Tris(dibenzylideneacetone)dipalladium-chloroform adduct

Reaction

Product Name: Tris(dibenzylideneacetone)dipalladium-chloroform adduct
CAS No.: 52522-40-4
Chemical Name: Tris(dibenzylideneacetone)dipalladium-chloroform adduct
Synonyms: Pd2dba3.CHCl3;TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM CHLOROFORM COMPLEX;TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0) CHLOROFORM ADDUCT;Pd2(bda)3 CHCl3;TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM-CHLOROFORM;Tris(dibenzylideneacetone)dipalladium(0)-chloroform;chloroform,(1E,4E)-1,5-diphenylpenta-1,4-dien-3-one,palladium;Tris DBA;adium-chL;oroform adduct
CBNumber: CB2298434
Molecular Formula: C52H31Cl3O3Pd2
Formula Weight: 1023.01
MOL File: 52522-40-4.mol

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Tris(dibenzylideneacetone)dipalladium-chloroform adduct Property

Melting point:: 131-135 °C(lit.)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
form: Crystalline Powder
color: Purple to black
Water Solubility: Soluble in organic solvents. Insoluble in water.
Sensitive: Air & Moisture Sensitive
InChIKey: NLYJPAJWGANOKG-CXKPDERJSA-N

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 22-38-40-48/20/22-36/37/38
Safety Statements: 36/37-37/39-26
WGK Germany: 3
TSCA: No
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H351Suspected of causing cancer

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 366315
Product name: Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct
Packaging: 250mg
Price: $49.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 366315
Product name: Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct
Packaging: 1g
Price: $178
Updated: 2024/03/01

Alfa Aesar

Product number: 044969
Product name: Tris(dibenzylideneacetone)dipalladium(0), complex with chloroform, Pd 20.6%
Packaging: 1g
Price: $109
Updated: 2024/03/01

Alfa Aesar

Product number: 044969
Product name: Tris(dibenzylideneacetone)dipalladium(0), complex with chloroform, Pd 20.6%
Packaging: 5g
Price: $396.65
Updated: 2024/03/01

Strem Chemicals

Product number: 46-3010
Product name: Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct
Packaging: 500mg
Price: $67
Updated: 2024/03/01

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Tris(dibenzylideneacetone)dipalladium-chloroform adduct Chemical Properties,Usage,Production

Reaction

Used for Pd-catalyzed asymmetric arylation, vinylation, and Allenylation of tert-cyclobutanols via enantioselective C−C Bond cleavage.
Used for synthesis of chiral chromans through the Pd-catalyzed asymmetric allylic alkylation (AAA).
Catalyst for double N-arylation of primary amines to synthesize multisubstituted carbazoles from 2,2‘biphenylylene ditriflates.
Paladium catalyst for regioand enantioselective allylic alkylation of ketones through allyl enol carbonates.
Used for Pd-catalyzed enantioselective C-3 allylation of 3-substituted-1H-indoles using trialkylboranes.
Used for enantioselective construction of spirocyclic oxindolic cyclopentanes by Pd-catalyzed trimethylenemethane-[3+2]-cycloaddition.
Used for Pd-catalyzed insertion of α-diazoesters into vinyl halides to generate α,β-unsaturated γ-amino Esters.
Pd catalyst for decarboxylative asymmetric allylic alkylation of enol carbonates.
Palladium catalyst for asymmetric addition of oxindoles and allenes.
Catalyst for diastereoand enantioselective formal [3+2]-cycloaddition between substituted vinylcyclopropanes and electron-deficient olefins.
Used for Pd-catalyzed asymmetric decarboxylative cycloaddition of vinylethylene carbonates with Michael sacceptors.
Catalyst for enantioselective [6+4] cycloaddition of vinyl oxetanes with azadienes to access ten-membered heterocycles.

Chemical Properties

purple to black crystalline powder

Uses

suzuki reaction

Uses

Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct is a catalyst that is used in the preparation of anticancer activity of amino vinylindoles via palladium catalyzed coupling of hydrazone, haloindoles and amines.

Application

Tris(dibenzylideneacetone)dipalladium-chloroform adduct (Pd2dba3·CHCl3) was used in the following studies:
To compose the catalytic system for the preparation of homoallylpalladium complexes.These complexes underwent in situ Stille type cross coupling with various vinyltin reagents to afford the cyclized products bearing allyl appendages.
As palladium source in the asymmetric transformations of 3,4-epoxy-1-butene.
As catalyst for the Heck cross-coupling reaction of iodobenzene with styrene.
As cyclization catalyst.
As catalyst for [2+2+2] cycloaddtion of didehydrotriphenylenes to the corresponding extended triphenylenes.
As catalyst for the carbonylation of b,b-imidoyl iodides to the corresponding imidate esters used, in turn, to prepare cyclic, quaternary amino acids.

General Description

Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct (Pd₂dba₃·CHCl₃) is reported to serve as effective precatalysts, or precursors to the active Pd(0) catalyst.

Biological Activity

N -myristoyltransferase-1 (NMT-1) inhibitor that prevents activation of MAPK, PI 3-K and STAT3 signaling pathways. Exhibits antiproliferative activity against melanoma cells in vitro and in vivo . Also used as a cyclization catalyst.

Tris(dibenzylideneacetone)dipalladium-chloroform adduct Preparation Products And Raw materials

Raw materials

Sodium acetate Acetonitrile Ethanol tert-Butyl methyl ether Acetone Toluene Chloroform Benzaldehyde Diethyl ether Ammonium chloride Palladium chloride Dichloromethane Methanol Sodium hydroxide

Preparation Products

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View Lastest Price from Tris(dibenzylideneacetone)dipalladium-chloroform adduct manufacturers

Shanghai Daken Advanced Materials Co.,Ltd

Product: Tris(dibenzylideneacetone)dipalladium-chloroform adduct 52522-40-4
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.00%
Supply Ability: 100KG /month
Release date: 2021-11-05

Wuhan LPBchem Technology Co.,Ltd

Product: Tris(dibenzylideneacetone)dipalladium-chloroform adduct 52522-40-4
Price: US $10.00-10.00/g
Min. Order: 1g
Purity: 0.98
Supply Ability: 50KG
Release date: 2020-11-26

Longyan Tianhua Biological Technology Co., Ltd

Product: Tris(dibenzylideneacetone)dipalladium-chloroform adduct 52522-40-4
Price: US $20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KG
Release date: 2020-11-10

52522-40-4, Tris(dibenzylideneacetone)dipalladium-chloroform adductRelated Search:

Benzyl chloride Tris(hydroxymethyl)aminomethane Tricine Dibenzylideneacetone Benzyltrimethylammonium chloride Benzalacetone BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE) Benzyltriethylammonium chloride Tris(dibenzylideneacetone)dipalladium Tris(dibenzylideneacetone)dipalladium TRIS(DIMETHYLAMINO)ANTIMONY TRIS(DIMETHYLAMINO)SILANE Tris(dibenzylideneacetone)dipalladium Tris(triphenylphosphine)rhodiu Tris(dimethylaminomethyl)phenol Tris(hydroxymethyl)nitromethane Benzylacetone Chloroform

TRIS(DIBENZYLIDENEACETONE)(CHLOROFORM)-DI-PALLADIUM(0)

TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0) CHLOROFORM ADDUCT

TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM-CHLOROFORM ADDUCT

TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM CHLOROFORM COMPLEX

DIPALLADIUM(0)TRIS(DIBENZYLIDENEACETONE)-CHLOROFORM ADDUCT

DI-PALLADIUM-TRIS(DIBENZYLIDENEACETONE)CHLOROFORM COMPLEX

Dipalladiumtris(dibenzylideneacetone) chloroform adduct

TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0) CHLOROFORM ADDUCT 98+%

TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM-CHLOROFORM

Tris(dibenylideneacetone)dipalladium-chloroform

adium-chL

oroform adduct

Tris (dibenzylidene acetone)di palladiuM(O)-chloroforM addict

chloroform,(1E,4E)-1,5-diphenylpenta-1,4-dien-3-one,palladium

Tris DBA chloroform adduct

DIPALLADIUM(0)TRIS(DIBENZYLI

tris(dibenzylideneacetone)(chloroform)-di-p

Tris(dibenzylideneacetone)dipalladium-chloroform a

Pd2(bda)3 CHCl3

Tris(dibenzylideneacetone)dipalladium(0)-chloroform

Tris(dibenzylideneacetone)dipalladium(0), complex with chloroform, Pd 20.6%

Tris(dibenzylideneacetone)dipalladium-chloroform adduct,97%

Tris-(dibenzylideneacetone)-dipalladium(O)-chloroform adduct

Tris(Dibenzylideneacetone)Dipalladium(0), Complex With Chloroform, Pd

Pd2dba3.CHCl3

Tris DBA

Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct [Pd > 20.2%]

Tris(dibenzylideneacetone)dipalladiuM-chloroforM adduct, 97% 1GR

Tris(dibenzylideneacetone)dipalladiuM (0) chloroforM adduct, Pd2(dba)3·CHCl3

Tris(Dibenzylideneacetone)DipalladiuM- ChloroforM AdduCL

2,2'',3',6,6'',7'-hexaphenyldispiro[1-palladatricyclo[3.1.0.0^{1,3}]hexane-1,2'-[1,2]dipalladatricyclo[4.1.0.0^{2,4}]heptane-1',1''-[1]palladatricyclo[3.1.0.0^{1,3}]hexane]-2,2'',3',5,5'',6'-hexaene-4,4'',5'-trione

Tris(dibenzylideneacetone)dipalladium chloroform adduct 98%

(1E,4E)-1,5-diphenyl-3-penta-1,4-dienone

Tris(dibenzylideneacetone)dipalladium-chloroform adduct ISO 9001：2015 REACH

Tris(dibenzylideneacetone)dipalladium-chloroform adduct 52522-40-4

TRIS (DIBENZYLIDENEACETONE) DIPALLADIUM CHLOROFORM ADDUCT For Synthesis

Palladium, tris[μ-[(1,2-η:4,5-η)-(1E,4E)-1,5-diphenyl-1,4-pentadien-3-one]]di-, compd. with trichloromethane (1:1) (9CI, ACI)

Trismu-(1,2-eta:4,5-eta)-(1E,4E)-1,5-diphenyl-1,4-pentadien-3-onedi-palladium compd. with trichloromethane (1:1)

52522-40-4

52552-40-4

C52H43Cl3O3Pd2

C51H42O3Pd2CHCl3

Pd2C17H14O3CHCl3

C6H5CHCHCOCHCHC6H53Pd2CHCl3

C52Cl3H43O3Pd2

C35H29Cl3O2Pd

C6H5CHCHCOCHCHC6H53Pd2稢HCl3

3C17H14OCHCl32Pd

Catalysis and Inorganic Chemistry

New Products for Chemical Synthesis May/June 2007

Homogeneous Pd Catalysts

organometallic complexes

Metal Compounds