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4-NITROPHENYL-ALPHA-D-GALACTOPYRANOSIDE

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4-NITROPHENYL-ALPHA-D-GALACTOPYRANOSIDE Basic information

Product Name:
4-NITROPHENYL-ALPHA-D-GALACTOPYRANOSIDE
Synonyms:
  • alpha-d-galactopyranoside,4-nitrophenyl
  • 4-NITROPHENYL-ALPHA-D-GALACTOPYRANOSIDE
  • PNP-ALPHA-D-GAL
  • PNP ALPHA-D-GALACTOPYRANOSIDE
  • PNP-ALPHA-GAL
  • PNPG
  • P-NITROPHENYL A-D-GALACTOPYRANOSIDE
  • P-NITROPHENYL ALPHA-D-GALACTOPYRANOSIDE
CAS:
7493-95-0
MF:
C12H15NO8
MW:
301.25
EINECS:
231-343-6
Product Categories:
  • substrate
  • Enzyme substrates
  • 13C & 2H Sugars
  • Biochemistry
  • Galactose
  • Carbohydrates & Derivatives
  • Substrates
  • Glycosides
  • Sugars
Mol File:
7493-95-0.mol
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4-NITROPHENYL-ALPHA-D-GALACTOPYRANOSIDE Chemical Properties

Melting point:
166-169 °C
Boiling point:
582.2±50.0 °C(Predicted)
Density 
1.599±0.06 g/cm3(Predicted)
refractive index 
239 ° (C=1, H2O)
storage temp. 
-20°C
solubility 
Methanol (Slightly), Water (Slightly)
pka
12.55±0.70(Predicted)
form 
Solid
color 
White to Off-White
BRN 
92214
InChIKey
IFBHRQDFSNCLOZ-IIRVCBMXSA-N
LogP
-0.550 (est)
CAS DataBase Reference
7493-95-0(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
22-24/25-36-26
WGK Germany 
3
3-10-21
HS Code 
29400090

MSDS

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4-NITROPHENYL-ALPHA-D-GALACTOPYRANOSIDE Usage And Synthesis

Chemical Properties

Off-White Crystalline Solid

Uses

p-Nitrophenyl α-D-Galactopyranoside (cas# 7493-95-0) is a compound useful in organic synthesis.

Definition

ChEBI: An alpha-D-galactopyranoside having a 4-nitrophenyl substituent at the anomeric position.

Purification Methods

Purify 4-nitrophenyl--D-galactopyranoside by recrystallisation from H2O or aqueous EtOH. The monohydrate has m 85o which resolidifies and melts again at 151-152o (the hemihydrate), then resolidifies again and melts at 173o to give the anhydrous form. Drying the monohydrate at 60o yields the hemihydrate, and drying at 100o gives the anhydrous compound. The tetraacetate has m 147o after drying at 100o. [Jermyn Aust J Chem 15 569 1962, Helfreich & Jung Justus Liebigs Ann Chem 589 77 1954.] It is a substrate for galactosidase [Dangelmaier & Holmsen Anal Biochem 104 182 1980]. [Beilstein 17/7 V 55.]

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