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ChemicalBook >  Product Catalog >  Chemical Reagents >  Organic reagents >  Phosphine ligand >  (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE

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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE Basic information

Product Name:
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE
Synonyms:
  • (R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYLAMINO)-PHENYLMETHYL]-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE
  • (S,S)-(-)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-BIS(DI(3,5-DIMETHYLPHENYL)PHOSPHINO)FERROCENE
  • MANDYPHOS SL-M009-1
  • (aR,aR)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis[di(3,5-xylyl)phos
  • (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE
  • (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(di(3,5-dimethylphenyl)phosphino)ferrocene,min.97%
  • (r,r)-1,1'-bis[(r)-α-(dimethylamino)-phenylmethyl]-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene (acc to cas)
  • (αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene
CAS:
793718-16-8
MF:
C60H66FeN2P210*
MW:
932.97
Product Categories:
  • Chiral Phosphine
  • Ferrocene Series
  • Mandyphos Series
Mol File:
793718-16-8.mol
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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE Chemical Properties

form 
Powder
color 
orange
Stability:
store cold
CAS DataBase Reference
793718-16-8
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Safety Information

WGK Germany 
3
HS Code 
29319090
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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE Usage And Synthesis

Reaction

  1. Ligand for Rh-catalyzed asymmetric hydrogenation of α-acetamidoacrylates.
  2. Ligand for Rh-catalyzed hydrogenation of α- and β-enamides, acrylic acid derivatives, itaconates, β-ketoesters and 1,3- diketones.
  3. Ligand for Rh-catalyzed asymmetric hydrogenation of furyl-substituted (Z)-dehydroamino acid derivatives.
  4. Ligand for Ir-catalyzed asymmetric transfer hydrogenation of ketones.
  5. Ligand for Cu-catalyzed enantioselective hydroboration of α- and β-unsaturated esters and nitriles.

Chemical Properties

Orange powder

General Description

sold in collaboration with Solvias AG

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENESupplier

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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE(793718-16-8)Related Product Information