Basic information Safety Supplier Related

Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II)

Basic information Safety Supplier Related

Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II) Basic information

Product Name:
Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II)
Synonyms:
  • Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II)
  • PCy3 Pd G2
  • Tricyclohexylphosphine Pd G2
  • (SP-4-3)-[2'-(Amino)[1,1'-biphenyl]-2-yl]chloro(tricyclohexylphosphine)palladium
  • (SP-4-3)-[2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC]chloro(tricyclohexylphosphine)palladium
  • PCy3 Palladacycle Gen.2
  • Chloro[(tricyclohexylphosphine)(2'-aminobiphenyl-2-yl)palladium(II)
  • Chloro[(tricyclohexylphosphine)(2'-aminobiphenyl-2-yl)palladium(II) / PCy3 Pd G2
CAS:
1353658-81-7
MF:
C30H42ClNPPd+2
MW:
589.507941
Mol File:
1353658-81-7.mol
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Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II) Chemical Properties

Melting point:
244-246 °C
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
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Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II) Usage And Synthesis

Uses

PCy3 Pd G2 is a monophosphine-coordinated 2-phenylaniline-based palladacycle complex that can be used as a precatalyst:

  • To prepare diarylmethanes by Suzuki cross-coupling reaction with heterocyclic-chloromethyl derivatives with aryl/heteroaryl boronic acids.
  • To synthesize poly(arylene)s by the Suzuki cross-coupling polymerization reaction between aryl dihalides and aryldiboronic acids.
  • In the C-H bond functionalization reactions.

Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II)Supplier

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