Methyl 3-(bromomethyl)benzoate

Product Name: Methyl 3-(bromomethyl)benzoate
CAS No.: 1129-28-8
Chemical Name: Methyl 3-(bromomethyl)benzoate
Synonyms: TIMTEC-BB SBB005793;METHYL ALPHA-BROMO-M-TOLUATE;M-CARBOMETHOXYBENZYL BROMIDE;3-CARBOMETHOXYBENZYL BROMIDE;Methyl 3-(bromomethyl)benzoat;METHYL 3-(BROMOMETHYL)BENZOATE;Methyle3-(bromomethyl)benzoate;Methyl 3-aMino-4-fluorobezoate;Methyl m-(Bromomethyl)benzoate;3-(BROMOMETHYL)PHENYLACETICACID
CBNumber: CB0331184
Molecular Formula: C9H9BrO2
Formula Weight: 229.07
MOL File: 1129-28-8.mol

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Methyl 3-(bromomethyl)benzoate Property

Melting point:: 46-47 °C(lit.)
Boiling point:: 112-114 °C3 mm Hg(lit.)
Density: 1,47 g/cm³
Flash point:: 115°C/0.8mm
storage temp.: 2-8°C
form: Crystals or Crystalline Powder
color: White
Water Solubility: Slightly soluble in water.
BRN: 638569
InChI: InChI=1S/C9H9BrO2/c1-12-9(11)8-4-2-3-7(5-8)6-10/h2-5H,6H2,1H3
InChIKey: YUHSMQQNPRLEEJ-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC=CC(CBr)=C1
CAS DataBase Reference: 1129-28-8(CAS DataBase Reference)
NIST Chemistry Reference: Methyl 3-bromomethylbenzoate(1129-28-8)

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Safety

Hazard Codes: C,Xi
Risk Statements: 22-34-43
Safety Statements: 26-36/37/39-45
RIDADR: UN 3261 8/PG 2
WGK Germany: 2
F: 19
Hazard Note: Irritant/Corrosive
HazardClass: 8
PackingGroup: III
HS Code: 29163990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 648116
Product name: Methyl 3-(bromomethyl)benzoate
Purity: 97%
Packaging: 5g
Price: $54.7
Updated: 2025/07/31

Sigma-Aldrich

Product number: 648116
Product name: Methyl 3-(bromomethyl)benzoate
Purity: 97%
Packaging: 25g
Price: $232.75
Updated: 2025/07/31

TCI Chemical

Product number: B2224
Product name: Methyl 3-(Bromomethyl)benzoate
Purity: >97.0%(GC)
Packaging: 5g
Price: $47
Updated: 2025/07/31

TCI Chemical

Product number: B2224
Product name: Methyl 3-(Bromomethyl)benzoate
Purity: >97.0%(GC)
Packaging: 25g
Price: $142
Updated: 2025/07/31

TRC

Product number: M294015
Product name: Methyl 3-(Bromomethyl)benzoate
Packaging: 1g
Price: $50
Updated: 2021/12/16

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Methyl 3-(bromomethyl)benzoate Chemical Properties,Usage,Production

Chemical Properties

white crystalline powder or crystals

Uses

Methyl 3-(bromomethyl)benzoate is used in organic synthesis of other chemicals.

Synthesis

99-36-5

1129-28-8

General procedure for the synthesis of methyl 3-bromomethylbenzoate from methyl m-methylbenzoate: 30 mL of carbon tetrachloride (CCl4) and 7.9 g of methyl m-methylbenzoate were added to a dry 100 mL three-necked flask, and after dissolution, 0.23 g of AIBN (azobisisobutyronitrile) and 9.36 g of NBS (N-bromosuccinimide) were sequentially added in three additions (with an interval of about 2-3 hours). The reaction system was heated to 70°C and the color of the reaction solution was observed to change gradually from yellow to orange and finally to white. The reaction was monitored by TLC (eluent: cyclohexane/ethyl acetate = 5:1) until the reaction was almost complete. At the end of the reaction, the resulting succinimide and unreacted N-bromosuccinimide were removed by filtration. The filtrate was rotary evaporated to give 11.5 g of a yellow oily product, methyl 3-bromomethylbenzoate, in 95% yield.

References

[1] Organic and Biomolecular Chemistry, 2003, vol. 1, # 14, p. 2506 - 2511
[2] Patent: CN106146413, 2016, A. Location in patent: Paragraph 0027; 0028
[3] European Journal of Medicinal Chemistry, 2009, vol. 44, # 1, p. 7 - 17
[4] Molecules, 2016, vol. 21, # 12,
[5] Patent: WO2018/169777, 2018, A1. Location in patent: Paragraph 0227

Methyl 3-(bromomethyl)benzoate Preparation Products And Raw materials

Raw materials

Benzoyl peroxide N-Bromosuccinimide Carbon tetrachloride Methyl 3-methylbenzoate PETROLEUM ETHER

Preparation Products

METHYL 3-((PIPERIDIN-4-YL)METHYL)BENZOATE 3-((1-(TERT-BUTOXYCARBONYL)PIPERIDIN-4-YL)METHYL)BENZOIC ACID Methyl 3-(aminomethyl)benzoate hydrochloride

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Methyl 3-(bromomethyl)benzoate Suppliers

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View Lastest Price from Methyl 3-(bromomethyl)benzoate manufacturers

Hebei Fengjia New Material Co., Ltd

Product: Methyl 3-(bromomethyl)benzoate 1129-28-8
Price: US $5.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10000
Release date: 2024-09-10

Hebei Chuanghai Biotechnology Co., Ltd

Product: Methyl 3-(bromomethyl)benzoate 1129-28-8
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 5tons
Release date: 2024-12-02

Shaanxi Dideu Medichem Co. Ltd

Product: Methyl 3-(bromomethyl)benzoate 1129-28-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 1000MT
Release date: 2024-07-17

1129-28-8, Methyl 3-(bromomethyl)benzoateRelated Search:

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Methyle3-(bromomethyl)benzoate

TIMTEC-BB SBB005793

METHYL 3-(BROMOMETHYL)BENZOATE

M-CARBOMETHOXYBENZYL BROMIDE

METHYL ALPHA-BROMO-M-TOLUATE

ALPHA-BROMO-M-TOLUIC ACID METHYL ESTER

3-(BROMOMETHYL)BENZOIC ACID METHYL ESTER

3-CARBOMETHOXYBENZYL BROMIDE

Methyl 3-(bromomethyl)benzoat

3-(BROMOMETHYL)PHENYLACETICACID

Methyl 3-(bromomethyl)benzoate ,97%

Methyl 3-(bromomethyl)benzoate,95%

Methyl 3-aMino-4-fluorobezoate

Methyl 3-(broMoMethyl)benzoate, 95% 5GR

3-(Bromomethyl)benzoic Acid Methyl Ester alpha-Bromo-m-toluic Acid Methyl Ester Methyl alpha-Bromo-m-toluate

Benzoic acid, 3-(broMoMethyl)-, Methyl ester

Methyl m-(Bromomethyl)benzoate

Methyl 3-(Bromomethyl)benzoate &gt

Methyl 3-(bromomethyl)phenylacetate

1129-28-8

1129-28-2

Esters

Organic Building Blocks

Building Blocks

Carbonyl Compounds

BENZYL HALIDE

C8 to C9

Building Blocks

C8 to C9

Carbonyl Compounds

Chemical Synthesis

Organic Building Blocks

Esters

Phenyls & Phenyl-Het

Aromatic Halides (substituted)