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Isopropylmagnesium chloride lithium chloride complex

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Isopropylmagnesium chloride lithium chloride complex Basic information

Product Name:
Isopropylmagnesium chloride lithium chloride complex
Synonyms:
  • ISOPROPYLMAGNESIUM CHLORIDE-LITHIUM CHLORIDE
  • ISOPROPYLMAGNESIUM CHLORIDE - LITHIUM CHLORIDE COMPLEX
  • Isopropylmagnesium chloride - Lithium chloride complex, ca 14% solution in THF
  • Isopropylmagnesium chloride - Lithium chloride complexca. 14% solution in THFAcroSeal§3
  • Isopropylmagnesium Chloride - Lithium Chloride (15% in Tetrahydrofuran, ca. 1mol/L) (This product is only available for selling domestically in Japan.)
  • Isopropylmagnesium chloride - Lithium chloride complex,1.3M solution in THF
  • Isopropylmagnesium chloride - Lithium chloride complex, 1.3M solution in THF, AcroSeal§3
  • ISOPROPYLMAGNESIUM CHLORIDE - LITHIUMCHLORIDE(1:1), ABT. 14% IN THF
CAS:
745038-86-2
MF:
C3H7Cl2Mg.Li
MW:
145.24
Mol File:
745038-86-2.mol
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Isopropylmagnesium chloride lithium chloride complex Chemical Properties

Density 
1.05
Flash point:
-17 °C
storage temp. 
Flammables area
form 
Solution
color 
Clear yellow to brown to gray
Sensitive 
air sensitive, moisture sensitive
InChI
InChI=1S/C3H6.2ClH.Li.Mg/c1-3-2;;;;/h1-2H3;2*1H;;/q-1;;;+1;+2/p-2
InChIKey
GFRAKTLEBRSDFT-UHFFFAOYSA-L
SMILES
[C-](C)(C)[Mg+2]([Cl-])[Cl-].[Li+]
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Safety Information

Hazard Codes 
C-F,C,F
Risk Statements 
34-19-14/15-11-40-37
Safety Statements 
7/8-45-43B-36/37/39-33-16-43-26
RIDADR 
UN 3399BC 4.3(3) / PGII
WGK Germany 
3
HazardClass 
4.3, 3
HS Code 
29319090

MSDS

  • Language:English Provider:ACROS
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Isopropylmagnesium chloride lithium chloride complex Usage And Synthesis

Chemical Properties

Clear brown solution

Uses

Isopropylmagnesium chloride lithium chloride complex is a reagent for Selective Metalations. And it was used with CH3MgCl/LiCl to affect magnesium-halogen exchange on unprotected aryl carboxylic acids.

Hazard

Isopropylmagnesium chloride lithium chloride complex is a highly flammable liquid and vapor, it is harmful if swallowed, it causes severe skin burns and eye damage.

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