ChemicalBook > CAS DataBase List > Ethyl 4-(bromomethyl)benzoate

Ethyl 4-(bromomethyl)benzoate

Uses

Product Name: Ethyl 4-(bromomethyl)benzoate
CAS No.: 26496-94-6
Chemical Name: Ethyl 4-(bromomethyl)benzoate
Synonyms: ETHYL 4-(BROMOMETHYL)BENZOATE;4-ethoxycarbonylbenzyl bromide;4-(methyl bromide) ethyl benzoate;4-(BROMOMETHYL)BENZOIC ACID ETHYL ESTER;Benzoic acid, 4-(bromomethyl)-, ethyl ester;ETHYL (4-BROMOMETHYL) BENZOATE (SB290160007);4-(Bromomethyl)benzoic acid ethyl ester~4-Ethoxycarbonylbenzyl bromide;4-(Ethoxycarbonyl)benzyl bromide, alpha-Bromo-4-(ethoxycarbonyl)toluene
CBNumber: CB1782301
Molecular Formula: C10H11BrO2
Formula Weight: 243.1
MOL File: 26496-94-6.mol

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Ethyl 4-(bromomethyl)benzoate Property

Melting point:: 40°C
Boiling point:: 145°C 5mm
Density: 1.402±0.06 g/cm3(Predicted)
refractive index: 1.5494
Flash point:: 145°C/5mm
storage temp.: 2-8°C
form: fused solid
color: White
BRN: 1869569
InChI: InChI=1S/C10H11BrO2/c1-2-13-10(12)9-5-3-8(7-11)4-6-9/h3-6H,2,7H2,1H3
InChIKey: TWQLMAJROCNXEA-UHFFFAOYSA-N
SMILES: C(OCC)(=O)C1=CC=C(CBr)C=C1
CAS DataBase Reference: 26496-94-6(CAS DataBase Reference)

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Safety

Hazard Codes: C
Risk Statements: 22-34
Safety Statements: 26-36/37/39-45
RIDADR: 1759
HazardClass: 8
PackingGroup: II
HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H400Very toxic to aquatic life

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC

Product number: B011510
Product name: 4-(bromomethyl)-BenzoicacidEthylEster
Packaging: 10g
Price: $155
Updated: 2021/12/16

Apolloscientific

Product number: OR30551
Product name: Ethyl4-(bromomethyl)benzoate
Purity: 96%
Packaging: 5g
Price: $101
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2723-9-X3
Product name: Ethyl 4-(bromomethyl)benzoate
Purity: 96%
Packaging: 5G
Price: $111
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0023187
Product name: ETHYL 4-(BROMOMETHYL)BENZOATE
Purity: 95.00%
Packaging: 1G
Price: $124.95
Updated: 2021/12/16

Apolloscientific

Product number: OR30551
Product name: Ethyl4-(bromomethyl)benzoate
Purity: 96%
Packaging: 25g
Price: $179
Updated: 2021/12/16

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Ethyl 4-(bromomethyl)benzoate Chemical Properties,Usage,Production

Uses

4-(bromomethyl)-Benzoic acid ethyl ester is a brominated aromatic building block used in various syntheses such as the preparation of imidazoles and imidazo-fused heterocycles.

Uses

4-?(bromomethyl)?-?Benzoic acid ethyl ester is a brominated aromatic building block used in various syntheses such as the preparation of imidazoles and imidazo-fused heterocycles.

Synthesis

94-08-6

26496-94-6

General procedure for the synthesis of ethyl 4-(bromomethyl)benzoate from ethyl p-methylbenzoate: to a stirred solution of ethyl 4-methylbenzoate (5 g, 30.49 mmol) in carbon tetrachloride (35 ml) was added sequentially N-bromosuccinimide (5.90 g, 33.53 mmol) and benzoyl peroxide (720 mg, 1.52 mmol). The reaction mixture was heated under reflux conditions for 4 h. The progress of the reaction was monitored by thin layer chromatography (TLC). After completion of the reaction, the mixture was cooled to room temperature and subsequently filtered. The filtrate was concentrated by vacuum evaporation to give the colorless oily product ethyl 4-(bromomethyl)benzoate (7.25 g, 98% yield).

References

[1] Chinese Journal of Chemistry, 2012, vol. 30, # 8, p. 1906 - 1908
[2] Patent: WO2009/109999, 2009, A1. Location in patent: Page/Page column 68
[3] Organic Process Research and Development, 1998, vol. 2, # 4, p. 261 - 269
[4] Synthesis (Germany), 2018, vol. 50, # 24, p. 4933 - 4939
[5] Tetrahedron, 2007, vol. 63, # 36, p. 8891 - 8901

Ethyl 4-(bromomethyl)benzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Ethyl 4-(bromomethyl)benzoate manufacturers

Career Henan Chemical Co

Product: Ethyl 4-(bromomethyl)benzoate 26496-94-6
Price: US $1.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 200kg
Release date: 2018-12-25

26496-94-6, Ethyl 4-(bromomethyl)benzoateRelated Search:

Ethylparaben Benzyl benzoate ETHYL ANTHRANILATE Ethyl 2-chloromethylbenzoate Ethyl benzoate Bromotrimethylsilane Ethanol 4-Bromomethylbenzoic acid Ethyl 4-methylbenzoate Ethyl acetate Ethyl 4-hydroxybenzoate,sodium salt Tris(trimethylsilyl)phosphate Sodium benzoate Emamectin benzoate Denatonium Benzoate Anhydrous Methyl 4-(bromomethyl)benzoate 4-(BROMOMETHYL)-BENZOIC ACID, 1,1-DIMETHYLETHYL ESTER Methyl bromide

ETHYL 4-(BROMOMETHYL)BENZOATE

4-(BROMOMETHYL)BENZOIC ACID ETHYL ESTER

4-(Bromomethyl)benzoic acid ethyl ester~4-Ethoxycarbonylbenzyl bromide

4-ethoxycarbonylbenzyl bromide

ETHYL (4-BROMOMETHYL) BENZOATE (SB290160007)

4-(Ethoxycarbonyl)benzyl bromide, alpha-Bromo-4-(ethoxycarbonyl)toluene

4-(methyl bromide) ethyl benzoate

Benzoic acid, 4-(bromomethyl)-, ethyl ester

26496-94-6

Aromatic Esters