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Piperonyloyl chloride

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Piperonyloyl chloride Basic information

Product Name:
Piperonyloyl chloride
Synonyms:
  • BUTTPARK 154\04-36
  • 3,4-(METHYLENEDIOXY)BENZOYL CHLORIDE
  • TIMTEC-BB SBB003720
  • PIPERONYLOYL CHLORIDE
  • 1,3-BENZODIOXOLE-5-CARBONYL CHLORIDE
  • Benzo[d][1,3]dioxole-5-carbonyl chloride
  • 1,3-Benzodioxole-5-carbonyl chloride (9CI)
  • Piperonoyl chloride
CAS:
25054-53-9
MF:
C8H5ClO3
MW:
184.58
Product Categories:
  • ACIDHALIDE
  • Acid Halides
  • Carbonyl Compounds
  • Organic Building Blocks
  • Acid Halides
  • Building Blocks
  • Carbonyl Compounds
  • Chemical Synthesis
  • Organic Building Blocks
Mol File:
25054-53-9.mol
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Piperonyloyl chloride Chemical Properties

Melting point:
78-79 °C (lit.)
Boiling point:
155 °C/25 mmHg (lit.)
Density 
1.3964 (estimate)
storage temp. 
Hygroscopic, Refrigerator, under inert atmosphere
solubility 
Chloroform (Slightly)
form 
Crystalline Powder
color 
Off-white to blue-gray
Stability:
Moisture Sensitive, reacts with Moisture in the air
CAS DataBase Reference
25054-53-9(CAS DataBase Reference)
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Safety Information

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
22-26-27-28-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
Hazard Note 
Corrosive
HazardClass 
8
PackingGroup 
III
HS Code 
29329900

MSDS

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Piperonyloyl chloride Usage And Synthesis

Chemical Properties

off-white to blue-grey crystalline powder

Uses

Piperonyloyl chloride is suitable for use in a kinetic study to evaluate the solvolysis rate constants of piperonyloyl chloride in 27 different solvents. It may be used in the synthesis of the following compounds:

  • 2-phenylbenzimidazoles
  • (Z)-3-hydroxy-1-(5-methoxy-2,2-dimethyl-2H-chromen-6-yl)-3-phenylprop-2-en-1-one
  • pongapinone A
  • 2-((1-(2-(N-(4-chlorophenyl)benzo[d][1,3]dioxole-5-carboxamido)ethyl)piperidin-4-yl)oxy)acetic acid phosphoric acid salt, inhibitor of platelet aggregation
  • justicidin B, the piscicidal components of Justicia Hayatai var. decumbens
  • piperazine derivatives

General Description

Piperonyloyl chloride is an acyl halide. It participates in the preparation of starting reagent (N-acyl indole), required for the synthesis of pyrrolophenanthridone alkaloids. Kinetic study of the solvolysis of piperonyloyl chloride in various pure and binary solvent mixtures has been proposed. Solvolysis reaction has been reported to proceed via electron-rich acyl transfer mechanism.

Piperonyloyl chloride Preparation Products And Raw materials

Raw materials

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