CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Basic information
- Product Name:
- CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
- Synonyms:
-
- (1,5-cyclooctadiene) (pentamethylcyclopentadiene) rubidium chloride
- Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II),98%
- Ruthenium,chloro[(1,2,5,6-h)-1,5-cyclooctadiene][(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]-
- 1,5-Cyclooctadiene, ruthenium complex
- Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium
- Cp*RuCl(cod)
- Chloro(1，5-cyclooctadiene)(pentamethylcyclopent...
- Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
- CAS:
- 92390-26-6
- MF:
- C18H27ClRu5*
- MW:
- 379.93
- Product Categories:
-
- Ru
- organometallic complex
- Mol File:
- 92390-26-6.mol
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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Chemical Properties
- Melting point:
- 143-147℃
- storage temp.
- -20°C
- color
- brown microxtls
- Stability:
- store cold
- InChIKey
- JBVMVFXUVNUNNG-ONEVTFJLSA-M
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Safety Information
- Hazard Codes
- F
- Risk Statements
- 20/21/22-14/15
- Safety Statements
- 22-36/37/39-43
- RIDADR
- UN 3395
- WGK Germany
- 3
- TSCA
- No
- HazardClass
- 4.3
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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Usage And Synthesis
Reactions
- Catalyst for regio and stereo-specific ring opening via N-O bond cleavage.
- Catalyst for transformation of 1,6-enynes and diazoalkanes into alkenylbicyclo[3.1.0]hexane derivatives.
- Catalyst for ring closing enyne metathesis.
- Catalyst for [2 + 2 + 2] cocyclization of diene-yne, and cyclodimerization of allenynes.
- Catalyst for hydrovinylation of ynamides with ethylene.
- Catalyst for C–H insertion reactions of carbenes.
Uses
Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.
It can be used:
- To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides.
- To catalyze C-C coupling of norbornenes and norbornadiene with alkynes?to form [2 + 2] cycloadducts.
- In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols.
- To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines.
- To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)Supplier
Shanghai Incat Chemtech Co.,Ltd. Gold
- Tel
- 021-57603038 13601791340
- 307593986@qq.com
Domole Scientific Gold
- Tel
- 13275595566 15001012717
- domole.infsci@outlook.com
Shaanxi Rock New Materials Co., Ltd. Gold
- Tel
- 917-917-8888777 18691746767
- zhaoting@bjrock.com
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
BeiJing Hwrk Chemicals Limted
- Tel
- 0757-86329057 18501085097
- sales3.gd@hwrkchemical.com
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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)(92390-26-6)Related Product Information
- 1,5-Cyclooctadiene
- Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II)
- Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
- Chloro(1,5-cyclooctadiene)rhodium(I) dimer
- XPhos Pd G2
- RuPhos Pd G1 Methyl t--Butyl Ether Adduct
- CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
- SPhos Pd G2
- Chloro(1,5-cyclooctadiene)iridium(I) dimer
- SPhos Pd G1, Methyl t-Butyl Ether Adduct
- RuPhos Pd G2
- XPhos Pd G1
- Chloro(1,5-cyclooctadiene)methylpalladium(II) 97%
- Allylpalladium(II) Chloride Dimer
- CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)
- XantPhos-Pd-G2
- cataCXium A-Pd-G2
- Rubidium chloride