ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Esters > Butyl Ester compounds > tert-Butyl N-hydroxycarbamate
tert-Butyl N-hydroxycarbamate
tert-Butyl N-hydroxycarbamate Basic information
- Product Name:
- tert-Butyl N-hydroxycarbamate
- Synonyms:
-
- N-Boc-hydroxylamine, >=98%
- N-tert-Butoxycarbonylhydroxylamine, 98+%
- N-(tert-Butoxycarbonyl)hydroxylamine~tert-ButylN-hydroxycarbamate
- N-(T-BUTOXYCARBONYL)-HYDROXYLAMINE
- N-T-BOC HYDROXYLAMINE
- N-HYDROXYCARBAMIC ACID TERT-BUTYL ESTER
- N-BOC-HYDROXYLAMINE
- TERT-BUTYL N-HYDROXYCARBAMATE 99.0%
- CAS:
- 36016-38-3
- MF:
- C5H11NO3
- MW:
- 133.15
- EINECS:
- 252-836-2
- Product Categories:
-
- Hydroxylamines
- Hydroxylamines (N-Substituted)
- INTERMEDIATESOFMEROPENAM
- API intermediates
- Naphthyridine,Quinoline
- 1
- Mol File:
- 36016-38-3.mol
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tert-Butyl N-hydroxycarbamate Chemical Properties
- Melting point:
- 53-55 °C (lit.)
- Boiling point:
- 245.66°C (rough estimate)
- Density
- 1.2510 (rough estimate)
- refractive index
- 1.4120 (estimate)
- storage temp.
- 2-8°C
- solubility
- Chloroform, Methanol
- pka
- 9.31±0.23(Predicted)
- form
- Crystalline Powder
- color
- White to light pink
- Water Solubility
- Slightly soluble in water.
- Sensitive
- Moisture Sensitive
- BRN
- 1756546
- CAS DataBase Reference
- 36016-38-3(CAS DataBase Reference)
MSDS
- Language:English Provider:N-Boc-hydroxylamine
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
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tert-Butyl N-hydroxycarbamate Usage And Synthesis
Chemical Properties
White to light pink crystalline powder
Uses
N-Boc-hydroxylamine is used in the preparation of azridines by cycloaddition of azides with nitroso Diels-Alder adducts. It acts as a reagent for the synthesis of hydroxylamine derivatives t-butyl-N-(acyloxy)carbamates and N,O-diacylated N-hydroxyarylsulfonamides.
Uses
tert-Butyl N-hydroxycarbamate is used in the preparation of azridines by cycloaddition of azides with nitroso Diels-Alder adducts.
Synthesis Reference(s)
Journal of the American Chemical Society, 81, p. 955, 1959 DOI: 10.1021/ja01513a049
Tetrahedron Letters, 24, p. 231, 1983 DOI: 10.1016/S0040-4039(00)81372-6
tert-Butyl N-hydroxycarbamateSupplier
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tert-Butyl N-hydroxycarbamate(36016-38-3)Related Product Information
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