Basic information Safety Supplier Related

(2R)-(-)-GLYCIDYL 4-NITROBENZOATE

Basic information Safety Supplier Related

(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Basic information

Product Name:
(2R)-(-)-GLYCIDYL 4-NITROBENZOATE
Synonyms:
  • (2r)-(-)-(2,3-epoxypropylester)-4-nitrobenzoate
  • 4-nitrobenzoate,(r)-oxiranemethano
  • (R)-(-)-GLYCIDYL-4-NITROBENZOATE
  • (2R)-(-)-GLYCIDYL 4-NITROBENZOATE
  • GLYCIDYL4-NITROBENZOATE
  • (R)-(-)-Oxirane-2-methanol 4-nitrobenzoate
  • (R)-(-)-Glycidyl 4-nitrobenzoate, (R)-(-)-Oxirane-2-methanol 4-nitrobenzoate
  • 2-Oxiranemethanol, 2-(4-nitrobenzoate), (2R)-
CAS:
106268-95-5
MF:
C10H9NO5
MW:
223.18
Mol File:
106268-95-5.mol
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(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Chemical Properties

Melting point:
60-62 °C (lit.)
storage temp. 
2-8°C
optical activity
[α]19/D 37°, c = 1.08 in chloroform
BRN 
5278590
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
RTECS 
RR0511000
F 
10-21

MSDS

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(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Usage And Synthesis

Uses

(2R)-(?)-Glycidyl 4-nitrobenzoate can be used as a starting material in the total synthesis of leukotriene B4.

Purification Methods

Purify glycidol by fractional distillation.The 4-nitrobenzoates have m 56o (±); m 60-62o, [] D20 -37.9o (c 3.38 CHCl3) for R-(-)-isomer [106268-95-5];m 60-62o, [] D20 +38o (c 1 CHCl3) for the S-(+)-isomer [115459-65-9] and are recrystallised from Et2O or Et2O/pet ether (b 40-60o) [S-isomer: Burgos et al. J Org Chem 52 4973 1987, Sowden & Fischer J Am Chem Soc 64 1291 1942.] [Beilstein 17 I 50, 17 III/IV 985, 17/3 V 9.]

(2R)-(-)-GLYCIDYL 4-NITROBENZOATESupplier

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