Basic information Safety Supplier Related

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

Basic information Safety Supplier Related

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Basic information

Product Name:
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
Synonyms:
  • Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium (1:1)
  • 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
  • 2,2,6,6-TetraMethylpiperidinylMagnesiuM chloride lithiuM chloride coMplex solution 1.0 M in THF/toluene
  • 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
  • piperidinyL
  • Magnesate(1-), dichloro(2,2,6,6-tetramethylpiperidinato)-, lithium (1:1)
  • lithium,magnesium,2,2,6,6-tetramethylpiperidin-1-ide,dichloride
  • Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium
CAS:
898838-07-8
MF:
C9H18Cl2LiMgN
MW:
242.4
Product Categories:
  • Chemical Synthesis
  • Grignard Reagents
  • Heteroaryl
  • Organometallic Reagents
Mol File:
898838-07-8.mol
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2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Chemical Properties

Density 
0.96g/mLat 25℃
Flash point:
-15°C
storage temp. 
2-8°C
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Safety Information

Hazard Codes 
F,C
Risk Statements 
63-11-14-19-34-37-40
Safety Statements 
16-26-36/37/39-45
RIDADR 
UN 3399 4.3/PG 1
WGK Germany 
3
HS Code 
29333990
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2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Usage And Synthesis

Uses

2,2,6,6-Tetramethylpiperidinylmagnesium Chloride Lithium Chloride Complex is used in preparation of Pyridazinones as herbicides. Also, used in preparation of MCL-1 inhibitors useful for treatment of cancer.

Uses

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.

Uses

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex deprotonations using Knochel-Hauser-Base

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