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ChemicalBook >  Product Catalog >  Chemical Reagents >  Organic reagents >  aliphatic ketones >  2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIENONE

2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIENONE

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2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIENONE Basic information

Product Name:
2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIENONE
Synonyms:
  • 2,5-Cyclohexadien-1-one, 2,4,4,6-tetrabromo-
  • 2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIEN-1-ONE
  • 2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIENONE
  • 2,4,4,6-tetrabromocyclohexa-2,5-dienone
  • 2,2,4,4-Tetrabromo-2,5-Cyclohexadienone
  • 2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIENONE, 90+%
  • 2,4,4,6-Tetrabromo-2,5-cyclohexadien-1-one95%
  • 2,4,4,6-TetrabroMo-2,5-cyclohexadien-1-one, 95% 5GR
CAS:
20244-61-5
MF:
C6H2Br4O
MW:
409.7
EINECS:
243-638-7
Product Categories:
  • Bromination
  • Halogenation
  • Synthetic Organic Chemistry
  • C3 to C6
  • Carbonyl Compounds
  • Ketones
Mol File:
20244-61-5.mol
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2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIENONE Chemical Properties

Melting point:
120-127 °C
Boiling point:
365.8±42.0 °C(Predicted)
Density 
2.6462 (rough estimate)
refractive index 
1.5000 (estimate)
storage temp. 
2-8°C
form 
Liquid
color 
Clear colorless
Water Solubility 
Insoluble in water.
BRN 
2048028
CAS DataBase Reference
20244-61-5(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HS Code 
29147000

MSDS

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2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIENONE Usage And Synthesis

Chemical Properties

orange to brown fine crystalline powder

Uses

2,4,4,6-Tetrabromo-2,5-cyclohexadienone was used as catalyst for efficient deoxygenation of sulfoxides to their corresponding sulfides with 1,3-dithiane. It was also used as reagent for conversion of alcohols to azides.

General Description

2,4,4,6-Tetrabromo-2,5-cyclohexadienone forms solid charge-transfer molecular complexes with 4-(aminomethyl)piperidine and their spectroscopic characteristics were studied.

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