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4-Acetylphenylboronic acid

Basic information Safety Supplier Related

4-Acetylphenylboronic acid Basic information

Product Name:
4-Acetylphenylboronic acid
Synonyms:
  • RARECHEM AH PB 0162
  • P-ACETYLPHENYLBORONIC ACID
  • TIMTEC-BB SBB000146
  • 4-ACETYLPHENYLBORONIC ACID
  • 4-ACETYLBENZENEBORONIC ACID
  • ACETOPHENONE-4-BORONIC ACID
  • AKOS BRN-0001
  • Boronic acid, (4-acetylphenyl)- (9CI)
CAS:
149104-90-5
MF:
C8H9BO3
MW:
163.97
EINECS:
629-086-3
Product Categories:
  • Boronate Ester
  • Potassium Trifluoroborate
  • B (Classes of Boron Compounds)
  • Boronic Acids
  • Boronic Acids
  • Boronic Acids and Derivatives
  • ACETYLGROUP
  • blocks
  • BoronicAcids
  • Boronic Acid series
  • Boronic Acid
  • Acetyl
  • Aryl
  • Organoborons
  • bc0001
Mol File:
149104-90-5.mol
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4-Acetylphenylboronic acid Chemical Properties

Melting point:
240-244 °C(lit.)
Boiling point:
354.2±44.0 °C(Predicted)
Density 
1.19±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly)
form 
Crystalline Powder
pka
7.58±0.10(Predicted)
color 
Pale yellow to yellow
Water Solubility 
25 g/L
BRN 
7869162
CAS DataBase Reference
149104-90-5(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
Hazard Note 
Irritant/Keep Cold
HazardClass 
IRRITANT
HS Code 
29310095

MSDS

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4-Acetylphenylboronic acid Usage And Synthesis

Chemical Properties

white to light yellow crystal powder

Uses

suzuki reaction

Uses

Reactant involved in:

  • Palladium-catalyzed decarboxylative coupling
  • Copper-catalyzed hydroxylation
  • Palladium-catalyzed Suzuki-Miyaura cross-coupling
  • Cross-coupling with α-bromocarbonyl compounds
  • Oxidation catalyzed by Baeyer-Villiger monooxygenases
  • 1,5-substitution reactions

Uses

4-Acetylphenylboronic acid4-Acetylphenylboronic Acid is used in several metal catalyzed cross-coupling reaction studies.

General Description

4-Acetylphenylboronic acid is a boronate, belongs to a class of synthetic organic compounds. It reacts rapidly with peroxynitrite (ONOO(-)) to form stable hydroxy derivatives. It undergoes Suzuki coupling with 4-bromotriphenylamine catalyzed by dichlorobis(triphenylphosphine)Pd(II), during the synthesis of dendrimers.

4-Acetylphenylboronic acid Preparation Products And Raw materials

Raw materials

4-Acetylphenylboronic acidSupplier

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