ChemicalBook > CAS DataBase List > Benzaldehyde, 2-broMo-4-hydroxy

Benzaldehyde, 2-broMo-4-hydroxy

Product Name
Benzaldehyde, 2-broMo-4-hydroxy
CAS No.
22532-60-1
Chemical Name
Benzaldehyde, 2-broMo-4-hydroxy
Synonyms
2-BroMo-4-Hydroxy benzaldehyde;Benzaldehyde, 2-broMo-4-hydroxy
CBNumber
CB22631185
Molecular Formula
C7H5BrO2
Formula Weight
201.02
MOL File
22532-60-1.mol
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Benzaldehyde, 2-broMo-4-hydroxy Property

Boiling point:
292.4±20.0 °C(Predicted)
Density 
1.737±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
6.81±0.18(Predicted)
Appearance
Off-white to yellow Solid
InChI
InChI=1S/C7H5BrO2/c8-7-3-6(10)2-1-5(7)4-9/h1-4,10H
InChIKey
OCBOCCOUCDGNKX-UHFFFAOYSA-N
SMILES
C(=O)C1=CC=C(O)C=C1Br
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
B997133
Product name
2-Bromo-4-hydroxybenzaldehyde
Packaging
100mg
Price
$60
Updated
2021/12/16
TRC
Product number
B997133
Product name
2-Bromo-4-hydroxybenzaldehyde
Packaging
500mg
Price
$110
Updated
2021/12/16
AK Scientific
Product number
Z4448
Product name
2-Bromo-4-hydroxybenzaldehyde
Packaging
1g
Price
$91
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB142526
Product name
2-Bromo-4-hydroxybenzaldehyde
Packaging
1g
Price
$172
Updated
2021/12/16
Matrix Scientific
Product number
119817
Product name
2-Bromo-4-hydroxybenzaldehyde
Purity
95+%
Packaging
1g
Price
$197
Updated
2021/12/16
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Benzaldehyde, 2-broMo-4-hydroxy Chemical Properties,Usage,Production

Synthesis

64-17-5

591-20-8

22532-60-1

The general procedure for the synthesis of 2-bromo-4-hydroxybenzaldehyde from ethanol and m-bromophenol was as follows: 30% aqueous sodium hydroxide solution (160 mL) was mixed with 3-bromophenol (10.04 g, 58 mmol) and heated to 70-75 °C. Subsequently, ethanol (5 mL) was added all at once and chloroform (28 mL, 0.35 mol) was added slowly and dropwise. After maintaining the reaction at 75 °C for 1 hour, the reaction mixture was continued to be stirred at this temperature for 3 hours. Upon completion of the reaction, the mixture was cooled to room temperature and acidified with 10N hydrochloric acid. Most of the by-products were removed by steam distillation. The residue was cooled and the precipitate was separated by filtration. The crude product was purified by silica gel column chromatography using hexane/ethyl acetate (2:1, v/v) as eluent to give 1.75 g of 2-bromo-4-hydroxybenzaldehyde in 15% yield.

References

[1] Patent: WO2011/37731, 2011, A1. Location in patent: Page/Page column 111-112

Benzaldehyde, 2-broMo-4-hydroxy Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Benzaldehyde, 2-broMo-4-hydroxy manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
2-Bromo-4-hydroxybenzaldehyde 22532-60-1
Price
US $3.00-9.00/kg
Min. Order
1kg
Purity
99%min
Supply Ability
50kg
Release date
2025-07-28
Career Henan Chemical Co
Product
POTASSIUM (4-CYANOPHENYL)TRIFLUOROBORATE 850623-36-8
Price
US $1.00/ASSAYS
Min. Order
1ASSAYS
Purity
99%
Supply Ability
1000KGS
Release date
2019-12-20