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9-Bromo-9-phenylfluorene

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9-Bromo-9-phenylfluorene Basic information

Product Name:
9-Bromo-9-phenylfluorene
Synonyms:
  • 9-BROMO-9-PHENYL-9H-FLUORENE
  • 9-BROMO-9-PHENYLFLUORENE
  • AKOS 91526
  • 9-Bromo-9-phenylfluorene,97%
  • 9-Bromo-9-phenylfluorene ,98%
  • 9-Phenylfluorenyl BroMide
  • NSC 28079
  • (9-Bromo-9H-fluoren-9-yl)benzene
CAS:
55135-66-5
MF:
C19H13Br
MW:
321.21
EINECS:
628-283-1
Product Categories:
  • Intermediates
  • Aromatics Compounds
  • Fluorenes
  • Fluorenes & Fluorenones
  • Protection & Derivatization Reagents (for Synthesis)
  • Synthetic Organic Chemistry
  • Chiral Compound
  • Aromatics
  • Aryl
  • C13 to C37+
  • Halogenated Hydrocarbons
Mol File:
55135-66-5.mol
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9-Bromo-9-phenylfluorene Chemical Properties

Melting point:
99-101 °C (lit.)
Boiling point:
394.3±41.0 °C(Predicted)
Density 
1.425±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
Water Solubility 
Insoluble in water
solubility 
soluble in Chloroform, Dichloromethane, Ether, Ethyl Acetate, Methanol
form 
powder to crystal
color 
Light orange to Yellow to Green
BRN 
2561445
InChIKey
HYQXNCDBSALQLB-UHFFFAOYSA-N
CAS DataBase Reference
55135-66-5(CAS DataBase Reference)
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Safety Information

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-27-28-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
HazardClass 
8
PackingGroup 
II
HS Code 
29039930

MSDS

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9-Bromo-9-phenylfluorene Usage And Synthesis

Chemical Properties

Yellow Crystalline Solid

Uses

A bulky amine protecting reagent reported to be 6000 times more stable to acid than the trityl group

Uses

9-Bromo-9-phenylfluorene may be used in the preparation of:

  • N-(9-(9-phenylfluorenyl))-L-alaninal
  • N-(9-phenylfluoren-9-yl)-L-serine
  • 1-hydroxypyrazoles priotected at the oxygen atom

General Description

Solvolysis of 9-bromo-9- phenylfluorene has been reported to proceed via limiting SN1 mechanism.

9-Bromo-9-phenylfluorene Preparation Products And Raw materials

Raw materials

9-Bromo-9-phenylfluoreneSupplier

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