Potassium peroxymonosulfate

Reactions

Product Name: Potassium peroxymonosulfate
CAS No.: 70693-62-8
Chemical Name: Potassium peroxymonosulfate
Synonyms: Potassium peroxymonosulfate sulfate;PotassiuM Monopersulfate coMpound;potassium peroxymonopersulfate;PotassiuM 3-sulfotrioxidan-1-ide;Potassium hydrogen monopersulfate;Potassiumhydrogenperoxymonosulfate;Potassium peroxymonosulfate,Active Oxygen≥4.5%;Oxone PS-16;OXONE Extra Pure;POTASSIUM CAROATE
CBNumber: CB2503525
Molecular Formula: H3K5O18S4
Formula Weight: 614.74
MOL File: 70693-62-8.mol

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Potassium peroxymonosulfate Property

Density: 1.15
storage temp.: Store at <= 20°C.
solubility: 250-300g/l soluble
form: solid
Specific Gravity: 1.12-1.20
color: white
PH: 2-3 (10g/l, H2O, 20℃)
Water Solubility: Soluble in water (100 mg/ml).
Sensitive: Hygroscopic
Exposure limits: ACGIH: TWA 0.1 mg/m3
Stability:: Stable. Oxidizer. Incompatible with combustible materials, bases.
InChIKey: HVAHYVDBVDILBL-UHFFFAOYSA-M
LogP: -3.9 at 25℃
CAS DataBase Reference: 70693-62-8(CAS DataBase Reference)
EPA Substance Registry System: Potassium peroxymonosulfate sulfate (K5[HSO3(O2)][SO3(O2)](HSO4)2) (70693-62-8)

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Safety

Hazard Codes: O,C
Risk Statements: 8-22-34-42/43-37-35
Safety Statements: 22-26-36/37/39-45
RIDADR: UN 3260 8/PG 2
WGK Germany: 1
TSCA: Yes
HS Code: 2833 40 00
HazardClass: 5.1
PackingGroup: III
Toxicity: LD50 orally in Rabbit: > 2000 mg/kg

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 911356
Product name: OXONE®, monopersulfate compound
Purity: free-flowing, Redi-Dri?
Packaging: 50G
Price: $48
Updated: 2024/03/01

Sigma-Aldrich

Product number: 911356
Product name: OXONE?, monopersulfate compound
Purity: free-flowing,Redi-Dri?
Packaging: 100G
Price: $71.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 911356
Product name: OXONE®, monopersulfate compound
Purity: free-flowing, Redi-Dri?
Packaging: 500G
Price: $87
Updated: 2024/03/01

Sigma-Aldrich

Product number: 911356
Product name: OXONE®, monopersulfate compound
Purity: free-flowing, Redi-Dri?
Packaging: 1KG
Price: $103
Updated: 2024/03/01

Sigma-Aldrich

Product number: 228036
Product name: OXONE?, monopersulfate compound
Packaging: 5g
Price: $48
Updated: 2024/03/01

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Potassium peroxymonosulfate Chemical Properties,Usage,Production

Reactions

Reagent for the catalytic asymmetric Shi epoxidation
Reagent for the synthesis of nitro heteroaromatics in water
Reagent for the syntheses of benzoxazoles and benzothiazoles using aryl iodides via C-H functionalization and C-O/S bond formation
Reagent used for bromolactonization in the asymmetric total synthesis of (+)-Dubiusamine C
Reagent for the benzofuran oxidative dearomatization cascade in the total synthesis of Integrastatin B

Chemical Properties

white crystalline powder

Uses

PCB metal surface treatment chemical and water treatment etc.

Uses

Oxone is used for halogenation of a,b-unsaturated carbonyl compounds and catalytic generation of hypervalent iodine reagents for alcohol oxidation. It is a used for rapid, and good synthesis of oxaziridines.

General Description

OXONE^?, monopersulfate compound is a potassium triple salt mainly used as a stable, easy to handle and nontoxic oxidant.

Flammability and Explosibility

Non flammable

Purification Methods

This is a stable form of Caro's acid and should contain >4.7% of active oxygen. It can be used in EtOH/H2O and EtOH/AcOH/H2O solutions. If active oxygen is too low. it is best to prepare it afresh from 1mole of KHSO5, 0.5mole of KHSO4 and 0.5mole of K2SO4. [Kennedy & Stock J Org Chem 25 1901 1960, Stephenson US Patent 2,802,722 1957.] A rapid preparation of Caro's acid is made by stirring finely powdered potassium persulfate (M 270.3) into ice-cold conc H2SO4 (7mL) and when homogeneous add ice (40-50g). It is stable for several days if kept cold. Keep away from organic matter as it is a STRONG OXIDANT. A detailed preparation of Caro's acid (hypersulfuric acid, H2SO5) in crystalline form m ~45o from H2O2 and chlorosulfonic acid was described by Fehér in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 388 1963.

Potassium peroxymonosulfate Preparation Products And Raw materials

Raw materials

Ampicillin Potassium hydroxide Sulfuric acid

Preparation Products

1,2-EPOXYCYCLODODECANE 4-Bromo-2-nitrophenol 5-BROMO-2-BENZOXAZOLINONE 97 6-BROMO-2H-1,4-BENZOXAZIN-3(4H)-ONE 4-Methylmorpholine N-oxide monohydrate 2-Amino-4-bromophenol 2-AMINOETHYLMETHYLSULFONE HYDROCHLORIDE

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Potassium peroxymonosulfate Suppliers

China 313 China Hong Kong 1 Europe 2 France 1 Germany 2 India 15 South Korea 1 Switzerland 1 United Kingdom 5 United States 6 Global 347

Alfa Aesar

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Beijing HwrkChemical Technology Co., Ltd

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JinYan Chemicals(ShangHai) Co.,Ltd.

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View Lastest Price from Potassium peroxymonosulfate manufacturers

Watson Biotechnology Co.,Ltd

Product: Potassium peroxymonosulfate MPS 70693-62-8
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20MT
Release date: 2024-09-21

Hebei ZB Gamay Biological Technology Co.,Ltd

Product: Potassium Monopersulfate Compound 70693-62-8
Price: US $0.00-0.00/kg
Min. Order: 25kg
Purity: 42.8%
Supply Ability: 2000kg
Release date: 2022-09-16

Shandong Deshang Chemical Co., Ltd.

Product: Potassium peroxymonosulfate 70693-62-8
Price: US $8.80-6.20/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10 tons
Release date: 2024-07-01

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POTASSIUM CAROATE

Oxone PS-16

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Monopersulfate Compound (Oxone)

Potassium monopersulfate Available Oxygen: 4.50%+

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Oxone (Potassium peroxymonosulfate)

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2-Nitrotoluene 88-72-2

Potassium peroxymonosulfate sulfate (K5[HSO3(O2)][SO3(O2)](HSO4)2) (9CI, ACI)

Potassium hydrogenperoxo monopersulfate

Potassium peroxymonosulfate MPS

70693-62-8

2KHSO5KHSO4K2SO4H3K5O18

2KHSO5KHSO4K2SO4H3K5O18S4

KHSO505KHSO405K2SO4

K2SO4KHSO42KHSO5

HKO6S

K3H3O18S4

Inorganics

70693-62-8