CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)
CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) Basic information
- Product Name:
- CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)
- Synonyms:
-
- 1,3-Bis(2,6-diisopropylphenyl)-2,3-dihydro-2-imidazolyl]copper(I) Chloride
- [1,3-Bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene](chloro)copper
- [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper chloride
- Chloro[1,3-bis(2,6-diisopropylphenyl)iMidazol-2-ylidene]copp
- [(iPr)CuCl]
- (1,3-Bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium-2-yl) copper chloride
- CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)
- Chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copper(I),98%
- CAS:
- 578743-87-0
- MF:
- C27H36ClCuN2*-
- MW:
- 487.58714
- Product Categories:
-
- Cu
- Catalysis and Inorganic Chemistry
- Chemical Synthesis
- Copper
- organometallic complex
- Mol File:
- 578743-87-0.mol
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CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) Chemical Properties
- Melting point:
- >300 °C
- storage temp.
- Inert atmosphere,Room Temperature
- form
- Powder
- color
- white
- Sensitive
- air sensitive
- InChI
- InChI=1S/C27H36N2.ClH.Cu/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;;/h9-16,18-21H,1-8H3;1H;/q;;+1/p-1
- InChIKey
- JPUFNIIPFXQOCB-UHFFFAOYSA-M
- SMILES
- N1(C=CN(C2C(=CC=CC=2C(C)C)C(C)C)C1=[Cu]Cl)C1=C(C=CC=C1C(C)C)C(C)C
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CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) Usage And Synthesis
Reaction
- Catalyst for the aziridination of olefins.
- Mild catalyst, superior to CuCl, in the methylenetriphenylphosphorane methyleneation of aldehydes and ketones.
- Copper(I) catalyzed alkylation of aryl and alkenylsilanes.
- Copper-catalyzed formal methylative and hydrogenative carboxylation of alkynes with carbon dioxide.
- Regioselective copper-catalyzed carboxylation of allylboronates with carbon dioxide.
- Carboxylation of organoboronic esters with potassium methyl carbonate under copper catalysis.
- Catalytic anti-Markovnikov hydrobromination of alkynes.
- Copper-catalyzed borylative cross-coupling of allenes and imines.
Uses
"Use for reduction of olefin and carbonyl, carbene transfer reaction, aziridination of olefins, and methyleneation of aldehydes."
reaction suitability
core: copper
reagent type: catalyst
CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)Supplier
Panjin Greenchem Technology Co., Ltd. Gold
- Tel
- 13121959385
- chemrocking@bjgreenchem.com
J & K SCIENTIFIC LTD.
- Tel
- 18210857532; 18210857532
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 4006356688 18621169109
- market03@meryer.com
TCI (Shanghai) Development Co., Ltd.
- Tel
- 021-67121386
- Sales-CN@TCIchemicals.com
Beijing HwrkChemical Technology Co., Ltd
- Tel
- 18515581800 18501085097
- sales.bj@hwrkchemical.com
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