cataCXium A Pd G3 Chemical Properties

Melting point:

196-241 °C (decomposition)

storage temp. 

under inert gas (nitrogen or Argon) at 2–8 °C

form 

Powder

color 

off-white

InChI

InChI=1S/C24H39P.C12H9N.CH4O3S.Pd/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h17-22H,2-16H2,1H3;1-6,8-9,13H;1H3,(H,2,3,4);/q;-2;;+2

InChIKey

VIYNMTFDXQNMCC-UHFFFAOYSA-N

SMILES

P(C12CC3CC(CC(C3)C1)C2)(C12CC3CC(CC(C3)C1)C2)([Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C)CCCC

cataCXium A Pd G3 Usage And Synthesis

Reaction

Precatalyst for the palladium-catalyzed cross-coupling of cesium trifluoroborate salts with aryl halides.

Uses

cataCXium^? A Pd G3 is a Buchwald third generation precatalyst that can be used in:

• Direct ortho-arylation of pyridinecarboxylic acids.
• Catalyzing Suzuki–Miyaura cross-coupling in the synthesis of 1-heteroaryl-3-azabicyclo[3.1.0]hexanes.
• Palladium-catalyzed carbonylative carboperfluoroalkylation of alkynes.
• Suzuki–Miyaura coupling reaction of geminal bis(boryl)cyclopropanes in the synthesis of various gem-disubstituted cyclopropanes.

cataCXium A Pd G3(1651823-59-4)Related Product Information

• MorDalPhos Pd G4
• XPhos Pd G4
• Xantphos Pd G3
• BrettPhos Pd G3
• t-BuXphos Palladacycle Gen. 4
• Methanesulfonato 2-dicyclohexylphosphino-2-(N,N-dimethylamino)biphenyl(2′-amino-1,1′-biphenyl-2-yl) palladium(II)
• Methanesulfonate(2-Dicyclohexylphosphino-2'-methyl)(2'-Amino-1,1'-Biphenyl-2-Yl)Palladium(II) (Mephos Pd G3)
• QPhos Pd G3
• VPhos Pd G4
• RockPhos Pd G3
• RuPhos Palladacycle Gen. 4
• SPhos Pd G3
• EPhos Pd G4
• XantPhos Pd G4
• Methanesulfonato(triphenylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) (PPH3 PD G3)
• APhos Pd G3
• DavePhos-Pd-G3
• t-BuBrettPhos Palladacycle Gen. 3