ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Rare-Earth Metal > (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) Basic information
- Product Name:
- (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)
- Synonyms:
-
- (1R,2R)-(-)-N,N'-BIS(3,5-DI-T-BUTYLSALICYDENE)-1,2-CYCLOHEXANEDIAMINOCOBALT(II)
- (1R,2R)-(-)-1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)COBALT(II)
- (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
- CyclohexanediaminoNNbisditbutylsalicylidene
- (R,R)-(-)-N,N'-BIS(3,5-DI-T-BUTYLSALICYL ID -ENE)-1,2-CYCLOHEXANEDIAMINOCOBALT(II
- (1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)cobalt(II)
- (1r,2r)-(-)-1,2-cyclohexanediamino-n,n'-bis(3,5- di-t-butylsalicylidene)cobalt
- (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)
- CAS:
- 176763-62-5
- MF:
- C36H52CoN2O2
- MW:
- 603.74
- Product Categories:
-
- Jacobsen Metal
- Co
- Kinetic ResolutionChiral Catalysts, Ligands, and Reagents
- Asymmetric Synthesis
- Chiral Catalysts, Ligands, and Reagents
- fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis
- Privileged Ligands and Complexes
- SALENs
- Mol File:
- 176763-62-5.mol
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(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) Chemical Properties
- Melting point:
- >350 °C(lit.)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- form
- Powder
- color
- Orange to red to brown
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Safety Information
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 36/37/39-26
- WGK Germany
- 3
- HS Code
- 29349990
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
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(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) Usage And Synthesis
Reaction
- Catalyst used in the kinetic resolution of racemic, terminal epoxides yielding a chiral diol and the unreacted enantiomer of the epoxide.
- Precursor to a Co(III) catalyst for the kinetic resolution of terminal epoxides with alcohols.
- Desymmetrization of meso-epoxides with carboxylic acids and fluoride.
- Catalyst for asymmetric cyclopropanation of styrene.
- Catalyst for copolymerization of CO2 and epoxides.
- Enantioselective intramolecular openings of oxetanes.
Chemical Properties
Orange to red-brown powder
Uses
Catalyst for the hydrolytic kinetic resolution of terminal epoxides and the enantioselective ring opening of meso epoxides.
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)Supplier
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(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)(176763-62-5)Related Product Information
- 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride
- BIS(3 5 3' 5'-DIMETHOXYDIBENZYLIDENEACE&
- SPhos Pd G2
- ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98
- DICHLORO(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)PALLADIUM(II)
- RuPhos Pd G2
- Cobalt
- (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)
- N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE
- (1R,2R)-(-)-1,2-Diaminocyclohexane
- (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)
- (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE
- SALCOMINE
- N,N'-BIS(SALICYLIDENE)-1,2-PROPANEDIAMINE
- DIBENZYLIDENE ETHYLENEDIAMINE
- N-benzylidenecyclohexylamine
- N,N'-BIS(SALICYLIDENE)-1,6-HEXANEDIAMINE
- CIS/TRANS-DISALYCYLIDENE-1,2-CYCLOHEXYLIDENEDIAMINE