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Tetrahydrofurfuryl acrylate

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Tetrahydrofurfuryl acrylate Basic information

Product Name:
Tetrahydrofurfuryl acrylate
Synonyms:
  • sartomer285
  • sartomer302
  • sr285
  • viscoat150
  • TETRAHYDROFURFURYL ACRYLATE
  • Tetrahydrofurfurylacrylate,tech.90%,stab.with500ppmhydroquinone
  • 2-Propenoic acid, tetrahydrofurfuryl este
  • TETRAHYDROFURFURYL ACRYLATE: TECH., 90%, STABILIZED WITH 500PPM HYDROQUINONE
CAS:
2399-48-6
MF:
C8H12O3
MW:
156.18
EINECS:
219-268-7
Product Categories:
  • AcrylateSelf Assembly&Contact Printing
  • Fluorine-Containing Monomers for 157 nm UV Lithography Resist PolymersBuilding Blocks
  • Acrylic Monomers
  • Furans
  • Heterocyclic Building Blocks
  • Lithography Monomers
  • Monomers
Mol File:
2399-48-6.mol
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Tetrahydrofurfuryl acrylate Chemical Properties

Boiling point:
87 °C/9 mmHg (lit.)
Density 
1.064 g/mL at 25 °C (lit.)
vapor pressure 
1.19hPa at 25℃
refractive index 
n20/D 1.46(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Soluble in water
form 
clear liquid
color 
Colorless to Almost colorless
Water Solubility 
79.1g/L at 20.9℃
BRN 
113115
InChIKey
YNXCGLKMOXLBOD-UHFFFAOYSA-N
LogP
0.81 at 21.7℃
CAS DataBase Reference
2399-48-6(CAS DataBase Reference)
EPA Substance Registry System
Tetrahydrofurfuryl acrylate (2399-48-6)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/38
Safety Statements 
26
RIDADR 
3334
WGK Germany 
3
RTECS 
UD3670893
TSCA 
Yes
HazardClass 
9
HS Code 
29321900

MSDS

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Tetrahydrofurfuryl acrylate Usage And Synthesis

Uses

Tetrahydrofurfuryl acrylate may be used as an acrylic matrix for silver nanoparticles/polymer nanocomposites . It can form copolymers with butadiene. Prior to transfer printing, cellulosic and proteinic fibers are grafted with THFA.

Uses

Tetrahydrofurfuryl acrylate (THFA) can be used to prepare bio-based photopolymers. A series of thermostable shape memory photopolymers were synthesised from a mixture of two bio-based monomers, THFA and tridecyl methacrylate, with the addition of a small amount of 1,3-benzodithiol. Ethyl phenylphosphonate (2,4,6 trimethylbenzoyl) was used as a photoinitiator. The biorenewable carbon content of these photopolymers ranged from (63.7-74.9) %. The increase in THFA content in the photocured resins increased the light curing rate, increased the stiffness, and improved the mechanical and thermal properties of the obtained polymers. The developed bio-based photopolymers could replace petroleum-derived thermostable shape memory polymer analogues in a wide range of applications[1].

Hazard

A moderate skin irritant.

Safety

Tetrahydrofurfuryl acrylate is a contact irritant affecting the skin, eyes, and mucous membranes and may cause sensitization through skin contact in certain individuals. If swallowed, it causes irritation of the gastrointestinal tract, causing nausea and vomiting.

References

[1] JUSTINAS JARAS; Jolita O; Aukse Navaruckiene. Thermoresponsive Shape-Memory Biobased Photopolymers of Tetrahydrofurfuryl Acrylate and Tridecyl Methacrylate.[J]. Materials, 2023. DOI:10.3390/ma16062156.

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