CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Basic information
- Product Name:
- CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
- Synonyms:
-
- C9H7RuCl2(C18H15P)
- Reaxys ID: 11961247
- CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)R&
- Chloro(indenyl)bis(triphenylphosphine)ruthenium(II),dichloromethaneadduct,min.98%
- Chloro(indenyl)bis(triphenylphosphine)rutheniuM(II),dichloroMethane adduct,98%
- Ruthenium,chloro[(1,2,3,3a,7a-h)-1H-inden-1-yl]bis(triphenylphosphine)-
- Chloro(indenyl)bis(triphenylphosphine)ruthenium(II) may contain <=1 molar equivalent dichloromethane/acetone
- CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II),DICHLOROMETHANEADDUCT,MIN.
- CAS:
- 99897-61-7
- MF:
- C45H37ClP2Ru5*
- MW:
- 776.25
- Product Categories:
-
- Ru
- organometallic complexes
- Mol File:
- 99897-61-7.mol
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CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Chemical Properties
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- crystal
- color
- red-brown
- InChI
- 1S/2C18H15P.C9H7.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-5-9-7-3-6-8(9)4-1;;/h2*1-15H;1-7H;1H;/q;;;;+1/p-1
- InChIKey
- AUSVTIHCDLKYHV-UHFFFAOYSA-M
- SMILES
- Cl[Ru].[CH]1[CH][C]2C=CC=C[C]2[CH]1.c3ccc(cc3)P(c4ccccc4)c5ccccc5.c6ccc(cc6)P(c7ccccc7)c8ccccc8
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Safety Information
- Hazard Codes
- Xn
- Risk Statements
- 36/37/38-40
- Safety Statements
- 26-36/37/39-36/37
- WGK Germany
- WGK 3
- TSCA
- No
- Storage Class
- 11 - Combustible Solids
- Hazard Classifications
- Carc. 2
Eye Irrit. 2
Skin Irrit. 2
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CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Usage And Synthesis
Uses
Catalyst for:
- Single-chain folding of polymers
- Domino redox bicycloisomerization
- Selective radical addition with a designed heterobifunctional halide
- Tandem living radical polymerization via in situ monomer transformation with alcohols
- Atom-economical synthesis of nitrogen heterocycles
Reactant for the synthesis of chiral-at-metal ruthenium allenylidene complexes
reaction suitability
core: ruthenium
reagent type: catalyst
CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)Supplier
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CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)(99897-61-7)Related Product Information
- Chloro(1,5-cyclooctadiene)rhodium(I) dimer
- XPhos Pd G2
- RuPhos Pd G1 Methyl t--Butyl Ether Adduct
- SPhos Pd G2
- CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
- Chloro(1,5-cyclooctadiene)iridium(I) dimer
- SPhos Pd G1, Methyl t-Butyl Ether Adduct
- RuPhos Pd G2
- XPhos Pd G1
- CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
- CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II),DICHLOROMETHANE ADDUCT