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DIETHYL ALLYLPHOSPHONATE

Basic information Safety Supplier Related

DIETHYL ALLYLPHOSPHONATE Basic information

Product Name:
DIETHYL ALLYLPHOSPHONATE
Synonyms:
  • DIETHYL(PROP-1(E)-ENYL)PHOSPHONATE
  • DIETHYL(PROP-2-(E)-ENYL)PHOSPHONATE
  • DIETHYL-(ALLYLPHOSPHONAT)
  • DIETHYL ALLYLPHOSPHONATE
  • DIETHYL-(2-PROPENYL)-PHOSPHONAT
  • DIETHYL(2-PROPENYL)PHOSPHONATE
  • DIETHYL (1-PROPENYL)PHOSPHONATE
  • AURORA KA-1466
CAS:
1067-87-4
MF:
C7H15O3P
MW:
178.17
EINECS:
619-646-5
Product Categories:
  • C-C Bond Formation
  • Horner-Wadsworth-Emmons Reagents
  • Olefination
Mol File:
1067-87-4.mol
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DIETHYL ALLYLPHOSPHONATE Chemical Properties

Boiling point:
46 °C/0.35 mmHg (lit.)
Density 
1,035 g/cm3
vapor pressure 
55.2Pa at 25℃
refractive index 
n20/D 1.4340(lit.)
Flash point:
224 °F
form 
Liquid
color 
Clear colorless
LogP
1.33 at pH7
Surface tension
56.4-60.9mN/m at 1g/L and 19℃
CAS DataBase Reference
1067-87-4(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29319090

MSDS

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DIETHYL ALLYLPHOSPHONATE Usage And Synthesis

Chemical Properties

clear colorless liquid

Uses

Reactant for:

  • Copolymerization of phosphonated allyl monomers and maleic anhydride
  • Enantioselective synthesis of solamin type mono-THF acetogenins
  • RCM reaction yielding oxaphospholene and oxaphosphinene heterocycles
  • Synthesis of spongistatin 2 using Wittig coupling
  • Stereoselective synthesis of pentacyclic furanosteroids
  • Preparation of protected polyhydroxylated β -amino acid constitutents of microsclerodermins

Synthesis Reference(s)

Synthetic Communications, 22, p. 2219, 1992 DOI: 10.1080/00397919208019075
Synthesis, p. 563, 1986 DOI: 10.1055/s-1986-31704

DIETHYL ALLYLPHOSPHONATESupplier

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