ALLYLDIPHENYLPHOSPHINE Chemical Properties

Boiling point:

194-200 °C/15 mmHg (lit.)

Density 

1.049 g/mL at 25 °C (lit.)

refractive index 

n20/D 1.619(lit.)

Flash point:

>230 °F

storage temp. 

2-8°C, protect from light, stored under nitrogen

form 

Liquid

color 

Colorless

Water Solubility 

Soluble in most organic solvents. Insoluble in water.

Sensitive 

Air Sensitive

InChI

1S/C15H15P/c1-2-13-16(14-9-5-3-6-10-14)15-11-7-4-8-12-15/h2-12H,1,13H2

InChIKey

PDDYFPPQDKRJTK-UHFFFAOYSA-N

SMILES

C=CCP(c1ccccc1)c2ccccc2

Safety Information

Hazard Codes 

Xi,Xn

Risk Statements 

36/37/38-20/21/22

Safety Statements 

26-27-28-36/37/39-39-37-36

RIDADR 

UN3278

WGK Germany 

3

HazardClass 

6.1

PackingGroup 

III

HS Code 

29310099

Storage Class

10 - Combustible liquids

Hazard Classifications

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

ALLYLDIPHENYLPHOSPHINE Usage And Synthesis

Chemical Properties

Colorless to light yellow liqui

Uses

Cocatalyst in palladium catalyzed hydrocarboxylation reactions. Cocatalyst in Palladium catalyzed cross-coupling reactions. Ligand for hydroformylation catalysts. Ligand for the rhenium phosphinoborane pendant Lewis acid-assisted reductive coupling reactions. Catalyst precursor for alkene hydroboration.

Uses

Allyldiphenylphosphine is used as a cocatalyst in palladium catalyzed hydrocarboxylation reactions, cocatalyst in Palladium catalyzed cross-coupling reactions, ligand for hydroformylation catalysts, ligand for the rhenium phosphinoborane pendant Lewis acid-assisted reductive coupling reactions, catalyst precursor for alkene hydroboration.

Uses

• Cocatalyst in palladium catalyzed hydrocarboxylation reactions
• Cocatalyst in Palladium catalyzed cross-coupling reactions
• Ligand for hydroformylation catalysts
• Ligand for the rhenium phosphinoborane pendant Lewis acid-assisted reductive coupling reactions
• Catalyst precursor for alkene hydroboration

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

ALLYLDIPHENYLPHOSPHINE(2741-38-0)Related Product Information

• ALLYLDIPHENYLPHOSPHINE OXIDE
• 1-allylhydrazine hydrochloride
• DIETHYL ALLYLPHOSPHONATE
• Allyl methyl carbonate
• Dimethyl allylmalonate
• Allyl Benzyl Ether
• Allylbenzene
• Diethyl allylmalonate
• ALLYLUREA
• Allyltrimethylsilane
• Methyl allyl disulfide
• ALLYLTRIISOPROPYLSILANE
• allyltrimethylammonium chloride
• ALLYLDIMETHYLCHLOROSILANE
• 2-Allyloxyethanol
• Sodium allylsulfonate
• POTASSIUM ALLYLTRIFLUOROBORATE
• Allyltrimethoxysilane