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Bromomethyl methyl ether

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Bromomethyl methyl ether Basic information

Product Name:
Bromomethyl methyl ether
Synonyms:
  • METHOXYMETHYL BROMIDE
  • BROMOMETHYL METHYL ETHER
  • Bromo(methoxy)methane
  • bromomethoxy-methan
  • Ether, bromomethyl methyl
  • Methane, bromomethoxy-
  • BROMOMETHYL METHYL ETHER, TECH., 90%
  • BMME~Methoxymethylbromide
CAS:
13057-17-5
MF:
C2H5BrO
MW:
124.96
Product Categories:
  • Ethers
  • Organic Building Blocks
  • Oxygen Compounds
Mol File:
13057-17-5.mol
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Bromomethyl methyl ether Chemical Properties

Boiling point:
87 °C (lit.)
Density 
1.531 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.456(lit.)
Flash point:
80 °F
storage temp. 
2-8°C
solubility 
Chloroform (Soluble), Methanol (Slightly)
form 
clear liquid
Specific Gravity
1.531
color 
Colorless to Light yellow to Light orange
Water Solubility 
Sparingly soluble in water.
Sensitive 
Moisture Sensitive
BRN 
1730853
CAS DataBase Reference
13057-17-5(CAS DataBase Reference)
NIST Chemistry Reference
Bromomethyl methyl ether(13057-17-5)
EPA Substance Registry System
Methane, bromomethoxy- (13057-17-5)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
10-20/21/22-36/37/38-40
Safety Statements 
26-36/37
RIDADR 
UN 1992 3/PG 3
WGK Germany 
3
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
29091990

MSDS

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Bromomethyl methyl ether Usage And Synthesis

Chemical Properties

Colorless liquid

Uses

Bromomethyl methyl ether is used as reagent for protection of OH groups as their methoxymethyl (MOM) ethers. It is used in enantiocontrolled synthesis of intermediate containing carbons 18 to 35 of the macrocyclic immunosuppressant FK-506. It was used in the synthesis of 1-methoxymethyl-4-tritylthio-2-azetidinone.

Uses

Bromomethyl methyl ether was used in enantiocontrolled synthesis of intermediate containing carbons 18 to 35 of the macrocyclic immunosuppressant FK-506. It was used in the synthesis of 1-methoxymethyl-4-tritylthio-2-azetidinone.

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