DavePhos-Pd-G3
DavePhos-Pd-G3 Basic information
- Product Name:
- DavePhos-Pd-G3
- Synonyms:
-
- Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-diMethylaMino)-1,1'-biphenyl](2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) CH2Cl2 adduct, Min. 98% [DavePhos Palladacycle]
- DavePhos-Pd-G3 AldrichCPR
- DavePhos-Pd-G3 95%
- Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) CH2Cl2 adduct
- METHANESULFONATO[2-(DICYCLOHEXYLPHOSPHINO)-2'-(N,N-DIMETHYLAMINO)-1,1'-BIPHENYL](2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II)CH2CL2ADDUCT,MIN.98%[DAVEPHOSPALLADACYCLEGEN.3]
- [2-(dicyclohexylphosphino)-2-(N,N-dimethylamino)-1,1-biphenyl]-2-(2-amino-1,1-biphenyl)]palladium(II) methanesulfonate
- Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) CH2Cl2 adduct,[DavePhos Palladacycle Gen. 3]
- Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-diMethylaMino)-1,1'-biphenyl](2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) CH2Cl2 adduct [DavePhos Palladacycle]
- CAS:
- 1445085-87-9
- MF:
- C39H49N2O3PPdS
- MW:
- 763.29
- Product Categories:
-
- Buchwald Ligands&Precatalysts
- Buchwald Precatalysts Series
- Pd
- Mol File:
- 1445085-87-9.mol
DavePhos-Pd-G3 Chemical Properties
- Melting point:
- 183-200°C (decomp)
- storage temp.
- 2-8°C, protect from light, stored under nitrogen
- form
- Powder
- color
- white
- InChIKey
- LPLXTNDHFXGKKB-UHFFFAOYSA-N
- SMILES
- P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C=CC=CC=1N(C)C)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C
DavePhos-Pd-G3 Usage And Synthesis
Uses
Pd precatalyst for cross-coupling
General Description
DavePhos-Pd-G3 is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. They are versatile catalysts. They have long life in solutions and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
DavePhos-Pd-G3Supplier
- Tel
- 02763499399 13797220777
- lpbchem@163.com
- Tel
- 15690792173
- sales@runvmat.com
- Tel
- 131-21959385 18804271668
- chemrocking@bjgreenchem.com
- Tel
- 18210857532; 18210857532
- jkinfo@jkchemical.com
- Tel
- 18515581800 18501085097
- sales.bj@hwrkchemical.com
DavePhos-Pd-G3(1445085-87-9)Related Product Information
- cataCXium A Pd G3
- APhos Pd G3
- SPhos Palladacycle Gen. 4
- XPhos Pd G4
- Xantphos Pd G3
- BrettPhos Pd G3
- XPhos Pd G2
- RuPhos Pd G1 Methyl t--Butyl Ether Adduct
- SPhos Pd G2
- BrettPhosPalladacycle
- Palladacycle Gen. 3
- t-BuXphos Palladacycle Gen. 4
- RuPhos Palladacycle Gen. 4
- t-BuBrettPhos Palladacycle Gen. 3
- SPhos Pd G3
- SPhos Pd G1, Methyl t-Butyl Ether Adduct
- RuPhos Pd G2
- tBuXPhos Pd G1