Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II) Chemical Properties

Melting point:

244-246 °C

storage temp. 

2-8°C, protect from light, stored under nitrogen

form 

solid

InChIKey

YJEJUSIMNMMILB-UHFFFAOYSA-N

SMILES

C1(C2=CC=CC=C2N)=CC=CC=C1[Pd+2].P(C1CCCCC1)(C1CCCCC1)C1(Cl)CCCCC1

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26

Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II) Usage And Synthesis

Uses

PCy3 Pd G2 is a monophosphine-coordinated 2-phenylaniline-based palladacycle complex that can be used as a precatalyst:

• To prepare diarylmethanes by Suzuki cross-coupling reaction with heterocyclic-chloromethyl derivatives with aryl/heteroaryl boronic acids.
• To synthesize poly(arylene)s by the Suzuki cross-coupling polymerization reaction between aryl dihalides and aryldiboronic acids.
• In the C-H bond functionalization reactions.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: C-H Activation
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II)(1353658-81-7)Related Product Information

• CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
• CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)
• XantPhos-Pd-G2
• tBuXPhos-Pd-G3
• cataCXium A-Pd-G2
• Methanesulfonato(tricyclohexylphosphine)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) dichloroMethane adduct
• P(t-Bu)3 Pd G4
• Carbonylchlorohydrotris(triphenylphosphine)ruthenium
• Bis(cyclopentadienyl)anthracene (II)
• Potassium chloropalladite
• CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
• Carbonyldihydrotris(triphenylphosphine)ruthenium
• Bis(benzonitrile)palladium chloride
• Tris(triphenylphosphine)ruthenium(II) chloride
• Tetrakis(triphenylphosphine)nickel
• BIS(T-BUTYLCYCLOPENTADIENYL)TITANIUM DICHLORIDE
• XPhos Pd G2
• SPhos Pd G2