ChemicalBook > CAS DataBase List > XantPhos Pd G4

XantPhos Pd G4

Product Name
XantPhos Pd G4
CAS No.
1621274-19-8
Chemical Name
XantPhos Pd G4
Synonyms
5-Bis(diphenylphosphino)-9;XantPhos Pd G4;Methanesulfonato[4;Xantphos Palladacycle Gen.4;9-dimethylxanthene](2-methylamino-1;1-biphenyl-2-yl)palladium(II) (Xantphos Pd G4);[2'-(Methylamino)-2-biphenylyl]palladium(1+) methanesulfonate - (9,9-dimethyl-9H-xanthene-4,5;Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene](2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato[4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene](2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene](2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
CBNumber
CB13159438
Molecular Formula
C92H78NO8P4PdS2-
Formula Weight
1620.050664
MOL File
1621274-19-8.mol
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XantPhos Pd G4 Property

form 
solid
color 
yellow
InChI
InChI=1S/2C39H32O4P2S.C13H12N.CH4.Pd/c2*1-39(2)32-24-15-25-33(44(28-16-7-3-8-17-28)29-18-9-4-10-19-29)37(32)43-38-34(26-27-35(36(38)39)46(40,41)42)45(30-20-11-5-12-21-30)31-22-13-6-14-23-31;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;;/h2*3-27H,1-2H3,(H,40,41,42);2-7,9-10,14H,1H3;1H4;/q;;;;+1/p-2
InChIKey
YEBRPYRJQFPKNJ-UHFFFAOYSA-L
SMILES
C1(C)(C)C2=C(C(P(C3=CC=CC=C3)C3=CC=CC=C3)=CC=C2)OC2=C1C(S([O-])(=O)=O)=CC=C2P(C1=CC=CC=C1)C1=CC=CC=C1.C1(C)(C)C2=C(C(P(C3=CC=CC=C3)C3=CC=CC=C3)=CC=C2)OC2=C1C(S([O-])(=O)=O)=CC=C2P(C1=CC=CC=C1)C1=CC=CC=C1.[Pd+]C1=CC=CC=C1C1=CC=CC=C1NC.C
CAS DataBase Reference
1621274-19-8
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
900329
Product name
XantPhos Pd G4
Packaging
250MG
Price
$137
Updated
2024/03/01
Sigma-Aldrich
Product number
900329
Product name
XantPhos Pd G4
Packaging
1G
Price
$341
Updated
2024/03/01
Strem Chemicals
Product number
46-0388
Product name
Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene](2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), 98% [Xantphos Palladacycle Gen. 4]
Packaging
250mg
Price
$71
Updated
2024/03/01
Strem Chemicals
Product number
46-0388
Product name
Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene](2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), 98% [Xantphos Palladacycle Gen. 4]
Packaging
1g
Price
$214
Updated
2024/03/01
Strem Chemicals
Product number
46-0388
Product name
Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene](2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), 98% [Xantphos Palladacycle Gen. 4]
Packaging
5g
Price
$849
Updated
2024/03/01
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XantPhos Pd G4 Chemical Properties,Usage,Production

Uses

A powerful ligand for classic cross-coupling reactions combined with the Buchwald Fourth Generation Palladacycle. Bench stable, soluble in most organic solvents.

Reactions

  1. Catalyst used in the aminocarbonylation of (hetero)aryl bromides.
  2. Catalyst used in the aminocarbonylation of bromopyridine and alkyl-substituted bromobenzene.

XantPhos Pd G4 Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from XantPhos Pd G4 manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
XantPhos Pd G4 1621274-19-8
Price
US $0.00/G
Min. Order
10G
Purity
98%min
Supply Ability
30kg/month
Release date
2023-02-02
Longyan Tianhua Biological Technology Co., Ltd
Product
[2'-(Methylamino)-2-biphenylyl]palladium(1+) methanesulfonate - (9,9-dimethyl-9H-xanthene-4,5 1621274-19-8
Price
US $25.00/KG
Min. Order
1KG
Purity
99
Supply Ability
1000KG
Release date
2020-11-10
Career Henan Chemical Co
Product
[2'-(Methylamino)-2-biphenylyl]palladium(1+) methanesulfonate - (9,9-dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphine) (1:1:1) 1621274-19-8
Price
US $1.00/KG
Min. Order
1KG
Purity
Min98% HPLC
Supply Ability
g/kg/ton
Release date
2020-01-08

1621274-19-8, XantPhos Pd G4Related Search:


  • Methanesulfonato[4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene](2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
  • METHANESULFONATO[9,9-DIMETHYL-4,5-BIS(DIPHENYLPHOSPHINO)XANTHENE](2'-METHYLAMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),98%[XANTPHOSPALLADACYCLEGEN.4]
  • Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene](2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
  • Xantphos Palladacycle Gen.4
  • [2'-(Methylamino)-2-biphenylyl]palladium(1+) methanesulfonate - (9,9-dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphine) (1:1:1)
  • (SP-4-3)-[[5-(Diphenylphosphino)-9,9-dimethyl-9H-xanthen-4-yl]diphenylphosphine-κP](methanesulfonato-κO)[2'-(methylamino-κN)[1,1'-biphenyl]-2-yl-κC]palladium
  • [2'-(Methylamino)-2-biphenylyl]palladium(1+) methanesulfonate - (9,9-dimethyl-9H-xanthene-4,5
  • Methanesulfonato[4
  • 9-dimethylxanthene](2-methylamino-1
  • 5-Bis(diphenylphosphino)-9
  • 1-biphenyl-2-yl)palladium(II) (Xantphos Pd G4)
  • XantPhos Pd G4
  • Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene](2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
  • Methanesulfonato[4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene](2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
  • 1621274-19-8
  • 1601274-19-8
  • C53H47NO4P2PdS