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2,5-DIBROMO-M-XYLENE

Product Name
2,5-DIBROMO-M-XYLENE
CAS No.
100189-84-2
Chemical Name
2,5-DIBROMO-M-XYLENE
Synonyms
2,5-Dibromo-1,3-dimethylbenzene;5-DIBROMO-M-XYLENE;2,5-DIBROMO-M-XYLENE;2,5-Dibromo-3-methyl-toluene;1,4-DIBROMO-2,6-DIMETHYLBENZENE;Benzene, 2,5-dibroMo-1,3-diMethyl-;D848545 2,5-Dibromo-1,3-dimethylbenzene,98%
CBNumber
CB2665465
Molecular Formula
C8H8Br2
Formula Weight
263.96
MOL File
100189-84-2.mol
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2,5-DIBROMO-M-XYLENE Property

Melting point:
26-28°
Boiling point:
261.7±35.0 °C(Predicted)
Density 
1.710±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
Appearance
White to off-white Solid-liquid mixture
InChI
InChI=1S/C8H8Br2/c1-5-3-7(9)4-6(2)8(5)10/h3-4H,1-2H3
InChIKey
XXFGKGMZLZIPCN-UHFFFAOYSA-N
SMILES
C1(C)=CC(Br)=CC(C)=C1Br
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
D426120
Product name
2,5-Dibromo-m-xylene
Packaging
250mg
Price
$55
Updated
2021/12/16
TRC
Product number
D426120
Product name
2,5-Dibromo-m-xylene
Packaging
500mg
Price
$65
Updated
2021/12/16
AK Scientific
Product number
J53399
Product name
2,5-Dibromo-1,3-dimethylbenzene
Packaging
1g
Price
$10
Updated
2021/12/16
AK Scientific
Product number
B844
Product name
2,5-Dibromo-1,3-dimethylbenzene
Packaging
1g
Price
$14
Updated
2021/12/16
Oakwood
Product number
018507
Product name
2,5-Dibromo-m-xylene
Packaging
1g
Price
$15
Updated
2021/12/16
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2,5-DIBROMO-M-XYLENE Chemical Properties,Usage,Production

Synthesis

24596-19-8

100189-84-2

General procedure for the synthesis of 2,5-dibromo-m-xylene from 4-bromo-2,6-dimethylaniline: 4-bromo-2,6-dimethylaniline (6.00 g, 30 mmol) was suspended in a 48% aqueous hydrobromic acid solution (20 mL), cooled to -10 °C, then sodium nitrite (2.28 g, 33 mmol) dissolved in water was slowly added, and the mixture was kept at that temperature with continuous stirring for 1 hour. Subsequently, sulfamic acid (0.58 g, 6 mmol) was added to quench the excess nitrite. The reaction mixture was transferred to a 48% aqueous hydrobromic acid solution (20 mL) containing ferrous sulfate heptahydrate (4.17 g, 15 mmol), gradually warmed to 80 °C and stirred at this temperature for 1 hour. After completion of the reaction, water was added to the mixture and extracted with hexane. The organic phases were combined, dried with anhydrous sodium sulfate and concentrated under reduced pressure to remove the solvent. Finally, the target product 2,5-dibromo m-xylene (6.19 g, 72% yield) was purified by medium-pressure column chromatography (silica gel as stationary phase and hexane as mobile phase).

References

[1] Journal of the American Chemical Society, 2018, vol. 140, # 18, p. 5925 - 5933
[2] Patent: JP2018/90535, 2018, A. Location in patent: Paragraph 0072; 0073; 0082; 0083
[3] Patent: JP2018/90536, 2018, A. Location in patent: Paragraph 0098; 0099; 0100; 0101
[4] Journal of Porphyrins and Phthalocyanines, 2010, vol. 14, # 9, p. 804 - 814
[5] Journal of Organic Chemistry, 2012, vol. 77, # 4, p. 2074 - 2079

2,5-DIBROMO-M-XYLENE Preparation Products And Raw materials

Raw materials

Preparation Products

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2,5-DIBROMO-M-XYLENE Suppliers

China 102 France 1 India 2 Lithuania 1 United Kingdom 4 United States 11 Global 121
Carbosynth
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United Kingdom
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Fluorochem Ltd
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vernam@fluorochem.co.uk
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United Kingdom
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Fluorochem Ltd.
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enquiries@fluorochem.co.uk
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Wychem Ltd.
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terry.robinson@wychem.co.uk
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United Kingdom
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View Lastest Price from 2,5-DIBROMO-M-XYLENE manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
2,5-DIBROMO-M-XYLENE 100189-84-2
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-10-14
Henan Fengda Chemical Co., Ltd
Product
2,5-DIBROMO-M-XYLENE 100189-84-2
Price
US $101.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-28
Career Henan Chemical Co
Product
2,5-dibromo-1,3-dimethylbenzene 100189-84-2
Price
US $1.00/KG
Min. Order
1KG
Purity
98% HPLC
Supply Ability
10 tons/month
Release date
2020-01-09

100189-84-2, 2,5-DIBROMO-M-XYLENERelated Search:

4,5-DIBROMO-O-XYLENE 5-Bromo-m-xylene à,à'-dibromo-m-xylene,alpha,alpha'-Dibromo-meta-xylene,α,α’-dibromo-m-xylen 2,5-Dibromotoluene 2,5-DIBROMO-P-XYLENE,2,5-DIBROMO-P-XYLENE, 98+%,2,5-DIBROMO-4-XYLENE alpha,alpha'-Dibromo-p-xylene ALPHA,ALPHA-DIBROMO-O-XYLENE,ALPHA,ALPHA'-DIBROMO-2-XYLENE,alpha,alpha '-Dibromo-ortho-xylene,α,α’-dibromo-o-xylen alpha-Dibromo-m-xylene 4,5-Dibromo-m-xylene 3,5-Dibromo-o-xylene A,A'-DIBROMO-P-XYLENE-D8,ALPHA,ALPHA'-DIBROMO-P-XYLENE-D8 1,4-DIBROMO-O-XYLENE 2,5-DIBROMO-M-XYLENE 1,4-DIBROMO-2,3,5,6-TETRAMETHYLBENZENE 2,5-Dibromo-1,3-diethylbenzene OMEGA,OMEGA'-DIBROMO-O-XYLENE Ω,Ω'-DIBROMO-P-XYLENE A.A'-DIBROMO-M-XYLENE SOLUTION 100UG/ML IN HEXANE 5X1ML

  • 2,5-DIBROMO-M-XYLENE
  • 1,4-DIBROMO-2,6-DIMETHYLBENZENE
  • 2,5-Dibromo-1,3-dimethylbenzene
  • Benzene, 2,5-dibroMo-1,3-diMethyl-
  • 5-DIBROMO-M-XYLENE
  • D848545 2,5-Dibromo-1,3-dimethylbenzene,98%
  • 2,5-Dibromo-3-methyl-toluene
  • 100189-84-2
  • Bromine Compounds