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Perfluorobutyl iodide

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Perfluorobutyl iodide Basic information

Product Name:
Perfluorobutyl iodide
Synonyms:
  • PERFLUOROBUTYL IODODE
  • Nonafluoro-1-iodobutane,1-Iodoperfluorobutane, Perfluorobutyl iodide
  • 1-Iodoperfluorobutane, 1,1,1,2,2,3,3,4,4-Nonafluoro-4-iodobutane
  • 1-Iodoperfluorobutane, Perfluorobutyl iodide
  • Perfluorobutyl iodide,99%
  • PERFLUOROBUTYL IODIDE (STABILISED WITH S
  • Nonafluoro-1-iodobutane 98%
  • Perfluorobutyl iodide (stabilised with silver platelets) for synthesis
CAS:
423-39-2
MF:
C4F9I
MW:
345.93
EINECS:
207-025-8
Product Categories:
  • Alkyl
  • Building Blocks
  • Chemical Synthesis
  • Fluorinated Building Blocks
  • F-Tagged
  • Halogenated Hydrocarbons
  • Organic Fluorides
  • Fluorous Chemistry
  • Fluorous Compounds
  • Synthetic Organic Chemistry
  • Organic Building Blocks
  • Organic Fluorinated Building Blocks
Mol File:
423-39-2.mol
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Perfluorobutyl iodide Chemical Properties

Melting point:
-88 °C
Boiling point:
66-67 °C
Density 
2.01 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.3285(lit.)
Flash point:
None
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
Liquid
Specific Gravity
2.010
color 
Clear purple
Water Solubility 
immiscible
Sensitive 
Light Sensitive
BRN 
1777546
Exposure limits
ACGIH: TWA 0.01 ppm
Stability:
Stable. Incompatible with bases.
InChIKey
PGRFXXCKHGIFSV-UHFFFAOYSA-N
CAS DataBase Reference
423-39-2(CAS DataBase Reference)
NIST Chemistry Reference
1-Iodononafluorobutane(423-39-2)
EPA Substance Registry System
Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo- (423-39-2)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
RIDADR 
2810
WGK Germany 
3
RTECS 
EK5360000
8
Hazard Note 
Irritant/Light Sensitive
TSCA 
T
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29034700

MSDS

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Perfluorobutyl iodide Usage And Synthesis

Description

Perfluorobutyl iodide (PFBI) is a promising alternative to chlorofluorocarbon solvents used in aircraft ground maintenance operations and other military and commercial operations because it cleans well, has zero ozone depletion potential, and has extremely low global warming properties. Perfluorobutyl iodides also could used as gain media for a solar-pumped laser amplifier. This compound is usually utilized as perfluoroalkyl radical precursors[1–3].

Chemical Properties

clear colourless liquid with pungent odour

Uses

Perfluorobutyl Iodide is used as an organocatalyst in some polymerization reactions.

References

[1] Darol Dodd, Colin Hardy, Gary Hoffman. "Perfluoro-n-butyl iodide: acute toxicity, subchronic toxicity and genotoxicity evaluations. " International Journal of Toxicology 23 4 (2004): 249–58.
[2] J. Lee, B. Tabibi, W. Weaver. "Perfluorobutyl iodides as gain media for a solar-pumped laser amplifier." Optics Communications 67 1 (1988): 435–440.
[3] Zhang, Juan et al. "Perfluorobutyl iodide-assisted direct cyanomethylation of azoles and phenols with acetonitrile?." RSC Advances 26 (2015): 20562–20565.

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