6-Methylnicotinaldehyde

Application

Product Name: 6-Methylnicotinaldehyde
CAS No.: 53014-84-9
Chemical Name: 6-Methylnicotinaldehyde
Synonyms: 5-FORMYL-2-PICOLINE;6-Methylnicotinaldehyde;5-Formyl-2-methylpyridine;3-FORMYL-6-METHYL-PYRIDINE;3-Formyl-6-methyl-pyridine ,97%;6-Methylpyridine-3-carboxaldehyde;6-METHYL-3-PYRIDINECARBOXALDEHYDE;3-Pyridinecarboxaldehyde, 6-methyl-;6-Methyl-3-pyridinecarboxaldehyde>6-Methylpyridine-3-carboxaldehyde 97%
CBNumber: CB0438566
Molecular Formula: C7H7NO
Formula Weight: 121.14
MOL File: 53014-84-9.mol

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6-Methylnicotinaldehyde Property

Boiling point:: 95℃/20mm
Density: 1.084
refractive index: 1.546
Flash point:: 88℃
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
pka: 4.15±0.10(Predicted)
form: Liquid
Appearance: Colorless to light yellow Liquid
Sensitive: Moisture Sensitive
InChI: InChI=1S/C7H7NO/c1-6-2-3-7(5-9)4-8-6/h2-5H,1H3
InChIKey: IMWMEIWYPWVABQ-UHFFFAOYSA-N
SMILES: C1=NC(C)=CC=C1C=O
CAS DataBase Reference: 53014-84-9

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Safety

Hazard Codes: Xn
Risk Statements: 22-36
Safety Statements: 26
WGK Germany: 3
HS Code: 29333990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H227Combustible liquid

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 718726
Product name: 6-Methylpyridine-3-carboxaldehyde
Purity: 97%
Packaging: 500mg
Price: $177
Updated: 2023/06/20

TCI Chemical

Product number: M2654
Product name: 6-Methyl-3-pyridinecarboxaldehyde
Purity: >98.0%(GC)
Packaging: 200mg
Price: $56
Updated: 2021/12/16

TCI Chemical

Product number: M2654
Product name: 6-Methyl-3-pyridinecarboxaldehyde
Purity: >98.0%(GC)
Packaging: 1g
Price: $192
Updated: 2021/12/16

TRC

Product number: M323490
Product name: 6-Methylnicotinaldehyde
Packaging: 100mg
Price: $75
Updated: 2021/12/16

Matrix Scientific

Product number: 068688
Product name: 6-Methylnicotinaldehyde
Purity: >95%
Packaging: 1g
Price: $24
Updated: 2021/12/16

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6-Methylnicotinaldehyde Chemical Properties,Usage,Production

Application

3-Aldehyde-6-methylpyridine is a pyridine heterocyclic compound mainly used in laboratory research and development of organic synthesis processes.

Synthesis

To a solution of 5-bromo-2-methylpyridine (151; 10 g, 58.1 mmol) in THF (150 mL) was added n-BuLi (2.5 M, 25.6 mL) at -78 ℃. The reaction mixture was stirred at this temperature for Ih. DMF (1.30 mL) was added,, and the resulting reaction mixture was stirred for 1 h at -78 °C. The addition of aq quenched the reaction. NH4Cl. Upon warming to room temperature, the mixture was extracted with EtOAc. The combined organic layers were dried (Na2SO4) and concentrated under reduced pressure. The resulting residue was purified by chromatography to afford 6-methylnicotinaldehyde 152 (5.0 g, 72percent).

References

[1] Patent: US2006/287341, 2006, A1. Location in patent: Page/Page column 46
[2] Patent: US2007/4772, 2007, A1. Location in patent: Page/Page column 82
[3] Journal of Medicinal Chemistry, 1989, vol. 32, # 3, p. 583 - 593
[4] Journal of Organic Chemistry, 1988, vol. 53, # 15, p. 3513 - 3521
[5] Patent: US4778796, 1988, A

6-Methylnicotinaldehyde Preparation Products And Raw materials

Raw materials

N,N-Dimethylformamide 2-Bromo-5-methylpyridine Tetrahydrofuran Magnesium n-Butyllithium 2-Chloropropane

Preparation Products

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6-Methylnicotinaldehyde Suppliers

Americas 1 Belgium 1 China 154 Europe 1 France 1 Germany 6 India 8 Japan 1 Switzerland 1 The Netherlands 1 United Kingdom 6 United States 34 Global 215

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View Lastest Price from 6-Methylnicotinaldehyde manufacturers

Dideu Industries Group Limited

Product: 3-FORMYL-6-METHYL-PYRIDINE 53014-84-9
Price: US $1.10/g
Min. Order: 1g
Purity: 99.00%
Supply Ability: 100 Tons min
Release date: 2021-08-25

Career Henan Chemical Co

Product: 3-FORMYL-6-METHYL-PYRIDINE 53014-84-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: Customized
Release date: 2019-07-01

53014-84-9, 6-MethylnicotinaldehydeRelated Search:

DIMETHYL PYRIDINE-2,5-DICARBOXYLATE Streptonigrin Nalidixic acid sodium salt 6-METHYL-2,3-PYRIDINEDICARBOXYLIC ACID 2,5-PYRIDINEDICARBOXYLIC ACID Methyl 6-methylnicotinate DIETHYL 2,6-DIMETHYL-3,5-PYRIDINEDICARBOXYLATE 2-CHLORO-4,6-DIMETHYLNICOTINAMIDE 2,5-PYRIDINEDICARBOXYLIC ACID DI-N-PROPYL ESTER Nalidixic acid 3-Acetyl-2,4,6-trimethylpyridine Amfonelic acid 2-Hydroxy-6-methylpyridine-3-carboxylic acid 6-METHYLNICOTINAMIDE 6-Methylpyridine-3-carboxylic acid DIMETHYL 4-(4-METHOXYPHENYL)-2,6-DIMETHYLPYRIDINE-3,5-DICARBOXYLATE 2-METHYL-3-HYDROXY-4-HYDROXYMETHYL-5-CARBOXYPYRIDINE LACTONE 2,5-DICHLORO-4,6-DIMETHYLNICOTINAMIDE

6-METHYL-3-PYRIDINECARBOXALDEHYDE

5-FORMYL-2-PICOLINE

3-FORMYL-6-METHYL-PYRIDINE

6-Methylpyridine-3-carboxaldehyde

5-Formyl-2-methylpyridine

6-Methylnicotinaldehyde

3-Pyridinecarboxaldehyde, 6-methyl-

3-Formyl-6-methyl-pyridine ,97%

5-ForMyl-2-picoline/6-Methylnicotinaldehyde

6-Methylpyridine-3-carboxaldehyde, 5-Formyl-2-methylpyridine

6-Methylpyridine-3-carboxaldehyde 97%

2-Phenyl-[1,2,4]triazolo[1,5-a]pyridin-6-amine

6-Methyl-3-pyridinecarboxaldehyde&gt

3-FORMYL-6-METHYL-PYRIDINE ISO 9001：2015 REACH

53014-84-9

Heterocycle-Pyridine series

Building Blocks

Pyridines

Aldehydes

C7

C7 to C8

Carbonyl Compounds

Chemical Synthesis

Heterocyclic Building Blocks

Organic Building Blocks

Pyridine