ChemicalBook > CAS DataBase List > (1S)-(-)-Camphanic acid

(1S)-(-)-Camphanic acid

Product Name
(1S)-(-)-Camphanic acid
CAS No.
13429-83-9
Chemical Name
(1S)-(-)-Camphanic acid
Synonyms
CAMPHANIC ACID;(-)-CAMPHANIC ACID;(-)-Camphanic Acid;(-) Camphenic acid;(?)-Camphanic acid;(IS) CAMPHANIC ACID;(-)-Camphanic acid,99%;(-)-Camphanic Acid >(1R)-(-)-CAMPHANIC ACID;(1S)-(-)-CAMPHANIC ACID
CBNumber
CB2669519
Molecular Formula
C10H14O4
Formula Weight
198.22
MOL File
13429-83-9.mol
More
Less

(1S)-(-)-Camphanic acid Property

Melting point:
201-205 °C
alpha 
-18.5 º (c=1, dioxane)
Boiling point:
255.53°C (rough estimate)
Density 
1.0143 (rough estimate)
refractive index 
1.4500 (estimate)
storage temp. 
Sealed in dry,Room Temperature
pka
3.36±0.60(Predicted)
form 
powder to crystaline
color 
White to Almost white
optical activity
[α]20/D 18°, c = 1 in dioxane
BRN 
84570
InChIKey
RKFCLVFAFZYVCG-WDEREUQCSA-N
CAS DataBase Reference
13429-83-9(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
22-24/25-37/39-26-36-37
WGK Germany 
3
HS Code 
29329995
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
328227
Product name
(1S)-(?)-Camphanic acid
Purity
98%
Packaging
1g
Price
$62.9
Updated
2023/06/20
Sigma-Aldrich
Product number
328227
Product name
(1S)-(?)-Camphanic acid
Purity
98%
Packaging
5g
Price
$73.6
Updated
2023/01/07
TCI Chemical
Product number
C1021
Product name
(-)-Camphanic Acid
Purity
>98.0%(T)
Packaging
1g
Price
$25
Updated
2024/03/01
TCI Chemical
Product number
C1021
Product name
(-)-Camphanic Acid
Purity
>98.0%(T)
Packaging
5g
Price
$74
Updated
2024/03/01
Alfa Aesar
Product number
L16098
Product name
(1S)-(-)-Camphanic acid, 99%
Packaging
5g
Price
$122
Updated
2021/12/16
More
Less

(1S)-(-)-Camphanic acid Chemical Properties,Usage,Production

Chemical Properties

WHITE TO SLIGHTLY BEIGE CRYSTALLINE POWDER

Uses

(1S)-(-)-Camphanic acid may be used in the preparation of (-)-(1S,4R)-camphanoyl chloride by reacting with thionyl chloride.

Definition

ChEBI: (-)-camphanic acid is a delta-lactone.

General Description

(1S)-(-)-Camphanic acid is commonly used as a chiral auxiliary for the separation of racemates.

Purification Methods

Dissolve it in CH2Cl2, dry (MgSO4), filter, evaporate and the residue is sublimed at 120o/0.5mm or 140o/1mm. [Gerlach Helv Chim Acta 61 2773 1978, Beilstein 18/8 V 101.]

(1S)-(-)-Camphanic acid Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(1S)-(-)-Camphanic acid Suppliers

Americas 1 Belgium 1 China 146 Europe 3 France 1 Germany 7 India 7 Japan 3 Switzerland 2 The Netherlands 3 Ukraine 1 United Kingdom 15 United States 29 Global 219
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3576
Advantage
66
More
Less

View Lastest Price from (1S)-(-)-Camphanic acid manufacturers

Aromsyn Co., Ltd.
Product
(1S)-(-)-Camphanic acid 13429-83-9
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
kgs
Release date
2023-02-17
Career Henan Chemical Co
Product
(1S)-(-)-Camphanic acid 13429-83-9
Price
US $1.00/KG
Min. Order
1KG
Purity
90%-99.9%
Supply Ability
500kg
Release date
2019-07-12
Career Henan Chemical Co
Product
(1S)-(-)-Camphanic acid 13429-83-9
Price
US $1.00/KG
Min. Order
1KG
Purity
90%-99.9%
Supply Ability
500kg
Release date
2019-07-09

13429-83-9, (1S)-(-)-Camphanic acidRelated Search:

Palmitic acid cis-Vaccenic acid 4-Bromomethylbenzoic acid Citric acid Folic acid DL-Camphor Sulbactam Isopropyl myristate 3,5-Dimethylbenzoic acid 2-(Trifluoromethyl)benzoic acid METHYL HEPTADECANOATE 6-Aminopenicillanic acid Trimethyl borate o-Toluic acid Stearic acid Hendecanoic acid Hyaluronic acid Methyl 4-(bromomethyl)benzoate

  • 4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
  • (1S)-(-)-CAMPHANIC ACID
  • (1S)-3-OXO-4,7,7-TRIMETHYL-2-OXABICYCLO[2.2.1]HEPTANE-1-CARBOXYLIC ACID
  • (1R)-(-)-CAMPHANIC ACID
  • (S)-(-)-1-CAMPHANIC ACID
  • (-) Camphenic acid
  • (1S,4R)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
  • (3R,6S)-2-Oxo-3β,6β-isopropylidene-3-methyltetrahydro-2H-pyran-6-carboxylic acid
  • [1S,4R,(-)]-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
  • (-)-Camphanic acid,99%
  • (1S)-(-)-CAMPHANIC ACID FOR SYNTHESIS
  • (1S)-(-)-Camphanic acid 98%
  • (4S)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanecarboxylic acid
  • (1S)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
  • 4,7,7-trimethyl(2-oxabicyclo[2.2.1]hept-1-yl)carboxylic acid
  • (1S)-(-)-OMEGA-Camphanic acid
  • 2-Oxabicyclo2.2.1heptane-1-carboxylic acid, 4,7,7-trimethyl-3-oxo-, (1S,4R)-
  • (-)-CAMPHANIC ACID 98+%
  • (IS) CAMPHANIC ACID
  • (1S)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid, (1S)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
  • (-)-Camphanic acid, (1S)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
  • 1,7,7-Trimethyl-2-oxo-3-oxabicyclo[2.2.1]heptane-4-carboxylic acid
  • (1S,4R)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
  • (-)-CAMPHANIC ACID
  • CAMPHANIC ACID
  • (-)-Camphanic Acid &gt
  • (?)-Camphanic acid
  • (4S)-1,7,7-trimethyl-2-oxo-3-oxabicyclo[2.2.1]heptane-4-carboxylic acid
  • (-)-Camphanic Acid
  • 13429-83-9
  • C10H13O4
  • Enantiomer Excess & Absolute Conefiguration Determination
  • Bicyclic Monoterpenes
  • e.e. / Absolute Conefiguration Determination (NMR)
  • Terpenes
  • Asymmetric Synthesis
  • Chiral Resolution Reagents
  • Chiral Resolving Reagents
  • FINE Chemical & INTERMEDIATES
  • Chemical intermediate for Efavirenz
  • Miscellaneous Natural Products
  • API intermediates
  • Analytical Chemistry
  • Bicyclic Monoterpenes
  • Biochemistry
  • e.e. / Absolute Configuration Determination (NMR)
  • Enantiomer Excess & Absolute Configuration Determination
  • Terpenes
  • Chiral Compound