ChemicalBook > CAS DataBase List > 2,4,6-Tris(bromomethyl)mesitylene
2,4,6-Tris(bromomethyl)mesitylene
Uses- Product Name
- 2,4,6-Tris(bromomethyl)mesitylene
- CAS No.
- 21988-87-4
- Chemical Name
- 2,4,6-Tris(bromomethyl)mesitylene
- Synonyms
- JACS-21988-87-4;Einecs 244-697-1;2,4,6-Tris(bromometh;2,4,6-Tris(brommethyl)mesitylen;2,4,6-TRIS(BROMOMETHYL)MESITYLENE;2,4,6-Tris(bromomethyl)mesitylene 98%;2,4,6-Tribromomethyl-1,3,5-trimethylbenzene;1,3,5-tris(brommethyl)-2,4,6-trimethylbenzol;1,3,5-TRI(BROMOMETHYL)-2,4,6-TRIMETHYLBENZENE;2,4,6-Trimethyl-1,3,5-tris(bromomethyl)benzene
- CBNumber
- CB0218395
- Molecular Formula
- C12H15Br3
- Formula Weight
- 398.96
- MOL File
- 21988-87-4.mol
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2,4,6-Tris(bromomethyl)mesitylene Property
- Melting point:
- 187-189 °C (lit.)
- Boiling point:
- 399.8±37.0 °C(Predicted)
- Density
- 1.759±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- powder to crystal
- color
- White to Almost white
- InChI
- InChI=1S/C12H15Br3/c1-7-10(4-13)8(2)12(6-15)9(3)11(7)5-14/h4-6H2,1-3H3
- InChIKey
- BHIFXIATEXVOQA-UHFFFAOYSA-N
- SMILES
- C1(CBr)=C(C)C(CBr)=C(C)C(CBr)=C1C
- CAS DataBase Reference
- 21988-87-4(CAS DataBase Reference)
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Safety
- Hazard Codes
- C,Xi
- Risk Statements
- 20/21/22-34
- Safety Statements
- 22-26-27-36/37/39-45
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
- Hazard Note
- Irritant
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 2903998090
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 388467
- Product name
- 2,4,6-Tris(bromomethyl)mesitylene
- Purity
- 98%
- Packaging
- 5g
- Price
- $114
- Updated
- 2025/07/31
TCI Chemical
- Product number
- T1641
- Product name
- 1,3,5-Tris(bromomethyl)-2,4,6-trimethylbenzene
- Packaging
- 5G
- Price
- $148
- Updated
- 2025/07/31
TCI Chemical
- Product number
- T1641
- Product name
- 1,3,5-Tris(bromomethyl)-2,4,6-trimethylbenzene
- Packaging
- 25G
- Price
- $371
- Updated
- 2025/07/31
TRC
- Product number
- T886498
- Product name
- 2,4,6-Tris(bromomethyl)mesitylene
- Packaging
- 500mg
- Price
- $110
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- HCH0015615
- Product name
- 1,3,5-TRI(BROMOMETHYL)-2,4,6-TRIMETHYLBENZENE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $600.79
- Updated
- 2021/12/16
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2,4,6-Tris(bromomethyl)mesitylene Chemical Properties,Usage,Production
Uses
2,4,6-Tribromomethyltrimethylbenzene is used as an organic building block and a general reagent.
Synthesis
50-00-0
108-67-8
21988-87-4
Under nitrogen atmosphere, 1,3,5-trimethylbenzene (0.7 mL, 5 mmol) was added to the reaction vial, followed by the sequential addition of acetic acid (2.6 mL) and 33% wt solution of hydrobromic acid acetic acid (3.5 mL). Next, paraformaldehyde (570 mg, 18.8 mmol, 3.7 equiv) was added. The reaction mixture was stirred at 95 °C. After 3 h, the solid was observed to start precipitating. Stirring of the reaction mixture was continued for 9 h, followed by cooling to room temperature. The reaction mixture was poured into ice water and the solid product was collected by filtration and dried. Recrystallization by mixed solvent recrystallization of dichloromethane and petroleum ether afforded the target compound 2,4,6-tribromomethyltrimethylbenzene as white needle-like crystals (1.99 g, 5 mmol, 99% yield).1H NMR (500 MHz, CDCl3) δ 4.61 (s, 6H), 2.50 (s, 9H).13C NMR (126 MHz, CDCl3) δ 137.84, 133.18, 29.93, 15.38.
References
[1] Journal of Organic Chemistry, 1993, vol. 58, # 5, p. 1262 - 1263
[2] Patent: WO2018/106112, 2018, A1. Location in patent: Page/Page column 70
[3] Synthesis, 1994, # 11, p. 1132 - 1132
[4] Organic Letters, 2009, vol. 11, # 11, p. 2229 - 2232
[5] Tetrahedron Letters, 2013, vol. 54, # 8, p. 771 - 774
2,4,6-Tris(bromomethyl)mesitylene Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2,4,6-Tris(bromomethyl)mesitylene manufacturers
Henan Fengda Chemical Co., Ltd
- Product
- 2,4,6-Tris(bromomethyl)mesitylene 21988-87-4
- Price
- US $100.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-26
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- 2,4,6-Tris(bromomethyl)mesitylene 21988-87-4
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-11
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- 1,3,5-Tris(bromomethyl)-2,4,6-trimethylbenzene 21988-87-4
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
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