Basic information Reaction Safety Supplier Related

CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)

Basic information Reaction Safety Supplier Related

CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) Basic information

Product Name:
CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)
Synonyms:
  • 1,3-Bis(2,6-diisopropylphenyl)-2,3-dihydro-2-imidazolyl]copper(I) Chloride
  • [1,3-Bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene](chloro)copper
  • [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper chloride
  • Chloro[1,3-bis(2,6-diisopropylphenyl)iMidazol-2-ylidene]copp
  • [(iPr)CuCl]
  • (1,3-Bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium-2-yl) copper chloride
  • CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)
  • Chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copper(I),98%
CAS:
578743-87-0
MF:
C27H36ClCuN2*-
MW:
487.58714
Product Categories:
  • Cu
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Copper
  • organometallic complex
Mol File:
578743-87-0.mol
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CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) Chemical Properties

Melting point:
>300 °C
storage temp. 
Inert atmosphere,Room Temperature
form 
Powder
color 
white
Sensitive 
air sensitive
InChIKey
JPUFNIIPFXQOCB-UHFFFAOYSA-M
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Safety Information

WGK Germany 
3
HS Code 
2933299090
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CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) Usage And Synthesis

Reaction

  1. Catalyst for the aziridination of olefins.
  2. Mild catalyst, superior to CuCl, in the methylenetriphenylphosphorane methyleneation of aldehydes and ketones.
  3. Copper(I) catalyzed alkylation of aryl and alkenylsilanes.
  4. Copper-catalyzed formal methylative and hydrogenative carboxylation of alkynes with carbon dioxide.
  5. Regioselective copper-catalyzed carboxylation of allylboronates with carbon dioxide.
  6. Carboxylation of organoboronic esters with potassium methyl carbonate under copper catalysis.
  7. Catalytic anti-Markovnikov hydrobromination of alkynes.
  8. Copper-catalyzed borylative cross-coupling of allenes and imines.



Uses

"Use for reduction of olefin and carbonyl, carbene transfer reaction, aziridination of olefins, and methyleneation of aldehydes."

CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)Supplier

ChemicalRIM Co., Ltd Gold
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15184345951
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chemicalRIM@gmail.com
Panjin Greenchem Technology Co., Ltd. Gold
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13121959385 13121959385
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chemrocking@bjgreenchem.com
J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
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jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
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021-61259108 18621169109
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market03@meryer.com
TCI (Shanghai) Development Co., Ltd.
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021-67121386
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Sales-CN@TCIchemicals.com