Basic information Reactions Safety Supplier Related

CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

Basic information Reactions Safety Supplier Related

CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Basic information

Product Name:
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
Synonyms:
  • (1,5-cyclooctadiene) (pentamethylcyclopentadiene) rubidium chloride
  • Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II),98%
  • Ruthenium,chloro[(1,2,5,6-h)-1,5-cyclooctadiene][(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]-
  • 1,5-Cyclooctadiene, ruthenium complex
  • Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium
  • Cp*RuCl(cod)
  • Chloro(1，5-cyclooctadiene)(pentamethylcyclopent...
  • Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
CAS:
92390-26-6
MF:
C18H27ClRu5*
MW:
379.93
Product Categories:
  • Ru
  • organometallic complex
Mol File:
92390-26-6.mol
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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Chemical Properties

Melting point:
143-147℃
storage temp. 
-20°C
color 
brown microxtls
Stability:
store cold
InChIKey
JBVMVFXUVNUNNG-ONEVTFJLSA-M
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Safety Information

Hazard Codes 
F
Risk Statements 
20/21/22-14/15
Safety Statements 
22-36/37/39-43
RIDADR 
UN 3395
WGK Germany 
3
TSCA 
No
HazardClass 
4.3
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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Usage And Synthesis

Reactions

  1. Catalyst for regio and stereo-specific ring opening via N-O bond cleavage.
  2. Catalyst for transformation of 1,6-enynes and diazoalkanes into alkenylbicyclo[3.1.0]hexane derivatives.
  3. Catalyst for ring closing enyne metathesis.
  4. Catalyst for [2 + 2 + 2] cocyclization of diene-yne, and cyclodimerization of allenynes.
  5. Catalyst for hydrovinylation of ynamides with ethylene.
  6. Catalyst for C–H insertion reactions of carbenes. 

Uses

Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.
It can be used:

  • To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides.
  • To catalyze C-C coupling of norbornenes and norbornadiene with alkynes?to form [2 + 2] cycloadducts.
  • In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols.
  • To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines.
  • To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.

CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)Supplier

Shanghai Incat Chemtech Co.,Ltd. Gold
Tel
021-57603038 13601791340
Email
307593986@qq.com
Shaanxi Rock New Materials Co., Ltd. Gold
Tel
0917-8888777, 3380777,18691786767; 15619786767
Email
xuya@bjrock.com
Panjin Greenchem Technology Co., Ltd. Gold
Tel
13121959385 13121959385
Email
chemrocking@bjgreenchem.com
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Email
jkinfo@jkchemical.com
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Email
sales.bj@hwrkchemical.com
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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)(92390-26-6)Related Product Information