1-METHOXY-1,4-CYCLOHEXADIENE Chemical Properties

Boiling point:

148-150 °C (lit.)

Density 

0.94 g/mL at 25 °C (lit.)

refractive index 

n20/D 1.475(lit.)

Flash point:

98 °F

form 

liquid

color 

Clear, almost colourless to faint yellow

BRN 

1925467

Safety Information

Risk Statements 

10

Safety Statements 

16

RIDADR 

UN 1993 3/PG 3

WGK Germany 

3

HazardClass 

3.2

PackingGroup 

III

HS Code 

2909200090

MSDS

• Language:English Provider:SigmaAldrich

1-METHOXY-1,4-CYCLOHEXADIENE Usage And Synthesis

Uses

1-Methoxycyclohexa-1,4-diene is used in process for preparation of Ruthenium(0) Arene α-Diimine complexes as precursors for vapor and solution deposition of Ruthenium films.

Synthesis Reference(s)

The Journal of Organic Chemistry, 43, p. 4555, 1978 DOI: 10.1021/jo00417a045

General Description

1-Methoxy-1,4-cyclohexadiene reacts with RuCl₃·xH₂O in an alcohol solvent to give [RuCl₂(η⁶-C₆H₅OR)₂ (R = Me, Et or HOCH₂CH₂).

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