L(-)-10-Camphorsulfonyl chloride

Product Name: L(-)-10-Camphorsulfonyl chloride
CAS No.: 39262-22-1
Chemical Name: L(-)-10-Camphorsulfonyl chloride
Synonyms: ((1R,4S)-7,7-DiMethyl-2-oxobicyclo[2.2.1]heptan-1-yl)Methanesulfonyl chloride;(1R)-(-)-10-CamphorsuL;R)-()-10-CaMphorsulfony;L(-)Camphor sulfonyl chloride;(-)-10-CAMPHORSULFONYL CHLORIDE;(-)-10-Camphorsulfonyl Chloride;(-)-CAMPHOR-10-SULFONYL CHLORIDE;L(-)-10-CAMPHORSULFONYL CHLORIDE;(+)-camphor-10-sulfonyl chloride;L-(-)-1-Camphorsulfonyl chloride
CBNumber: CB0356635
Molecular Formula: C10H15ClO3S
Formula Weight: 250.74
MOL File: 39262-22-1.mol

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L(-)-10-Camphorsulfonyl chloride Property

Melting point:: 66-68 °C(lit.)
alpha: -33 º (c=3, chloroform)
Boiling point:: 349.4±15.0 °C(Predicted)
Density: 1.331±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: Acetone, Dichloromethane, Ethyl Acetate, Methanol
form: Solid
color: White
optical activity: [α]18/D 33°, c = 3 in chloroform
Water Solubility: Decomposes
Sensitive: Moisture Sensitive
BRN: 3205975
InChIKey: BGABKEVTHIJBIW-UHFFFAOYSA-N
CAS DataBase Reference: 39262-22-1(CAS DataBase Reference)

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Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 26-36/37/39-45
RIDADR: UN 3261 8/PG 2
WGK Germany: 3
F: 10-21
HazardClass: 8
PackingGroup: II
HS Code: 29147090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 301949
Product name: (1R)-(?)-10-Camphorsulfonyl chloride
Purity: 97%
Packaging: 5g
Price: $65.6
Updated: 2023/01/07

TCI Chemical

Product number: C1308
Product name: (-)-10-Camphorsulfonyl Chloride
Purity: >98.0%(T)
Packaging: 5g
Price: $42
Updated: 2024/03/01

TCI Chemical

Product number: C1308
Product name: (-)-10-Camphorsulfonyl Chloride
Purity: >98.0%(T)
Packaging: 25g
Price: $168
Updated: 2024/03/01

TRC

Product number: C175070
Product name: (1R)-(?)-10-Camphorsulfonyl chloride
Packaging: 10g
Price: $415
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0415093
Product name: (1R)-(-)-CAMPHOR-10-SULFONYL CHLORIDE
Purity: 95.00%
Packaging: 2G
Price: $825
Updated: 2021/12/16

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L(-)-10-Camphorsulfonyl chloride Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

A chiral derivative of Camphor.

Uses

L(-)-10-Camphorsulfonyl chloride is a useful synthetic intermediate,it is used for asymmetric hydroxylation.

Purification Methods

If free from OH bands in the IR, then recrystallise it from Et2O or pet ether; otherwise treat it with SOCl2 at 50o for 30minutes, evaporate, dry the residue over KOH in a vacuum and recrystallise it. The (±)-acid chloride has m 85o [Bartlett & Knox Org Synth 45 14 1965]. Itis characterised as the amide (prisms from EtOH) m 132o, [ ] 17 (+) and (-) 1.5o (EtOH). On repeated recrystallisation from EtOH the anilide has m 120.5-121o, [] 25 +76o (c 1, CHCl3). [Read & Storey J Chem Soc 2761 1930, Sutherland & Shriner J Am Chem Soc 58 62 1936, Halterman et al. J Am Chem Soc 109 8105 1987, Bartlet & Knox Org Synth 45 55 1945, Beilstein 11 IV 650.]

L(-)-10-Camphorsulfonyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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L(-)-10-Camphorsulfonyl chloride Suppliers

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View Lastest Price from L(-)-10-Camphorsulfonyl chloride manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: L(-)-10-Camphorsulfonyl chloride 39262-22-1
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-10-25

Zibo Hangyu Biotechnology Development Co., Ltd

Product: L(-)-10-Camphorsulfonyl chloride 39262-22-1
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100tons
Release date: 2024-08-27

Hebei Mujin Biotechnology Co.,Ltd

Product: L(-)-10-Camphorsulfonyl chloride 39262-22-1
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-08-31

39262-22-1, L(-)-10-Camphorsulfonyl chlorideRelated Search:

Ethanesulfonyl chloride Calcium chloride Benzyl chloride Tosyl chloride Choline chloride Ammonium chloride (2R)-Bornane-10,2-sultam Sulfuryl chloride (-)-CAMPHOR 4-Nitrobenzenesulfonyl chloride Mepiquat chloride Camphor (1R)-(-)-10-Camphorsulfonic acid Benzenesulfonyl chloride Sodium chloride Polyvinyl chloride L-carnitine (1R,2R)-(-)-1,2-Diaminocyclohexane

L(-)-10-CAMPHORSULFONYL CHLORIDE

(-)-CAMPHOR-10-SULFONYL CHLORIDE

(1R)-(-)-10-CAMPHORSULFONYL CHLORIDE

(1R)-(-)-CAMPHOR-10-SULPHONYL CHLORIDE

(1R)-(-)-CAMPHOR-10-SULFONIC ACID CHLORIDE

(1R)-CAMPHOR-10-SULFONIC ACID CHLORIDE

(1R)-(-)-CAMPHOR-10-SULFONYL CHLORIDE

(-)-10-CAMPHORSULFONYL CHLORIDE

[3-(chlorosulfonylmethyl)-2,2,3-trimethylcyclopentyl]methanesulfonyl chloride

(1R)-(-)-10-CAMPHORSULFONYL CHLORIDE, 97 %

(1R)-(-)-CAMPHOR-10-SULFONIC ACID CHLORIDE 98+%

6,(1R)-(-)-10-Camphorsulfonylchloride

Bicyclo2.2.1heptane-1-methanesulfonyl chloride, 7,7-dimethyl-2-oxo-, (1R,4S)-

(-)-Camphor-10-sulphonyl chloride

L(-)Camphor sulfonyl chloride

(1R)-CaMphor-1-sulfonic acid chloride

(-)-Camphor-10-sulfonyl chloride, (1R)-Camphor-10-sulfonic acid chloride

(7,7-Dimethyl-2-oxo-1-bicyclo[2.2.1]heptanyl)methanesulfonyl chloride

(1R,4S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfochloride

[1R,4R,(-)]-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonic acid chloride

L(-)-10-Camphorsulfonyl chloride,97%

(1R,4S)-7,7-DiMethyl-2-oxo-bicyclo[2.2.1]heptane-1-Methanesulfonyl Chloride

(1R)-(-)-CAMPHOR-10-SULFONIC ACID CHLORI

((1R,4S)-7,7-DiMethyl-2-oxobicyclo[2.2.1]heptan-1-yl)Methanesulfonyl chloride

R)-()-10-CaMphorsulfony

L-10- of caMphorsulfonyl chloride

L(-)-10-Camphorsulfonyl chloride (1R)-Camphor-10-sulfonic acid chloride

(1<i>R</i>)-()-10-Camphorsulfonyl chloride

(1R)-(-)-10-Camphorsulfonyl chloride 97%

(1R)-(-)-Camphor-10-sulfonic acid chloride for synthesis

[(1S,4R)-7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl]methanesulfonyl chloride

(-)-10-Camphorsulfonyl Chloride &gt

(1R)-(-)-10-CamphorsuL

L(-)-10-Camphorsulfonyl chloride USP/EP/BP

(+)-camphor-10-sulfonyl chloride

L-(-)-1-Camphorsulfonyl chloride

(-)-10-Camphorsulfonyl Chloride

(-)-Camphor-10-sulfonyl chloride

39262-22-1

C10H15O3Cl

Bicyclic Monoterpenes

Terpenes

for Resolution of Bases

for Resolution of Alcohols & Thiols

Optical Resolution

SULFONYL CHLORIDE

Peptide

Intermediates & Fine Chemicals

Pharmaceuticals

Sulfonyl Chlorides

chiral

Chiral Reagents

Bicyclic Monoterpenes

Biochemistry

for Resolution of Alcohols & Thiols

for Resolution of Bases

Optical Resolution

Synthetic Organic Chemistry