU)3PALLADACYCLEGEN.4]
  • P(t-Bu)3 Palladacycle Gen. 4
  • Methanesulfonato(tri-t-butylphosphino)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
  • P(t-Bu)3 Pd G4 / Methanesulfonato(tri-t-butylphosphino)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
  • Methanesulfonato(tri-t-butylphosphino)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) ISO 9001:2015 REACH
  • 1-biphenyl-2-yl)palladium(II)
CAS:
1621274-11-0
MF:
C26H45NO3P3PdS-3
MW:
651.046683
Mol File:
1621274-11-0.mol
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P(t-Bu)3 Pd G4 Chemical Properties

storage temp. 
2-8°C, protect from light, stored under nitrogen
form 
Powder
color 
tan to yellow
InChI
InChI=1S/C14H15N.3C4H10P.O3S.Pd/c1-11-7-3-4-8-12(11)13-9-5-6-10-14(13)15-2;3*1-4(2,3)5;1-4(2)3;/h3-10,15H,1-2H3;3*5H,1-3H3;;/q;4*-1;+1
InChIKey
JBZFBSFINJJLAH-UHFFFAOYSA-N
SMILES
CC1=CC=CC=C1C1=CC=CC=C1NC.[Pd-2](S([O-])(=O)=O)(PC(C)(C)C)(PC(C)(C)C)PC(C)(C)C
CAS DataBase Reference
1621274-11-0
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P(t-Bu)3 Pd G4 Usage And Synthesis

Reactions

  1. Alternative Pd-catalyzed cross-coupling reaction of s-BuB(OH)2 and 4-chloroanisole.
  2. Alternative Pd-catalyzed cross-coupling reaction of secondary alkylboronic acids and aryl chlorides.
  3. Alternative Pd-catalyzed cross-coupling reaction of secondary alkyltrifluoroborates and aryl chlorides

Chemical Properties

P(t-Bu)3 Pd G4 is a powder or crystalsis,it's stable, soluble in most organic solvents.

Uses

P(t-Bu)3 Pd G4 is a powerful ligand for classic cross-coupling reactions combined with the Buchwald Fourth Generation Palladacycle. Bench stable, soluble in most organic solvents.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

P(t-Bu)3 Pd G4Supplier

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