METHYL 5-BROMO-2-FUROATE
- Product Name
- METHYL 5-BROMO-2-FUROATE
- CAS No.
- 2527-99-3
- Chemical Name
- METHYL 5-BROMO-2-FUROATE
- Synonyms
- METHYL 5-BROMOFURAN-2-CARBOXYLATE;AKOS BBS-00004656;BUTTPARK 94\04-07;5-bromo-2-furoate;RARECHEM AL BF 0601;METHYL 5-BROMO-2-FURATE;METHYL 5-BROMO-2-FUROATE;Methyl 5-bromo-2-furanate;Methyl 5-bromo-2-furoate,98%;methyl 5-bromo-2-furoate 97%
- CBNumber
- CB1393880
- Molecular Formula
- C6H5BrO3
- Formula Weight
- 205.01
- MOL File
- 2527-99-3.mol
METHYL 5-BROMO-2-FUROATE Property
- Melting point:
- 63-68 °C
- Boiling point:
- 80°C/0.7mmHg(lit.)
- Density
- 1.623±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- Chloroform (Soluble), DMSO (Slightly)
- form
- Crystalline Powder
- color
- White to slightly yellow
- Water Solubility
- Slightly soluble in water.
- λmax
- 264nm(EtOH)(lit.)
- InChIKey
- FBPIDMAELBIRLE-UHFFFAOYSA-N
- CAS DataBase Reference
- 2527-99-3(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- S810541
- Product name
- METHYL 5-BROMO-2-FUROATE
- Purity
- Aldrich<sup>CPR</sup>
- Packaging
- 1 unit
- Price
- $185
- Updated
- 2025/07/31
- Product number
- S810541
- Product name
- METHYL 5-BROMO-2-FUROATE
- Purity
- Aldrich
- Packaging
- 50mg
- Price
- $179
- Updated
- 2024/03/01
- Product number
- M2538
- Product name
- Methyl 5-Bromo-2-furancarboxylate
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $42
- Updated
- 2025/07/31
- Product number
- M2538
- Product name
- Methyl 5-Bromo-2-furancarboxylate
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $124
- Updated
- 2025/07/31
- Product number
- M296140
- Product name
- Methyl5-bromofuran-2-carboxylate
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
METHYL 5-BROMO-2-FUROATE Chemical Properties,Usage,Production
Chemical Properties
White to slightly yellow crystalline powder
Uses
It is used in the preparation of hydroquinone bis(2-carbomethoxy-5-furyl ether).
Synthesis
67-56-1
585-70-6
2527-99-3
General procedure for the synthesis of methyl 5-bromofuran-2-carboxylate from methanol and 5-bromo-2-furoic acid: 5-bromo-2-furoic acid (950 mg, 5.00 mmol) was accurately weighed and dissolved in 10 mL of methanol, and 2 mL of sulfoxide chloride (SOCl2) was added slowly and dropwise. Upon completion of the reaction, the reaction mixture was cooled to room temperature and the solvent was subsequently removed by evaporation under reduced pressure. The residue was dissolved in an appropriate amount of toluene and this dissolution and evaporation process was repeated three times to give the intermediate 5-bromo-2-furoic acid methyl ester in 100% yield.
References
[1] Patent: CN103992311, 2017, B. Location in patent: Paragraph 0103; 0104; 0105; 0106; 0123; 0124; 0125
[2] Organic Letters, 2012, vol. 14, # 22, p. 5644 - 5647
[3] Patent: CN106977476, 2017, A. Location in patent: Paragraph 0103-0105
[4] Patent: WO2015/159103, 2015, A1. Location in patent: Page/Page column 33; 34; 37
[5] Patent: WO2015/1024, 2015, A1. Location in patent: Page/Page column 65
METHYL 5-BROMO-2-FUROATE Preparation Products And Raw materials
Raw materials
Preparation Products
METHYL 5-BROMO-2-FUROATE Suppliers
- Tel
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- Fax
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- mduris@georganics.sk
- Country
- Slovakia
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- Advantage
- 58
- Tel
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- Fax
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- georganics@nextra.sk
- Country
- Slovakia
- ProdList
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View Lastest Price from METHYL 5-BROMO-2-FUROATE manufacturers
- Product
- METHYL 5-BROMO-2-FUROATE 2527-99-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-13
- Product
- METHYL 5-BROMO-2-FUROATE 2527-99-3
- Price
- US $10.00-8.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-06-07
- Product
- METHYL 5-BROMO-2-FUROATE 2527-99-3
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 2000ton
- Release date
- 2023-08-31