Basic information Reaction Safety Supplier Related

XPhos Pd G1

Basic information Reaction Safety Supplier Related

XPhos Pd G1 Basic information

Product Name:
XPhos Pd G1
Synonyms:
  • XPhos Palladacycle
  • XPhos precatalyst
  • [2-(2-AMinoethyl)phenyl](chloro)palladiuM-dicyclohexyl(2',4',6'-triisopropyl-2-biphenylyl)phosphine (1:1)
  • Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II)
  • XPhos Pd G1
  • Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)[2-(2-aminoethyl)phenyl] palladium(II) methyl-t-butylether adduct
  • XPhos Pd
  • Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)[2-(2-aminoethyl)phenyl] palladium(II) methyl-t-butylether adduct, min. 98% [XPhos Palladacycle Gen. 1]
CAS:
1028206-56-5
MF:
C41H59ClNPPd
MW:
738.77
EINECS:
633-034-5
Product Categories:
  • Buchwald Ligands&Precatalysts
  • Buchwald Precatalysts Series
  • Pd
Mol File:
1028206-56-5.mol
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XPhos Pd G1 Chemical Properties

Melting point:
205-210°C
form 
Powder
color 
white
CAS DataBase Reference
1028206-56-5
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38-52/53
Safety Statements 
26-61
WGK Germany 
3
HS Code 
2843909000
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XPhos Pd G1 Usage And Synthesis

Reaction

  1. Catalyst for cross-coupling reactions of electron-deficient anilines with aryl chlorides.
  2. Catalyst for rapid C-N bond-forming process at low catalyst loading.
  3. Catalyst for C-N cross-coupling reactions, at or below room temperature.
  4. Catalyst for the synthesis of tetracyclic indoles via intermolecular α-arylation of ketones.
  5. Catalyst for the cross-coupling of benzyl chlorides with cyclopropanol-derived ketone homoenolates


Uses

XPhos Pd G1 is used as androgen receptor modulator for treatment of disorders including prostate cancer.

Uses

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Catalyst used for:

  • Amination / cyclization reactions
  • C-N bond-forming reactions via packed-bed microreactors
  • Boration of aryl chlorides
  • Arylation of oxazole
  • Cross-coupling reactions

Preparation

XPhos Pd G1 is an insoluble solid that can be prepared by cross-coupling reactions of imidazole derivatives with dioxane. 

General Description

Material may contain up to 5% pentane

Physiological effects

XPhos Pd G1 has been shown to have anti-infectious properties against bacteria and viruses including influenza A, respiratory syncytial virus (RSV), human immunodeficiency virus (HIV), and hepatitis B. It also has metabolic effects on the body by reducing levels of pyridine compounds and increasing pyrazolyl concentrations in the blood stream. 

XPhos Pd G1Supplier

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