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(1S)-(-)-Camphanic acid

Product Name
(1S)-(-)-Camphanic acid
CAS No.
13429-83-9
Chemical Name
(1S)-(-)-Camphanic acid
Synonyms
CAMPHANIC ACID;(-)-CAMPHANIC ACID;(-)-Camphanic Acid;(-) Camphenic acid;(?)-Camphanic acid;(IS) CAMPHANIC ACID;(-)-Camphanic acid,99%;(-)-Camphanic Acid >(1R)-(-)-CAMPHANIC ACID;(1S)-(-)-CAMPHANIC ACID
CBNumber
CB2669519
Molecular Formula
C10H14O4
Formula Weight
198.22
MOL File
13429-83-9.mol
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(1S)-(-)-Camphanic acid Property

Melting point:
201-205 °C
alpha 
-18.5 º (c=1, dioxane)
Boiling point:
255.53°C (rough estimate)
Density 
1.0143 (rough estimate)
refractive index 
1.4500 (estimate)
storage temp. 
Sealed in dry,Room Temperature
pka
3.36±0.60(Predicted)
form 
powder to crystaline
color 
White to Almost white
optical activity
[α]20/D 18°, c = 1 in dioxane
BRN 
84570
InChIKey
RKFCLVFAFZYVCG-WDEREUQCSA-N
CAS DataBase Reference
13429-83-9(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
22-24/25-37/39-26-36-37
WGK Germany 
3
HS Code 
29329995
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
328227
Product name
(1S)-(?)-Camphanic acid
Purity
98%
Packaging
1g
Price
$62.9
Updated
2023/06/20
Sigma-Aldrich
Product number
328227
Product name
(1S)-(?)-Camphanic acid
Purity
98%
Packaging
5g
Price
$73.6
Updated
2023/01/07
TCI Chemical
Product number
C1021
Product name
(-)-Camphanic Acid
Purity
>98.0%(T)
Packaging
1g
Price
$25
Updated
2024/03/01
TCI Chemical
Product number
C1021
Product name
(-)-Camphanic Acid
Purity
>98.0%(T)
Packaging
5g
Price
$74
Updated
2024/03/01
Alfa Aesar
Product number
L16098
Product name
(1S)-(-)-Camphanic acid, 99%
Packaging
5g
Price
$122
Updated
2021/12/16
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(1S)-(-)-Camphanic acid Chemical Properties,Usage,Production

Chemical Properties

WHITE TO SLIGHTLY BEIGE CRYSTALLINE POWDER

Uses

(1S)-(-)-Camphanic acid may be used in the preparation of (-)-(1S,4R)-camphanoyl chloride by reacting with thionyl chloride.

Definition

ChEBI: (-)-camphanic acid is a delta-lactone.

General Description

(1S)-(-)-Camphanic acid is commonly used as a chiral auxiliary for the separation of racemates.

Purification Methods

Dissolve it in CH2Cl2, dry (MgSO4), filter, evaporate and the residue is sublimed at 120o/0.5mm or 140o/1mm. [Gerlach Helv Chim Acta 61 2773 1978, Beilstein 18/8 V 101.]

(1S)-(-)-Camphanic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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(1S)-(-)-Camphanic acid Suppliers

Americas 1 Belgium 1 China 144 Europe 3 France 1 Germany 7 India 7 Japan 3 Switzerland 2 The Netherlands 3 Ukraine 1 United Kingdom 15 United States 28 Global 216
Matrix Fine Chemicals GmbH
Tel
--
Fax
--
Email
nfo@matrix-fine-chemicals.com
Country
Switzerland
ProdList
6968
Advantage
58
SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from (1S)-(-)-Camphanic acid manufacturers

Aromsyn Co., Ltd.
Product
(1S)-(-)-Camphanic acid 13429-83-9
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
kgs
Release date
2023-02-17
Career Henan Chemical Co
Product
(1S)-(-)-Camphanic acid 13429-83-9
Price
US $1.00/KG
Min. Order
1KG
Purity
90%-99.9%
Supply Ability
500kg
Release date
2019-07-12
Career Henan Chemical Co
Product
(1S)-(-)-Camphanic acid 13429-83-9
Price
US $1.00/KG
Min. Order
1KG
Purity
90%-99.9%
Supply Ability
500kg
Release date
2019-07-09

13429-83-9, (1S)-(-)-Camphanic acidRelated Search:

Palmitic acid cis-Vaccenic acid 4-Bromomethylbenzoic acid Citric acid Folic acid DL-Camphor Sulbactam Isopropyl myristate 3,5-Dimethylbenzoic acid 2-(Trifluoromethyl)benzoic acid METHYL HEPTADECANOATE 6-Aminopenicillanic acid Trimethyl borate o-Toluic acid Stearic acid Hendecanoic acid Hyaluronic acid Methyl 4-(bromomethyl)benzoate

  • 4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
  • (1S)-(-)-CAMPHANIC ACID
  • (1S)-3-OXO-4,7,7-TRIMETHYL-2-OXABICYCLO[2.2.1]HEPTANE-1-CARBOXYLIC ACID
  • (1R)-(-)-CAMPHANIC ACID
  • (S)-(-)-1-CAMPHANIC ACID
  • (-) Camphenic acid
  • (1S,4R)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
  • (3R,6S)-2-Oxo-3β,6β-isopropylidene-3-methyltetrahydro-2H-pyran-6-carboxylic acid
  • [1S,4R,(-)]-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
  • (-)-Camphanic acid,99%
  • (1S)-(-)-CAMPHANIC ACID FOR SYNTHESIS
  • (1S)-(-)-Camphanic acid 98%
  • (4S)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanecarboxylic acid
  • (1S)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
  • 4,7,7-trimethyl(2-oxabicyclo[2.2.1]hept-1-yl)carboxylic acid
  • (1S)-(-)-OMEGA-Camphanic acid
  • 2-Oxabicyclo2.2.1heptane-1-carboxylic acid, 4,7,7-trimethyl-3-oxo-, (1S,4R)-
  • (-)-CAMPHANIC ACID 98+%
  • (IS) CAMPHANIC ACID
  • (1S)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid, (1S)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
  • (-)-Camphanic acid, (1S)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
  • 1,7,7-Trimethyl-2-oxo-3-oxabicyclo[2.2.1]heptane-4-carboxylic acid
  • (1S,4R)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
  • (-)-CAMPHANIC ACID
  • CAMPHANIC ACID
  • (-)-Camphanic Acid &gt
  • (?)-Camphanic acid
  • (4S)-1,7,7-trimethyl-2-oxo-3-oxabicyclo[2.2.1]heptane-4-carboxylic acid
  • (-)-Camphanic Acid
  • 13429-83-9
  • C10H13O4
  • Enantiomer Excess & Absolute Conefiguration Determination
  • Bicyclic Monoterpenes
  • e.e. / Absolute Conefiguration Determination (NMR)
  • Terpenes
  • Asymmetric Synthesis
  • Chiral Resolution Reagents
  • Chiral Resolving Reagents
  • FINE Chemical & INTERMEDIATES
  • Chemical intermediate for Efavirenz
  • Miscellaneous Natural Products
  • API intermediates
  • Analytical Chemistry
  • Bicyclic Monoterpenes
  • Biochemistry
  • e.e. / Absolute Configuration Determination (NMR)
  • Enantiomer Excess & Absolute Configuration Determination
  • Terpenes
  • Chiral Compound