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1-Amino-7-naphthol

Basic information Safety Supplier Related

1-Amino-7-naphthol Basic information

Product Name:
1-Amino-7-naphthol
Synonyms:
  • CYANOL
  • 8-AMINO-2-NAPHTHOL
  • 8-AMINO-2-NAPHTOL
  • 7-HYDROXY-1-NAPHTHYLAMINE
  • 8-Amino-2-hydroxynaphthalene
  • 2-Naphthalenol, 8-aMino-
  • 8-Amino-2-hydroxynaphthalene 98%
  • 8-AMino-2-naphthol, 94% 5GR
CAS:
118-46-7
MF:
C10H9NO
MW:
159.18
EINECS:
204-252-4
Product Categories:
  • Organic Building Blocks
  • Oxygen Compounds
  • Phenols
  • Building Blocks
  • C9 to C20+
  • Chemical Synthesis
  • Intermediates of Dyes and Pigments
  • Anilines, Aromatic Amines and Nitro Compounds
  • Organic Building Blocks
  • Oxygen Compounds
Mol File:
118-46-7.mol
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1-Amino-7-naphthol Chemical Properties

Melting point:
206-210 °C(lit.)
Boiling point:
284.68°C (rough estimate)
Density 
1.1202 (rough estimate)
refractive index 
1.6070 (estimate)
solubility 
soluble in Methanol
form 
Powder or Crystals
pka
pK1: 4.20(+1) (25°C)
color 
Gray to brown
Water Solubility 
slightly soluble
Sensitive 
Light Sensitive
CAS DataBase Reference
118-46-7(CAS DataBase Reference)
EPA Substance Registry System
2-Naphthalenol, 8-amino- (118-46-7)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
2
RTECS 
QL3331000
TSCA 
Yes
HS Code 
29222990

MSDS

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1-Amino-7-naphthol Usage And Synthesis

Chemical Properties

grey to grey-brown granular powder

Uses

Sulfonation gives 1-amino-7-hydroxynaphthalene-4-sulfonic acid. The N-acetyl derivative is an important coupling component for after-chrome and metal-complex dyes, e.g., C.I. Mordant Black 38 and C.I. Acid Black 60.

Production Methods

The sodium salt of 1-aminonaphthalene-7-sulfonic acid is added to 80 % potassium hydroxide at 210℃, and the reaction is completed by heating for 6 h at 230℃. After dilution and careful acidification with hydrochloric acid, the acid solution is screened to remove impurities and neutralized to precipitate 159 in 80 % yield (mp 207℃).

1-Amino-7-naphthol Preparation Products And Raw materials

Preparation Products

Raw materials

1-Amino-7-naphtholSupplier

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