TOLU BALSAM Chemical Properties

Melting point:

55-60 °C(lit.)

FEMA 

3069 | TOLU, BALSAM, EXTRACT (MYROXYLON SPP.)

Odor

at 100.00 %. sweet balsamic amber fruity

Odor Type

balsamic

EPA Substance Registry System

Balsams, tolu (9000-64-0)

Safety Information

Hazard Codes 

Xi

Risk Statements 

43

Safety Statements 

36

WGK Germany 

3

RTECS 

CP2355000

Toxicity

skn-rbt 500 mg/24H MLD FCTXAV 14,689,76

MSDS

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TOLU BALSAM Usage And Synthesis

Chemical Properties

Tolu balsam resinoid is produced by extraction of the balsam of M. balsamum (L.) Harms var. balsamum and M. balsamum (L.) Harms var. genuinum (Fabaceae), which grow, for example, in Brazil or Venezuela. It is a dark orangebrownmass with a sweet, resinous, long-lasting odor, reminiscent of hyacinth. An essential oil is also distilled from the balsam.
Tolu balsam resinoid contains a fairly large amount of benzyl and cinnamyl esters of benzoic and cinnamic acid.
Both the resinoid and the balsam are used in perfumery, mainly for their fixative properties.

Chemical Properties

See Tolu Balsam (Gum).

Chemical Properties

Tolu balsam is a luxuriant, tall tree reaching more than 20 m (65 ft) in height; it usually grows in the northern part of South America (Magdalena River Valley and Nueva Granada region in Venezuela). The balsam consists of the plant exudate oozing from incisions made on the trunk. The fluid gum that exudes through capillary conduits in the tree is collected in cups placed at different heights along the trunk. The balsam is a semisolid plastic mass, brown or brownish-yellow, with a sweet, aromatic, persistent odor reminiscent of vanilla. Aging and climatic conditions strongly affect the appearance of the balsam. In addition to hardening, the balsam becomes friable with a glassy, clean cleavage on aging. The part used is the balsam exudate. Tolu balsam has an agreeable, sweet, lasting odor similar to hyacinth.

Physical properties

The balsam can be steam-distilled, yielding 2 to 7% oil. It is a viscous, pale-yellow to lightorange oil with a pleasant, sweet, resinous odor reminiscent of hyacinth.

Occurrence

In the tree of Myroxylon balsamum, also known as M. toluiferum L. Harms (Fam. Leguminosae) (Guenther. 1952).

Uses

resinous material from Myroxylon samum used as perfume fixative; in soap perfumery; vehicle for cough mixtures; expectorant; antiseptic

Definition

Extractives and their physically modified derivatives. It consists primarily of resins, essential oils, and usually cinnamic and benzoic acids. (Myroxylon balsamum, Leguminosae).

Preparation

By the tapping of the tree. M. balsamum L. Harms (Guenther, 1952).

Safety Profile

A mild skin irritant. When heatedto decomposition it yields toxic and irritating fumes andsmoke.

Metabolism

The absorption and excretion of balsams such as balsam tolu has been reviewed by LeNouene (1966). Benzoic and cinnamic acids, which are major components of balsam tolu, are excreted in the urine, chiefly as hippuric acid.

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