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4-(Methylthio)phenylboronic acid

Basic information Safety Supplier Related

4-(Methylthio)phenylboronic acid Basic information

Product Name:
4-(Methylthio)phenylboronic acid
Synonyms:
  • (4-thiomethoxyphenyl)boronic acid
  • 4-(Methylsulfanyl)phenylboronic acid, 95%, May contain varying aMounts of anhydride
  • Boronic acid, B-[4-(methylthio)phenyl]-
  • THIOANISOLE-4-BORONIC ACID
  • RARECHEM AH PB 0130
  • P-(METHYLTHIO)PHENYLBORONIC ACID
  • 4-(Methylthio)phenylboronic acid 4-Thioanisoleboronic acid
  • 4-(Methylthiophenyl)boronicacid,min.97%
CAS:
98546-51-1
MF:
C7H9BO2S
MW:
168.02
Product Categories:
  • Aryl Boronic Acids
  • Boronic Acids and Derivatives
  • B (Classes of Boron Compounds)
  • organic or inorganic borate
  • Chemical Synthesis
  • Monosubstituted Aryl Boronic Acids
  • Azoles
  • blocks
  • BoronicAcids
  • Boric Acid
  • Boronic acids
  • Boronic Acid
  • Aryl
  • Organoborons
  • Organometallic Reagents
  • Boronate Ester
  • Potassium Trifluoroborate
Mol File:
98546-51-1.mol
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4-(Methylthio)phenylboronic acid Chemical Properties

Melting point:
210-214 °C (lit.)
Boiling point:
333.5±44.0 °C(Predicted)
Density 
1.22±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
soluble in Methanol
pka
8.56±0.10(Predicted)
form 
Crystalline Powder
color 
Off-white
BRN 
3247219
CAS DataBase Reference
98546-51-1(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26-36-7/9
WGK Germany 
3
TSCA 
No
HazardClass 
IRRITANT
HS Code 
29163990

MSDS

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4-(Methylthio)phenylboronic acid Usage And Synthesis

Chemical Properties

Off-white crystalline powder

Uses

Reactant involved in:

  • Suzuki-Miyaura cross coupling reactions with 2-aryl-1-bromo-1-nitroethenes or alkynyl bromides
  • Addition reactions with naphthyridine N-oxides
  • Oxyarylation of Heck reaction intermediates for synthesis of THF derivatives
  • Sulfoxidation reactions
  • Copper-catalyzed halogenation

4-(Methylthio)phenylboronic acid Preparation Products And Raw materials

Preparation Products

Raw materials

4-(Methylthio)phenylboronic acidSupplier

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