ChemicalBook > CAS DataBase List > Sarcosine methyl ester hydrochloride
Sarcosine methyl ester hydrochloride
- Product Name
- Sarcosine methyl ester hydrochloride
- CAS No.
- 13515-93-0
- Chemical Name
- Sarcosine methyl ester hydrochloride
- Synonyms
- H-SAR-OME·HCL;SAR-OME HCL;H-SAR-OME HCL;METHYL 2-(METHYLAMINO)ACETATE HYDROCHLORIDE;H-Sar-OMe;L-Sar-OMe·HCl;N-ME-GLY-OME HCL;Sarcosine methyl;SARCOSINE-OME HCL;H-Sar-OMe·HCl, BR
- CBNumber
- CB0668093
- Molecular Formula
- C4H10ClNO2
- Formula Weight
- 139.58
- MOL File
- 13515-93-0.mol
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Sarcosine methyl ester hydrochloride Property
- Melting point:
- 117-119 °C(lit.)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
- form
- Crystals or Crystalline Powder
- color
- White to beige
- Water Solubility
- Soluble in water.
- Sensitive
- Hygroscopic
- BRN
- 3677128
- InChI
- InChI=1S/C4H9NO2.ClH/c1-5-3-4(6)7-2;/h5H,3H2,1-2H3;1H
- InChIKey
- HQZMRJBVCVYVQA-UHFFFAOYSA-N
- SMILES
- C(=O)(OC)CNC.Cl
- CAS DataBase Reference
- 13515-93-0(CAS DataBase Reference)
- EPA Substance Registry System
- Glycine, N-methyl-, methyl ester, hydrochloride (13515-93-0)
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Safety
- Hazard Codes
- Xn,O,Xi
- Risk Statements
- 22-37/38-41-36/37/38
- Safety Statements
- 26-39-36
- WGK Germany
- 3
- F
- 3
- TSCA
- Yes
- HS Code
- 29224999
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H318Causes serious eye damage
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 84570
- Product name
- Sarcosine methyl ester hydrochloride
- Purity
- ≥97.0% (T)
- Packaging
- 50g
- Price
- $430
- Updated
- 2025/07/31
Sigma-Aldrich
- Product number
- 84570
- Product name
- Sarcosine methyl ester hydrochloride
- Purity
- ≥97.0% (T)
- Packaging
- 250g
- Price
- $620
- Updated
- 2023/06/20
TRC
- Product number
- S140523
- Product name
- Sarcosine methyl ester hydrochloride
- Packaging
- 50g
- Price
- $90
- Updated
- 2021/12/16
SynQuest Laboratories
- Product number
- 4158-5-X0
- Product name
- N-Methylglycine methyl ester hydrochloride
- Packaging
- 25g
- Price
- $90
- Updated
- 2021/12/16
ChemPep
- Product number
- 190735
- Product name
- N-Me-Gly-OMe•HCl
- Packaging
- 25g
- Price
- $95
- Updated
- 2021/12/16
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Sarcosine methyl ester hydrochloride Chemical Properties,Usage,Production
Chemical Properties
White to beige crystals or crystalline powder
Uses
It can react with formic acid to get N-formyl-N-methyl-glycine methyl ester in the presence of HCO2Na at ambient temperature.
reaction suitability
reaction type: solution phase peptide synthesis
Synthesis
42492-57-9
13515-93-0
General procedure for the synthesis of methyl sarcosinate hydrochloride from methyl 2-((tert-butoxycarbonyl)(methyl)amino)acetate: To a stirring solution of methyl 2-((tert-butoxycarbonyl)(methyl)amino)acetate (1 mmol) in dichloromethane (2 mL) was slowly added a solution of 3.3 M HCl in dioxane (5 mL) at 0 °C. The temperature of the reaction mixture was gradually increased to 20 °C and stirring was continued at this temperature for 1 hour. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure. The resulting residue was placed in anhydrous ether and stirred to promote the formation of crystalline products. For less crystalline or hygroscopic products, the residue can be dissolved in dry chloroform, followed by evaporation of the solvent and drying of the product in a vacuum desiccator using P4O10 or KOH as the desiccant. A portion of the product may be purified by silica gel column chromatography using eluent mixture B or by gel filtration through biogel P2 or Fractogel TCK HW 40, followed by lyophilization to obtain a pure product.
References
[1] Tetrahedron, 2012, vol. 68, # 35, p. 7070 - 7076
Sarcosine methyl ester hydrochloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Sarcosine methyl ester hydrochloride manufacturers
Sichuan HongRi Pharma-Tech Co.,Ltd
- Product
- H-Sar-OMe·HCl 13515-93-0
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1T+
- Release date
- 2024-04-02
Baoji Guokang Healthchem co.,ltd
- Product
- Sarcosine methyl ester hydrochloride 13515-93-0
- Price
- US $250.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10tons
- Release date
- 2021-06-08
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- Sarcosine methyl ester hydrochloride 13515-93-0
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-11
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