1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

Reaction

Product Name: 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
CAS No.: 95464-05-4
Chemical Name: 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
Synonyms: Pd（dppf）2Cl2;Pd(dppf)Cl2.CH2Cl2;PdCl2(dppf)DCM;[PdCl2(dppf)]CH2Cl2;Palladium[PdCl2(dppf)]CH2Cl2;[1,1-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane PdCl2(dppf)CH2Cl2;CHEMDOSE;ex with dichL;adium(II),compL;Pd(dppf)Cl2 DCM
CBNumber: CB1347621
Molecular Formula: C34H28Cl2FeP2Pd.CH2Cl2
Formula Weight: 816.63
MOL File: 95464-05-4.mol

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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Property

Melting point:: 275-280 °C(lit.)
Density: 1 g/cm³
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Powder
color: orange-red
Water Solubility: Insoluble in water.
Stability:: Light Sensitive
CAS DataBase Reference: 95464-05-4(CAS DataBase Reference)

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22-36/37/38-40-67-48/20/22
Safety Statements: 23-24/25-26-36/37
WGK Germany: 3
TSCA: No
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 379670
Product name: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane
Packaging: 1g
Price: $64.3
Updated: 2024/03/01

Sigma-Aldrich

Product number: 379670
Product name: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane
Packaging: 5g
Price: $160
Updated: 2024/03/01

TCI Chemical

Product number: B2064
Product name: [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct
Purity: >98.0%(T)
Packaging: 1g
Price: $58
Updated: 2024/03/01

TCI Chemical

Product number: B2064
Product name: [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct
Purity: >98.0%(T)
Packaging: 5g
Price: $174
Updated: 2024/03/01

Alfa Aesar

Product number: 041225
Product name: Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), complex with dichloromethane (1:1), Pd 13%
Packaging: 1g
Price: $59.9
Updated: 2023/06/20

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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Chemical Properties,Usage,Production

Reaction

Catalyst for the borylation of aryl halides.
β-Alkyl Suzuki-Miyaura cross-coupling reactions with potassium alkyltrifluoroborates.
Catalyst for modified Negishi coupling.
Synthesis of polyheterocycles by a Pd-catalyzed intramolecular N-arylation/C-H bond activation/aryl-aryl bond-forming domino process.
Catalyst for Stille allylation.
Catalyst for the amination of aryl bromides.

Chemical Properties

orange/red solid

Uses

suzuki reaction

Uses

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is used in the preparation of imidazoles, benzimidazoles, and tetrahydropyrimidines,it is also used as a catalyst for Suzuki and Stile couplings.

Application

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is an organometallic compound that can be used as a noble metal catalyst for carbonylation reactions, cross-coupling reactions, Suzuki reaction.

Synthesis

1. Dissolve 2.00 grams of sodium palladium chloride in 30mL of anhydrous ethanol to obtain the ethanol solution of sodium palladium chloride;
2. Dissolve 4.15 grams of 1,1 '-bis (diphenylphosphine) ferrocene in 41mL dichloromethane to obtain 1,1' -bis (diphenylphosphine) ferrocene dichloromethane solution;
3. Under stirring conditions, add the ethanol solution of sodium palladite chloride in step 1 to dichloromethane solution of 1, 1 '-bis (diphenylphosphine) ferrocene in step 2. Stir and react for 1h at 25℃. 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex crystal, yield 90.46%.
In this method, the target product 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex was synthesized directly with dichloromethane as the solvent in one step, eliminating the synthesis process of precursor PDCl2 (DPPF). The reaction process is simple, the synthesis cycle is short, easy to operate, and the purity of the synthesized product is 99.4%.

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Preparation Products And Raw materials

Raw materials

Acetonitrile 1,1'-Bis(diphenylphosphino)ferrocene Toluene Palladium chloride Dichloromethane

Preparation Products

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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Suppliers

Americas 1 Australia 1 Belgium 1 Canada 2 China 380 China Hong Kong 1 Europe 1 Germany 4 India 13 Japan 3 South Korea 1 Switzerland 2 The Netherlands 1 Ukraine 1 United Kingdom 3 United States 25 Global 440

Xunteng International Trading Co.,Limited

Tel
Country: China Hong Kong
ProdList: 878
Advantage: 55

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View Lastest Price from 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex manufacturers

Shanghai Daken Advanced Materials Co.,Ltd

Product: 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex 95464-05-4
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 100KG /month
Release date: 2021-11-12

Hebei Chuanghai Biotechnology Co,.LTD

Product: 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromet 95464-05-4
Price: US $8.70/g
Min. Order: 10g
Purity: 99.95%
Supply Ability: 10000kg
Release date: 2024-08-09

Henan Fengda Chemical Co., Ltd

Product: 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex 95464-05-4
Price: US $100.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-25

95464-05-4, 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complexRelated Search:

Palladium chloride Cobalt chloride ETHYNYLFERROCENE Palladium Dichloromethane Acetylferrocene Ferrocenecarboxylic acid [1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloride dichloromethane complex (1:1) Aminoferrocene Ferrocene (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM Pd-107 [1,2-Bis(dicyclohexylphosphino)ethane]palladiuM(II) chloride,95% 1,1'-Bis(diphenylphosphino)ferrocene Phenyl phosphine Diphenylphosphine Chloromethane 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]-PALLADIUM DICHLOROMETHANE ADDUCT

DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHANE ADDUCT

DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHANE COMPLEX

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1'1-Bis(diphenylphosphino)fewocene Palladium(Ⅱ)chloride dichloromethane chloride

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichlorome

Pd(dppf)Cl2.CH2Cl2

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DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHA

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Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II), coMplex with dichloroMethane (1:1), Pd 13%

1,1'-Bis(diphenylphosphino)ferrocene palladium(Ⅱ)chloride dichloromethane complex

[PdCl2(dppf)]CH2Cl2

Palladium[PdCl2(dppf)]CH2Cl2

PALLADIUM, [1,1''-BIS(DIPHENYLPHOSPHINO-.KAPPA.P)FERROCENE]DICHLORO-, (SP-4-2)-, COMPD. WITH DICHLOROMETHANE

Pd（dppf）2Cl2

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1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE-PALLADIUM(II)DICHLORIDE DICHLOROMETHANE ADDUCT

[1,1-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane PdCl2(dppf)CH2Cl2

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(1,1'-Bis(diphenylphosphino)ferrocene)dichloropalladium-dichloromethane

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[1,1'-bis (diphenylphosphino) ferrocene] dichloropalladiuM dichloroMethane coMplex

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (1:1)

Pd(dppf)Cl2 DCM

Bis(dibenzylibeneacetone)palladium

adium(II),compL

ex with dichL

[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride, complex with dichloromethane (1:1)

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