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Methyl 4-methoxysalicylate

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Methyl 4-methoxysalicylate Basic information

Product Name:
Methyl 4-methoxysalicylate
Synonyms:
  • RARECHEM AL BF 0038
  • METHYL 2-HYDROXY-4-METHOXYBENZOATE
  • METHYL 4-METHOXYSALICYLATE
  • 2-HYDROXY-4-METHOXY-BENZOIC ACID METHYL ESTER
  • Benzoic acid, 2-hydroxy-4-methoxy-, methyl ester
  • 2-Hydroxy-4-methoxybenzoic acid methyl ester~Methyl 4-methoxysalicylate
  • ASISCHEM Z67646
  • 4-METHOXYSALICYLIC ACID METHYL ESTER
CAS:
5446-02-6
MF:
C9H10O4
MW:
182.17
EINECS:
226-657-5
Product Categories:
  • Building Blocks
  • C8 to C9
  • Carbonyl Compounds
  • Chemical Synthesis
  • Esters
  • Organic Building Blocks
  • Aromatic Esters
Mol File:
5446-02-6.mol
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Methyl 4-methoxysalicylate Chemical Properties

Melting point:
50-53 °C (lit.)
Boiling point:
134°C 7mm
Density 
1.1634 (rough estimate)
refractive index 
1.4600 (estimate)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Crystalline Powder or Crystals
pka
9.38±0.10(Predicted)
color 
White to light yellow
Water Solubility 
Soluble in acetone. Insoluble in water.
BRN 
2691644
InChIKey
ZICRWXFGZCVTBZ-UHFFFAOYSA-N
LogP
2.430 (est)
CAS DataBase Reference
5446-02-6(CAS DataBase Reference)
NIST Chemistry Reference
Methyl 4-methoxysalicylate(5446-02-6)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39-24/25
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29189900

MSDS

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Methyl 4-methoxysalicylate Usage And Synthesis

Chemical Properties

white to light yellow crystalline powder

Uses

Methyl 4-methoxysalicylate (methyl 2-hydroxy-4-methoxybenzoate) was used in the enantioselective synthesis of (+)-coriandrone A and B, two bioactive natural products.

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